非晶态Ni-P合金的晶化温度与预存晶核的关系

金属学报

1988, Vol. 24

Issue (2): 171-175

论文

本期目录 | 过刊浏览

非晶态Ni-P合金的晶化温度与预存晶核的关系

卢柯;王景唐

中国科学院金属研究所;中国科学院金属研究所

RELATIONSHIP BETWEEN CRYSTALLIZATION TEMPERATURE AND PRE-EXISTING NUCLEI IN THE AMORPHOUS Ni-P ALLOY

LU Ke Institute of Metal Research;Academia Sinica;Shenyang;WANG Jingtang Institute of Metal Research; Academia Sinica; Shenyang

引用本文:

卢柯;王景唐. 非晶态Ni-P合金的晶化温度与预存晶核的关系[J]. 金属学报, 1988, 24(2): 171-175.
, . RELATIONSHIP BETWEEN CRYSTALLIZATION TEMPERATURE AND PRE-EXISTING NUCLEI IN THE AMORPHOUS Ni-P ALLOY[J]. Acta Metall Sin, 1988, 24(2): 171-175.

全文: PDF(834 KB)

摘要: 用经典的相变理论(J-M-A方程)导出了由核长大主导的非晶态合金晶化的峰值温度(T_P)与预存晶核密度(N_0)之间的关系式: T_P~2exp(-Eg/RT_P)=L/N_0~(1/3)其中Eg为核长大激活能,L为常数,R为气体常数.通过对非晶Ni-P合金的预退火处理,获得预存晶核密度不同的非晶态样品,在DSC上测量这些样品的晶化温度.结果表明,上述关系式与实验结果符合很好,利用此关系式可估算出核长大速率常数(U_0),讨论了预退火处理对晶化开始温度T_x及△T_(Px)=T_P—T_x的影响.

关键词 ： Ni-P合金, 非晶态合金, 晶化温度, 预存晶核, 预退火处理

Abstract：According to the classical theory of phase transformation, a relation-ship between crystallization temperature (the peak temperature in the exothermiccurve of crystallization, T_p) and the density of pre-existing nuclei in the sample,N_0, was derived in the crystallization process dominated by growth of nuclei: T_P~2exp(-E_g/RT_P)=L/N_0~(1/3)where Eg is the activation energy for growth of nuclei, L is a constant and R isthe gas constant. Different number of preexisting nuclei was formed by pre-anneal-ing treatment of a Ni-P glass at a temperature about 50K lower than crystalliza-tion temperature for different time. By means of a DSC determination, the crystal-lization temperature of as-quenched and the preannealed samples were obtained andit was found that the new equation successfully agrees with the experimental results.And the growth rate of crystal nuclei in the Ni-P glass can be estimated from therelationship. The onset temperature, T_x, decreases and the difference between T_p and T_x,△T_(px)=T_p-T_x, increases with the increase of annealing time.

Key words： Ni-P alloy amorphous alloy crystallization temperature pre-existing nuclei pre-anneal treatment

收稿日期: 1988-02-18

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	卢柯
	王景唐
44.8K

链接本文:

https://www.ams.org.cn/CN/ 或 https://www.ams.org.cn/CN/Y1988/V24/I2/171

1 Greer A L. Acta Metall. 1982; 30: 171
2 Greer A L, Drehman A J. Acta Metall, 1984; 32: 323
3 Kiminami C S, Sahm P R. Acta Metall, 1986; 34: 2129
4 Baricco M, Battezzati L, Marino F, Riontino G. In: Steeb S, Warlimont H eds. Proc 5th Int Conf on Rapidly Quenched Metals, 1985: 239
5 Christian J W. The Theory of Transformation in Metals and Alloys, London: Pergamon, 1965
6 Henderson D W. J Non-Cryst Solids. 1979; 30: 301
7 Kelton K F, Greer A L, Thompson C V. J Chem Phys, 1983: 79: 6261
8 Lu Ke (卢柯), Wang Jingtang (王景唐). J Mater Sci, to be Published
9 Lu Ke (卢柯), Wang Jingtang (王景唐). Scr Metall, 1987; 21: 1185--1188#

[1]	马殿国,王英敏,李艳辉,张伟. Co含量对熔体快淬Fe_55-_xCo_xPt₁₅B₃₀合金的组织结构与磁性能的影响[J]. 金属学报, 2017, 53(5): 609-614.
[2]	董盼; 张甲; 常新春; 侯万良; 全明秀; 王建强 . Al--Co--Y体系中富 Al区非晶相的形成与结构演化[J]. 金属学报, 2008, 44(2): 227-232 .
[3]	刘元帅徐坚. Ti-(Cu, Ni)-Sn合金形成金属玻璃的成分优化及其相关联的共晶反应[J]. 金属学报, 2008, 44(12): 1424-1430.
[4]	张来昌; 沈智奇; 徐坚 . Sn替代Si和B对Ti50Ni22Cu18Al4Si4B2合金机械研磨非晶化的促进作用[J]. 金属学报, 2004, 40(9): 981-986 .
[5]	张晓强; 徐; 坚 . 机械研磨形成W颗/La55Al25Cu10Ni5Co5金属玻璃基复合材料[J]. 金属学报, 2004, 40(6): 647-.
[6]	张来昌; 沈智奇; 徐坚 . (Ti, Zr, Hf)--(Cu, Ni, Ag)--Al}多组元合金体系的机械驱动非晶化[J]. 金属学报, 2004, 40(4): 421-428 .
[7]	陈文智; 周少雄; 陈金昌 . 铁基-铁镍基非晶双金属的磁性及内应力模型[J]. 金属学报, 2003, 39(6): 592-596 .
[8]	王延玲; 徐坚; 杨锐 . 机械研磨Tix(Cu0.45Ni0.55)94-xSi4B2合金系的玻璃形成范围[J]. 金属学报, 2003, 39(4): 364-368 .
[9]	门华; 徐坚 . Mg-CU-Zn-y块体金属玻璃的形成[J]. 金属学报, 2001, 37(12): 1243-1246 .
[10]	王学业; 邱冠周 . 非晶态合金磁性能与结构参数的定量关系[J]. 金属学报, 2000, 36(2): 123-125 .
[11]	林德明; 郑国桢; 林光明 . 非晶态Fe46Ni32VSi14B6合金的分形断裂[J]. 金属学报, 1999, 35(5): 487-490 .
[12]	李凡; 季亚林; 王桂琴; 张淑仪 . 机械合金化法制备Fe-Ni-P-B磁性非晶合金的研究[J]. 金属学报, 1999, 35(11): 1183-1186 .
[13]	欧阳义芳; 钟夏平; 陈红梅 . 二元过渡族金属合金非晶态形成规律[J]. 金属学报, 1999, 35(10): 1095-1098 .
[14]	张瑗; 朱逢吾; 宝野和博; 井上明久 ; 樱井利夫 . 非晶合金Fe-7Zr-3B的纳米晶结晶化机理[J]. 金属学报, 1999, 35(1): 78-82 .
[15]	吕昭平; 李毅; 黄思峻; 冯元平; 卢柯 . 应用调制差示扫描量热计（Modulated-DSC）分离非晶态合金的玻璃化转变[J]. 金属学报, 1999, 35(1): 73-77 .

Viewed

Full text

Abstract

Cited

Shared

Discussed