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金属学报    DOI: 10.11900/0412.1961.2025.00316
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典型环境下埋地钢质管道交流腐蚀行为规律

卢 畅1  梁 毅1  董新利2  陈 乐1  刘 洋3  王春雨3  刘新凌3  杜艳霞1

1 北京科技大学 新材料技术研究院  北京 100083

2 北京市燃气集团有限责任公司  北京 100000

3 广东大鹏液化天然气有限公司  深圳 518048

Alternating Current Corrosion Behavior of Buried Steel Pipelines in Typical Environments

LU Chang 1, LIANG Yi 1, DONG Xinli 2, CHEN Le 1, LIU Yang 3, WANG Chunyu 3, LIU Xinling 3, DU Yanxia 1

1 Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China

2 Beijing Gas Group Co. Ltd., Beijing 100000, China

3 Guangdong Dapeng LNG Co. Ltd., Shenzhen 518048, China

引用本文:

卢畅, 梁毅, 董新利, 陈乐, 刘洋, 王春雨, 刘新凌, 杜艳霞. 典型环境下埋地钢质管道交流腐蚀行为规律[J]. 金属学报, DOI: 10.11900/0412.1961.2025.00316.

全文: PDF(2072 KB)  
摘要: 
为了准确评价珠三角地区埋地管道受到的交流腐蚀风险,本工作针对该地区管道所处的典型土壤环境,通过实验室模拟实验建立了管道交/直流参数与腐蚀情况的相关性,提出了适用于珠三角地区典型环境下管道交流干扰的评估指标和方法。结果表明,当交流电流密度小于等于100 A/m2时,在三种阴极保护电位-0.9、-1.15、-1.2 VCSE下,腐蚀速率均低于0.03 mm/a,随着极化电位负向偏移,交流腐蚀速率越大。当交流电流密度大于等于200 A/m2时,在三种阴极保护电位下,试样的腐蚀速率均高于0.03 mm/a。根据实验结果获得在珠三角地区典型环境下交流腐蚀速率低于0.03 mm/a的交流腐蚀评价指标为:当交流电流密度小于等于100 A/m2时,极化电位的范围为-0.9~-1.2 VCSE。当交流电流密度为500 A/m2时,试样腐蚀速率随着阴极保护电位的负移而增大,这源于高交流干扰与较负阴极保护电位共同作用的腐蚀产物膜动态演变机制,试样在交流电的阳极正半周形成完整的氧化物膜层,阴极反应过程中的析氢反应产生氢气泡导致氧化物膜层变得疏松多孔,试样表面经历Fe3O4产物膜层发生破裂且变疏松的循环变化过程,最终造成试样腐蚀速率显著增大。
关键词 交流腐蚀阴极保护典型土壤环境腐蚀速率    
Abstract

Under the condition of alternating current (AC) interference, the current domestic and international standards impose restrictions on the cathodic protection off-potential. According to the provisions of GB/T 40377–2021 and SY/T 0087.6–2021, when the AC current density is less than 100 A/m2, the polarization potential is required to be between −0.9 and −1.15 VCSE. However, to reduce the dynamic direct current (DC) interference corrosion risk of the metro, the cathodic protection potential of pipelines in the Pearl River Delta region is mostly lower than −1.15 VCSE. Therefore, to accurately assess the AC corrosion risk of buried pipelines in the Pearl River Delta region, this study focused on the typical soil environments encountered by pipelines in this area. Laboratory simulation experiments were conducted to establish the correlation between pipeline AC/DC parameters and corrosion behavior, aiming to propose AC interference assessment criteria and methods suitable for the typical environments of the Pearl River Delta. The results show that when the AC current density is less than or equal to 100 A/m2, the corrosion rate is less than 0.03 mm/a under three cathodic protection potentials of −0.9, −1.15, and −1.2 VCSE. With the negative shift of the polarization potential, the AC corrosion rate increases. When the AC current density is greater than or equal to 200 A/m2, the corrosion rate of the samples is higher than 0.03 mm/a under all three cathodic protection potentials. According to the experimental results, the AC corrosion evaluation index for the typical environment of the Pearl River Delta, where the AC corrosion rate is less than 0.03 mm/a is as follows: when the AC current density is less than or equal to 100 A/m2, the range of the polarization potential is −0.9 to −1.2 VCSE. When the AC density reaches 500 A/m2, the corrosion rate of the specimens increases with the negative shift of the cathodic protection potential, which originates from the dynamic evolution mechanism of the corrosion product film under the combined action of high AC interference and increasingly negative cathodic protection potentials. During the positive half-cycle of the AC signal, a complete oxide film layer forms on the specimen surface. In the cathodic reaction stage, the hydrogen evolution reaction generates hydrogen bubbles, causing the oxide film layer to become porous and loosely structured. The specimen surface undergoes a cyclic process of formation, rupture, and loosening of the Fe3O4 product film layer, ultimately leading to a notable increase in the corrosion rate of the specimen.

收稿日期: 2025-10-10     
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