Research paper

Effect of Hot Extrusion and Heat Treatment on the Microstructure and Tensile Properties of Network Structured TiBw/TC18 Composites

  • Run CHEN ,
  • Shuai WANG ,
  • Qi AN ,
  • Rui ZHANG ,
  • Wenqi LIU ,
  • Lujun HUANG ,
  • Lin GENG
Expand
  • School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
WANG Shuai, Tel: 13704505457, E-mail: wangshuai1993@hit.edu.cn

Received date: 2022-04-21

  Revised date: 2022-08-01

  Online published: 2022-09-01

Supported by

National Key Research and Development Program of China(2021YFB3701203);National Natural Science Foundation of China(52171137);National Natural Science Foundation of China(52071116);Natural Science Foundation of Heilongjiang Province(TD2020E001);Heilongjiang Postdoctoral Fund(LBH-Z20058)

Abstract

To improve the comprehensive performance of Ti matrix composites for defense applications such as aviation and aerospace, as-sintered TiBw/TC18 composites with different reinforcement contents were hot extruded and heat-treated. The composites were characterized and analyzed by OM, SEM, and TEM. The mechanical properties of the composites were measured using an electronic universal testing machine. By extruding in the β single-phase region, the β grain size of TiBw/TC18 was reduced from 70 μm to about 40 μm. After the subsequent triple-annealing or solution aging heat treatment, α phase with different sizes was precipitated and distributed in the β phase. The elongation of the as-extruded composites significantly showed improvement, but the strength decreased by about 17%. After applying the triple-annealing heat treatment, the tensile strength and elongation of 2.0%TiBw/TC18 (volume fraction) reached 1200 MPa and 21.7%, which are higher by 5.5% and 189%, respectively, than those in the sintered state. Moreover, after applying the solution aging heat treatment, the as-extruded 2.0%TiBw/TC18 exhibited tensile strength and elongation of 1389 MPa and 9.9%, which are higher by 22.2% and 32%, respectively, than those exhibited by as-sintered 2.0%TiBw/TC18. Consequently, the hot extrusion can effectively reduce the grain size of as-sintered TiBw/TC18, and the tensile properties of the extruded TiBw/TC18 can be modified to meet the requirements of different service conditions through different subsequent heat treatments.

Cite this article

Run CHEN , Shuai WANG , Qi AN , Rui ZHANG , Wenqi LIU , Lujun HUANG , Lin GENG . Effect of Hot Extrusion and Heat Treatment on the Microstructure and Tensile Properties of Network Structured TiBw/TC18 Composites[J]. Acta Metall Sin, 2022 , 58(11) : 1478 -1488 . DOI: 10.11900/0412.1961.2022.00187

