Effects of Laves Phase on Burst Behavior of GH3625 Superalloy Pipe During Hot Extrusion
Received date: 2020-07-17
Revised date: 2020-12-17
Online published: 2021-01-20
Supported by
National Key Research and Development Program of China(2017YFA0700703);National Natural Science Foundation of China(51661019);Program for Major Projects of Science and Technology in Gansu Province(145RTSA004);Program for State Key Laboratory Nickel and Cobalt Resources Comprehensive Utilization(301170503);Program for Hongliu First-Class Discipline Construction Plan of Lanzhou University of Technology
GH3625 superalloy is a type of solid-solution strengthened nickel-based wrought superalloy having Mo and Nb as the main strengthening elements. Because of its excellent high-temperature mechanical properties and oxidation resistance below 650 oC, it can be used in harsh stress and atmosphere environments. It is mainly used as a pipe material for aeroengine fuel main pipe, nuclear power steam generator heat transfer pipe, and pressure pipe, etc. Owing to the high alloying degree of nickel-based superalloys, large deformation resistance, and narrow thermal processing temperature range, the pipe preparation process is complicated. In this study, the as-cast and homogenized pipe billets were used for a short-flow hot extrusion pipe preparation test using the same process. The homogenized pipe billet was extruded successfully, and the pipe burst occurred during the extrusion of the as-cast billet. The pipe burst behavior was studied by OM, SEM, and EBSD, with an EDS analysis. The results showed a considerable amount of Laves phases in the as-cast pipe billet, and the Laves phases and micro-segregation were essentially eliminated after homogenization. Adiabatic heating of the as-cast pipe billet leads to the Laves phase remelting during the hot extrusion process, which is the main reason for pipe bursting during a hot extrusion process. The cracking mode of the pipe burst is a quasi-cleavage fracture, combining brittle fracture and ductile fracture with the predominance of the brittle fracture.
Key words: GH3625 superalloy; hot extruded pipe; microstructure; Laves phase; pipe burst
Jianjun CHEN , Yutian DING , Kun WANG , Kang YAN , Yuanjun MA , Xingmao WANG , Shengming ZHOU . Effects of Laves Phase on Burst Behavior of GH3625 Superalloy Pipe During Hot Extrusion[J]. Acta Metall Sin, 2021 , 57(5) : 641 -650 . DOI: 10.11900/0412.1961.2020.00264
| 1 | Guo J T. Materials Science and Engineering for Superalloys (Book 1) [M]. Beijing: Science Press, 2008: 1 |
| 1 | 郭建亭. 高温合金材料学 (上册) [M]. 北京: 科学出版社, 2008: 1 |
| 2 | Shi C X, Zhong Z Y. Fifty Years Development of Superalloy in China [M]. Beijing: Metallurgical Industry Press, 2006: 1 |
| 2 | 师昌绪, 仲增墉. 中国高温合金五十年 [M]. 北京: 冶金工业出版社, 2006: 1 |
| 3 | Gao Y B, Ding Y T, Chen J J, et al. Evolution of microstructure and texture during cold deformation of hot-extruded GH3625 alloy [J]. Acta Metall. Sin., 2019, 55: 547 |
| 3 | 高钰璧, 丁雨田, 陈建军等. 挤压态GH3625合金冷变形过程中的组织和织构演变 [J]. 金属学报, 2019, 55: 547 |
| 4 | Dang L, Yang H, Guo L G, et al. DRX rules during extrusion process of large-scale thick-walled Inconel 625 pipe by FE method [J]. Trans. Nonferrous Met. Soc. China, 2015, 25: 3037 |
| 5 | Tian D. Development and production of high-temperature alloy seamless tubulars [J]. Steel Pipe, 2002, 31( 3): 1 |
| 5 | 田 党. 高温合金无缝管材的研制与生产 [J]. 钢管, 2002, 31( 3): 1 |
| 6 | Zou Z H. Development of domestic manufacturing technologies for stainless steel tubes and gap with similar technologies developed overseas [J]. Steel Pipe, 2000, 29( 6): 7 |
| 6 | 邹子和. 我国不锈钢管生产技术的进展及其与国外的差距 [J]. 钢管, 2000, 29( 6): 7 |
| 7 | Li D F, Wu Z G, Guo S L, et al. Study on the processing map of GH625 Ni-based alloy deformed at high temperature [J]. Rare Met. Mater. Eng., 2012, 41: 1026 |
| 7 | 李德富, 吾志岗, 郭胜利等. GH625镍基合金高温塑性变形加工图研究 [J]. 稀有金属材料与工程, 2012, 41: 1026 |
