金属学报  1964, Vol. 7 Issue (1): 12-23

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熔盐溶液的统计理论 第一部分 二元系的混合能

陈念贻;张桂成

中国科学院冶金研究所;中国科学院冶金研究所

STATISTICAL THEORY OF MOLTEN SALT SOLUTIONS Ⅰ. ENERGY OF MIXING OF BINARY SYSTEMS

CHEN NIAN-YI; ZHENG GUI-CHENG;(Institute of Metallurgy; Academia Sinica)

陈念贻;张桂成. 熔盐溶液的统计理论 第一部分 二元系的混合能[J]. 金属学报, 1964, 7(1): 12-23.
, . STATISTICAL THEORY OF MOLTEN SALT SOLUTIONS Ⅰ. ENERGY OF MIXING OF BINARY SYSTEMS[J]. Acta Metall Sin, 1964, 7(1): 12-23.

摘要 参考文献 相关文章 Metrics 全文: PDF(807 KB)   摘要: 本文根据熔盐的径向分布函数理論,对于含一价离子的二元熔盐溶液,提出了三度空間的熔盐溶液統計模型。根据这一模型导出了計算二元熔盐系混合热、混合过剩自由能和某些二元相图液相线的公式,并利用这些公式对各种碱金属硝酸盐和卤化物的二元溶液作了計算,計算結果与实測值颇为符合。 Abstract：From the radial distribution function theory of molten salts, a three-dimensional statistical model was suggested for binary salt solutions, containing monovalent ions only. By this model, formulas for the heat of mixing, the excess free energy of mixing, and the liquidus lines of certain binary phase diagrams were derived. Calculations for various binary alkali nitrate mixtures and binary alkali halide mixtures were made. The results were in good agreement with the experimental values. 收稿日期: 1964-01-18      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 陈念贻 张桂成 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1964/V7/I1/12 [1] #12 [2] Forland, T.: J. Phys. Chem., 1955, 59, 152． [3] Blander, M.: J. Chem. Phys., 1961, 34, 697． [4] Blander, M.: J. Phys. Chem., 1959, 63, 1262． Blander, M.: J. Chem. Phys., 1961, 34, 432． [5] Kleppa, O. J., Katz, J. L.: J. Chem. Phys., 1962, 36, 144． [6] Lumsden, J.: Discussions Faraday Soc., 1961, 32, 138． [7] Stillinger, F. H., Kirkwood, J. G., Wojtowicz, P. J.: J. Chem. Phys., 1960, 32, 1837． [8] #12 [9] Kleppa, O. J.: J. Chem. Phys., 1961, 34, 351． [10] #12 [11] Aukrust, E.: Ann. N. Y. Acad. Sci., 1960, 79, 830． [12] Timmermans, J.: Physico-Chemical Constants of Binary Systems, (Interscience, 1959) . vol. 3, p. 1-301． [13] Guggenheim, E. A.: Mixtures, (Oxford, Univ. Press, 1951) , p. 38． [14] Sauerwald, F., Dombois, H. E.: Z. Anorg. Allgem. Chem.. 1954, 277-278, 60． [15] #12 No related articles found! Viewed Full text Abstract Cited   Shared      Discussed