金属学报  1966, Vol. 9 Issue (1): 4-12

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氧化鈷氯化反应平衡研究

陈新民;黄健康;鲍超;魏兆熊

THE CHLORINATION EQUILIBRIUM OF COBALT SESQUIOXIDE

CH'N HSIN-MIN; HUANG CHIEN-K'ANG; PAO CH'AO; WEI CHAO-HSIUNG

陈新民;黄健康;鲍超;魏兆熊. 氧化鈷氯化反应平衡研究[J]. 金属学报, 1966, 9(1): 4-12.
, , , . THE CHLORINATION EQUILIBRIUM OF COBALT SESQUIOXIDE[J]. Acta Metall Sin, 1966, 9(1): 4-12.

摘要 参考文献 相关文章 Metrics 全文: PDF(741 KB)   摘要: 报道了用循环法研究氧化钴氯化反应平衡的结果。在673—923°K之间,测得反应: Co_3O_4(固)+3Cl_2(气)=3CoCl_2(固)+2O_2(气)的平衡常数及标准自由能对温度的关系式为:两项式:logK_p-(404/T)-0.304, ΔG_T~O=-1850+1.39T。或者,三项式:logK_p=(4509/T)+12.28logT-41.13, ΔG_T~O=-20630-56.2TlogT+188.2T。 对上述结果与文献报道进行了评述比较,说明了本文作者数据的准确性。 Abstract：The chlorination equilibrium of cobalt sesquioxide has been investigated by the circulation method. Within the temperature range 673—923°K, the equilibrium constant and the standard free energy of the reactionCo_3O_4(s)+3Cl_2(g)=3CoCl_2(s)+2O_2(g) have been found to belog K_p=(404/T)-0.304,ΔG_T~O=-1850+1.39 T.or log K_p=(4509/T)+12.28 log T-41.13,ΔG_T~O=-20630-56.2 T log T+188.2 T.The thermodynamic data reported in previous literature are very divergent. They are critically examined and compared with our data. 收稿日期: 1966-01-18      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 陈新民 黄健康 鲍超 魏兆熊 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1966/V9/I1/4 [1] #12 [2] Sibert, M. E., Kolk, A. J., Steinberg, M. A.: Technology of Columbium (Niobium), Papers Presented at the Symposium on Columbium (Niobium) of the Electrothermics and Metallurgy Division, ed. B. W. Gooser et al., (Wiley, 1958) , p. 20． [3] 岡元敬蔵:日本矿业会志,1963,79,707． [4] Jellinek, K., Rudat, A.: Z. Anorg. Allg. Chem., 1926, 155, 73． [5] #12 [6] 佐野幸吉、岡(山岛)和久:铁钢,1958,44,859． [7] #12 [8] #12 [9] Kubaschewski, O., Evans, E. LL.: Metallurgical Thermochemistry, 3rd ed., (Pergamon, 1958) , p. 337． [10] Villa, H.: J. Soc. Chem. Ind., 1950, 69, 59． [11] #12 [12] Thompson, M.: The Total and Free Energies of Formation of Oxides of Thlrty-Two Metals, (Electrochemical Society, 1942) , p. 123． [13] #12 [14] #12 [15] Elliott, J. F., Gleiser, M.: Thermochemistry for Steel-Making, (Addison-Wesley, 1960) , p. 74． [16] Smithells, C. J.: Metals Reference Book, (Butterworths, 1955) , vol. 2, p. 590-596． [17] King, E. G., Christensen, A. U.: J. Am. Chem. Soc., 1958, 80, 1800． [18] 沈家树、张鸣孝:化学学报,1960,26,124． No related articles found! Viewed Full text Abstract Cited   Shared      Discussed