金属学报  1986, Vol. 22 Issue (3): 90-94

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液态Fe-Mn和Fe-S二元系表面组成的研究

王景唐;边茂恕;马禄铭

中国科学院金属研究所;中国科学院金属研究所;中国科学院金属研究所

COMPOSITION IN SURFACE OF LIQUID Fe-Mn AND Fe-S SYSTEMS

by WANG Jingtang; BIAN Maoshu; MA Luming(lnstitute of Metal Research; Academia Sinica; Shenyang)

王景唐;边茂恕;马禄铭. 液态Fe-Mn和Fe-S二元系表面组成的研究[J]. 金属学报, 1986, 22(3): 90-94.
, , . COMPOSITION IN SURFACE OF LIQUID Fe-Mn AND Fe-S SYSTEMS[J]. Acta Metall Sin, 1986, 22(3): 90-94.

摘要 参考文献 相关文章 Metrics 全文: PDF(360 KB)   摘要: 曾以卧滴法测定了表面活性元素S,Mn对液Fe表面张力的影响,并按Gibbs方程计算了S,Mn在液Fe表面的吸附值。为比较计算的吸附值和实测值,本文利用Auger电子谱仪和辉光放电发射光谱对Fe-S和Fe-Mn二元系合金进行了表面逐层分析。结果表明,Mn在合金表面沿深度的分布有一贫Mn区;Fe-S系也出现贫硫区;同时观察到,硫在表面的富集系数(C_s~s/C_b~s)较Mn约高两个数量级。这与研究Fe-S和Fe-Mn系的表面现象计算的结果相近。 Abstract：The effect of the surface active elements S and Mn on the surface tension of liquid Fe was investigated by the sessile drop method and their adsorptivity on the liquid Fe surface was calculated by the Gibb's equation. In order to compare the calculated with directly measured adsorption values, the distribution of S and Mn along different depth from the surface of liquid Fe-Mn and Fe-S binary system was analysed layer by layer by AES and/or glow discharge emission spectroscopy. Results indicated that a Mndepleted zone appeared along the depth of surface layer of alloy, and it is the same to S. The higher surface active element S is found to have a greater segregation coefficient about two orders of magnitude of that of Mn. This is analogous to the previous works on calculation of adsorption values from surface tension for the Fe-Mn and Fe-S binary systems. 收稿日期: 1986-03-18      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 王景唐 边茂恕 马禄铭 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1986/V22/I3/90 1 #12 2 Allen, B.C., Liquid Metals, Chemistry and Physics. Eds. Beer, S.Z., Dekker, New York, 1972, p. 170． 3 王景唐,金属学报,8(1965) ,59． 4 徐升美;张功杼;张洪度;于波;王淑梅,金属学报,15(1979) ,126． 5 Davis; L.E,; MacDonald, N.C.; Palmberg, P. W.; Riach, G.E.; Weber, R.E., Handbook, of Auger Electron Spectroscopy, 2nd Ed., Physical Electronics Industries Inc., 1976, p. 13． 6 Overburg, S,H.; Bertrand, P.A.; Somorjai, G.A., J.Chem. Rev., 75 (1975) , 547． No related articles found! Viewed Full text Abstract Cited   Shared      Discussed