金属学报  1966, Vol. 9 Issue (1): 13-17

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氧化鎳氯化反应平衡研究

鲍超;黄健康;魏兆熊;陈新民

THE CHLORINATION EQUILIBRIUM OF NICKELOUS OXIDE

PAO CH'AO; HUANG CHIEN-K'ANG; WEI CHAO-HSIUNG; CH'IEN HSIN-MIN

鲍超;黄健康;魏兆熊;陈新民. 氧化鎳氯化反应平衡研究[J]. 金属学报, 1966, 9(1): 13-17.
, , , . THE CHLORINATION EQUILIBRIUM OF NICKELOUS OXIDE[J]. Acta Metall Sin, 1966, 9(1): 13-17.

摘要 参考文献 相关文章 Metrics 全文: PDF(375 KB)   摘要: 用循环法在666—928°K范围内,从两个方向研究了氧化亚镍的氯化反应平衡。确定其反应方程式为: NiO(固)+Cl_2(气)=NiCl_2(固)+1/2O_2(气)。所得数据可用下式表示: logK_p=(2720/T)-2.312, △G_T~O=-12,450+10.58T。 本工作所得数据与文献热力学数据计算结果基本接近。△G~o的最大绝对误差估计为±300卡左右。但随着温度的降低的实验结果与本工作数据有所差异,这可能是由于前者的实验未达到平衡所致。 Abstract：The chlorination equilibrium of nickelous oxide has been investigated using the circulation method within the temperature range 666—928°K from both sides. The reaction is established as NiO(s)+Cl_2(g)=NiCl_2(s)+1/2O_2(g). The equilibrium constant and standard free energy of this reaction may be represented aslog K_p=(2720/T)-2.312ΔG_T~O=-12450+10.58 T.The result is found to be in good agreement with thermodynamic data in the literature. The maximum error for ΔG_T~O is estimated to be about +300 cal. At lower temperature, the experimental results of show some deviation from our data, probably due to unattainment of equilibrium in his experiments. 收稿日期: 1966-01-18      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 鲍超 黄健康 魏兆熊 陈新民 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1966/V9/I1/13 [1] Jellinek, K., Rudat, A.: Z. Anorg. Allgem. Chem., 1926, 155, 73． [2] #12 [3] 陈新民、黄健康、鲍超等:金属学报,1965,9,4． [4] #12 [5] #12 [6] Kubaschewski, O., Evans, E. LL.: Metallurgical Thermochemistry, 3rd ed., (Pergamon, 1958) , p. 262, 320． [7] #12 [8] #12 [9] #12= No related articles found! Viewed Full text Abstract Cited   Shared      Discussed