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金属学报  1983, Vol. 19 Issue (6): 67-71    
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熔体淬火条件下若干轻稀土金属在Ag中固溶度亚稳扩展的研究
宁远涛;郑云
冶金工业部贵金属研究所;冶金工业部贵金属研究所
METASTABLE EXTENSION OF SOLID SOLUBILITY OF CERTAIN LIGHT RARE-EARTH METALS IN Ag
NING Yuantao; ZHENG Yun (Institute of Precious Metals Research; Kunming)
引用本文:

宁远涛;郑云. 熔体淬火条件下若干轻稀土金属在Ag中固溶度亚稳扩展的研究[J]. 金属学报, 1983, 19(6): 67-71.
, . METASTABLE EXTENSION OF SOLID SOLUBILITY OF CERTAIN LIGHT RARE-EARTH METALS IN Ag[J]. Acta Metall Sin, 1983, 19(6): 67-71.

全文: PDF(374 KB)  
摘要: 以点阵参数法测定了轻稀土金属La,Ce,Pr,Nd和Gd于熔体淬火条件下在Ag中固溶度的扩展.在10~5—10~6 K/s冷却速度下,它们在Ag中的亚稳极限固溶度分别为1.0,1.5,2.5,3.0和6.0at.-%。这些合金的固溶度扩展与镧系收缩成正比,并且符合作者早先对α(A)-A_mB_n型共晶系所提出的扩展机理和规律,还进一步讨论了平衡态固溶度的规律。
Abstract:The metastable extension of solid solubility of certain light rare-earth, i.e. La, Ce, Pr, Nd and Gd, in Ag has evaluated by measurement of the lattice parameters of the quenched melts, made of separate metal with Ag. It was resulted that at the cooling rate about 10~5—10~6 K/s, their metastable limit solid solubility is 1.0, 1.5, 2.5, 3.0 and 6.0 at.-% respectively, which is directly proportional to the contractions of the lanthanide and conform to the authors' proposal on a(A)-A_mB_n eutectic systems. The solid solubility in equilibrium has been discussed.
收稿日期: 1983-06-18     
1 周新铭;靳嘉禄;宁远涛;赵钟民,金属学报,18 (1982) ,534.
2 宁远涛,金属学报,19 (1983) .A 346.
3 Staudhammer, K. P.; Murr, L. E., Atlas of Binary Alloys, Marcel Dekker, Inc., New York, 1973, p. 6.
4 Gschneidner, K. A., Jr.; McMasters, O. D.; Alexander, D. G.; Venteicher, R. F., Metall. Trans., 1 (1970) , 1961.
5 Delfino, S.; Ferro, R.; Capelli, R.; Borsese, A., Z. Metallk., 65 (1974) , 781.
6 Delfino, S.; Ferro, R.; Capelli, R., Borsese, A., J. Less-Common Met., 41 (1975) , 60.
7 Delfino, S.; Borsese, A.; Capelli, R.; Ferro, R., ibid., 35 (1974) , 32.
8 Ferro, R.; Borsese, A.; Selfino, S.; Marazza, R.; Seminara, A., ibid., 35 (1974) , 40.
9 Kiessler, G.; Gebhardt, E.; Steeb, S., ibid., 26 (1972) , 295.
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