References

1 Zhang R, Wang D J, Huang L J, et al. Effects of heat treatment on microstructure and high temperature tensile properties of TiBw/TA15 composite billet with network architecture [J]. Mater. Sci. Eng., 2017, A679: 314
2 Wang S, An Q, Zhang R, et al. Microstructure characteristics and enhanced properties of network-structured TiB/(TA15-Si) composites via rolling deformation at different temperatures [J]. Mater. Sci. Eng., 2022, A829: 142176
3 Huang L J, Geng L. Progress on discontinuously reinforced titanium matrix composites [J]. J. Aeronaut. Mater., 2014, 34(04): 126
3 黄陆军, 耿 林. 非连续增强钛基复合材料研究进展 [J]. 航空材料学报, 2014, 34(04): 126
4 Tjong S C, Ma Z Y. Microstructural and mechanical characteristics of in situ metal matrix composites [J]. Mater. Sci. Eng., 2000, R29: 49
5 Ma Z Y, Tjong S C, Gen L. In-situ Ti-TiB metal-matrix composite prepared by a reactive pressing process [J]. Scr. Mater., 2000, 42: 367
6 Patel V V, El-Desouky A, Garay J E, et al. Pressure-less and current-activated pressure-assisted sintering of titanium dual matrix composites: Effect of reinforcement particle size [J]. Mater. Sci. Eng., 2009, A507: 161
7 Panda K B, Ravi Chandran K S. Synthesis of ductile titanium-titanium boride (Ti-TiB) composites with a beta-titanium matrix: The nature of TiB formation and composite properties [J]. Metall. Mater. Trans., 2003, 34A: 1371
8 Huang L J, Geng L, Li A B, et al. In situ TiBw/Ti-6Al-4V composites with novel reinforcement architecture fabricated by reaction hot pressing [J]. Scr. Mater., 2009, 60: 996
9 Hashin Z, Shtrikman S. A variational approach to the theory of the elastic behaviour of multiphase materials [J]. J. Mech. Phys. Solids, 1963, 11: 127
10 Wang S, Huang L J, Jiang S, et al. Multiplied bending ductility and toughness of titanium matrix composites by laminated structure manipulation [J]. Mater. Des., 2021, 197: 109237
11 Wei S L, Huang L J, Li X T, et al. Correction to: Network-strengthened Ti-6Al-4V/(TiC + TiB) composites: Powder metallurgy processing and enhanced tensile properties at elevated temperatures [J]. Metall. Mater. Trans., 2020, 51A: 1437
12 Zhang R, Huang L J, An Q, et al. The hyperbolic constitutive equations and modified dynamic material model of TiBw/Ti-6.5Al-2.5Zr-1Mo-1V-0.5Si composites [J]. Mater. Sci. Eng., 2019, A766: 138329
13 Jiao Y, Huang L J, Wei S L, et al. Constructing two-scale network microstructure with nano-Ti5Si3 for superhigh creep resistance [J]. J. Mater. Sci. Technol., 2019, 35: 1532
14 Roy S, Suwas S, Tamirisakandala S, et al. Development of solidification microstructure in boron-modified alloy Ti-6Al-4V-0.1B [J]. Acta Mater., 2011, 59: 5494
15 Sun S Y, Lu W J. Effects of trace reinforcements on microstructure and tensile properties of in-situ synthesized TC18 Ti matrix composite [J]. J. Compos. Mater., 2017, 51: 3623
16 Sen I, Ramamurty U. Elastic modulus of Ti-6Al-4V-xB alloys with B up to 0.55 wt.% [J]. Scr. Mater., 2010, 62: 37
17 Liu C M, Wang H M, Tian X J, et al. Microstructure and tensile properties of laser melting deposited Ti-5Al-5Mo-5V-1Cr-1Fe near β titanium alloy [J]. Mater. Sci. Eng., 2013, A586: 323
18 Prithiv T S, Kloenne Z, Li D, et al. Grain boundary segregation and its implications regarding the formation of the grain boundary α phase in the metastable β-Titanium Ti-5Al-5Mo-5V-3Cr alloy [J]. Scr. Mater., 2022, 207: 114320
19 Sun J F, Zhang Z W, Zhang M L, et al. Microstructure evolution and their effects on the mechanical properties of TB8 titanium alloy [J]. J. Alloys Compd., 2016, 663: 769
20 Yao C F, Wu D X, Ma L F, et al. Surface integrity evolution and fatigue evaluation after milling mode, shot-peening and polishing mode for TB6 titanium alloy [J]. Appl. Surf. Sci., 2016, 387: 1257
21 Chen R, An Q, Wang S, et al. Overcoming the strength-ductility trade-off dilemma in TiBw/TC18 composites via network architecture with trace reinforcement [J]. Mater. Sci. Eng., 2022, A842: 143092
22 Zheng Y F, Wu Y H. Revolutionizing metallic biomaterials [J]. Acta Metall. Sin., 2017, 53: 257
22 郑玉峰, 吴远浩. 处在变革中的医用金属材料 [J]. 金属学报, 2017, 53: 257
23 Liu D K, Huang G S, Gong G L, et al. Influence of different rolling routes on mechanical anisotropy and formability of commercially pure titanium sheet [J]. Trans. Nonferrous Met. Soc. China, 2017, 27: 1306
24 Ma J K, Li J J, Wang Z J, et al. Bonding zone microstructure and mechanical properties of forging-additive hybrid manufactured Ti-6Al-4V Alloy [J]. Acta. Metall. Sin., 2021, 57: 1246
24 马健凯, 李俊杰, 王志军 等. 锻造-增材复合制造Ti-6Al-4V合金结合区显微组织及力学性能 [J]. 金属学报, 2021, 57: 1246
25 Liu R C, Wang Z, Liu D, et al. Microstructure and tensile properties of Ti-45.5A1-2Cr-2Nb-0.15B alloy processed by hot extrusion [J]. Acta Metall. Sin., 2013, 49: 641
25 刘仁慈, 王 震, 刘 冬 等. Ti-45.5A1-2Cr-2Nb-0.15B合金热挤压组织与拉伸性能研究 [J]. 金属学报, 2013, 49: 641
26 Wang B, Huang L J, Hu H T, et al. Superior tensile strength and microstructure evolution of TiB whisker reinforced Ti60 composites with network architecture after β extrusion [J]. Mater. Charact., 2015, 103: 140
27 Wang B, Huang L J, Geng L, et al. Effects of heat treatments on microstructure and tensile properties of as-extruded TiBw/near-α Ti composites [J]. Mater. Des., 2015, 85: 679
28 Banerjee D, Williams J C. Perspectives on titanium science and technology [J]. Acta Mater., 2013, 61: 844
29 Guo X L, Wang L Q, Wang M M, et al. Effects of degree of deformation on the microstructure, mechanical properties and texture of hybrid-reinforced titanium matrix composites [J]. Acta Mater., 2012, 60: 2656
Outlines

/