| 8 | Ding Y T, Chen J J, Li H F, et al. Study on processing map of homogenized GH3625 superalloy and its tube manufacturing by short-flow hot extrusion [J]. Mater. Rev., 2019, 33: 2753 |
| 8 | 丁雨田, 陈建军, 李海峰等. 均匀化态GH3625合金热加工图及短流程热挤压管材研究 [J]. 材料导报, 2019, 33: 2753 |
| 9 | Wei J X, Su C L, He Y H. The research on hot extruding temperature of GH3625 alloy tube billet [J]. Spec. Steel Technol., 2015, 21( 2): 38 |
| 9 | 韦家向, 苏承龙, 何云华. GH3625合金管坯热挤压温度研究 [J]. 特钢技术, 2015, 21( 2): 38 |
| 10 | Ding Y T, Liu D X, Hu Y, et al. A short-flow hot extrusion process for forming Inconel 625 superalloy pipe [P]. Chin Pat, 201510899976.1, 2015 |
| 10 | 丁雨田, 刘德学, 胡 勇等. 短流程热挤压变形高温合金Inconel 625管材方法 [P]. 中国专利, 201510899976.1, 2015)) |
| 11 | Liu D X, Cheng X W, Zhang X, et al. Effects of heating and hot extrusion process on microstructure and properties of Inconel 625 alloy [J]. J. Wuhan Univ. Technol., 2016, 31: 1368 |
| 12 | Dong J X. Extrusion and Microstructure Control of Nickel based Alloy Tubes [M]. Beijing: Metallurgical Industry Press, 2014: 1 |
| 12 | 董建新. 镍基合金管材挤压及组织控制 [M]. 北京: 冶金工业出版社, 2014: 1 |
| 13 | Wang B S, Shao Y, Su C. Investigation on cracks in 825 alloy pipe during hot extrusion process [J]. Hot Work. Technol., 2013, 42( 15): 127 |
| 13 | 王宝顺, 邵 羽, 苏 诚. 825合金热挤压管裂纹研究 [J]. 热加工工艺, 2013, 42( 15): 127 |
| 14 | Gao Y G, Sun H G, Pang Y S, et al. Investigation of hot extrusion-caused cracking of Inconel 718 seamless steel tube and related control measures [J]. Steel Pipe, 2017, 46( 6): 44 |
| 14 | 高玉光, 孙海刚, 庞于思等. Inconel 718无缝钢管热挤压开裂原因分析和控制 [J]. 钢管, 2017, 46( 6): 44 |
| 15 | Peng H J. Study on hot deformation behaviors and hot tube extrusion mechanism of GH690 alloy [D]. Beijing: General Research Institute for Nonferrous Metals, 2014 |
| 15 | 彭海健. GH690合金热变形行为及管材热挤压机理研究 [D]. 北京: 北京有色金属研究总院, 2014 |
| 16 | Wang B. High speed hot tube extrution process of Inconel690 superalloy [J]. Rare Met. Mater. Eng., 2014, 43( ): 137 |
| 16 | 王 彬. Inconel690合金管高速热挤压成形工艺研究 [J]. 稀有金属材料与工程, 2014, 43( ): 137 |
| 17 | Jiang H, Yang L, Dong J X, et al. The recrystallization model and microstructure prediction of alloy 690 during hot deformation [J]. Mater. Des., 2016, 104: 162 |
| 18 | Godasu A K, Prakash U, Mula S. Flow stress characteristics and microstructural evolution of cast superalloy 625 during hot deformation [J]. J. Alloys Compd., 2020, 844: 156200 |
| 19 | Guo S L, Li D F, Guo Q M, et al. Investigation on hot workability characteristics of Inconel 625 superalloy using processing maps [J]. J. Mater. Sci., 2012, 47: 5867 |
| 20 | Wang Y, Wang J S, Dong J S, et al. Hot deformation characteristics and hot working window of as-cast large-tonnage GH3535 superalloy ingot [J]. J. Mater. Sci. Technol., 2018, 34: 2439 |
| 21 | Lypchanskyi O, ?leboda T, Zygula K, et al. Evaluation of hot workability of nickel-based superalloy using activation energy map and processing maps [J]. Materials, 2020, 13: 3629 |
| 22 | Yao Z H, Dong J X, Zhang M C, et al. Hot deformation behaviour of superalloy GH738 [J]. Rare Met. Mater. Eng., 2013, 42: 1199 |
| 22 | 姚志浩, 董建新, 张麦仓等. GH738高温合金热加工行为 [J]. 稀有金属材料与工程, 2013, 42: 1199 |
| 23 | Ding Y T, Gao X, Dou Z Y, et al. Numerical simulation of hot extrusion process of GH3625 alloy tubes [J]. Spec. Cast. Nonferrous Alloys, 2016, 36: 1121 |
| 23 | 丁雨田, 高 鑫, 豆正义等. GH3625合金管材热挤压过程的数值模拟 [J]. 特种铸造及有色合金, 2016, 36: 1121 |
| 24 | Ding Y T, Wang K, Gao Y B, et al. Microstructure and crack forming mechanism of GH3625 alloy tube by hot extruded forming process [J]. Rare Met. Mater. Eng., 2020, 49: 1743 |
| 24 | 丁雨田, 王 琨, 高钰璧等. 热挤压成形GH3625合金管材组织及裂纹形成机理 [J]. 稀有金属材料与工程, 2020, 49: 1743 |
| 25 | Ding Y T, Li H F, Wang W, et al. Microsegregation and homogenization of GH3625 alloy ingot [J]. Mater. Sci. Technol., 2016, 24( 6): 14 |
| 25 | 丁雨田, 李海峰, 王 伟等. 铸锭GH3625合金微观偏析及均匀化热处理 [J]. 材料科学与工艺, 2016, 24( 6): 14 |
| 26 | Schirra J J, Caless R H, Hatala R W. The effect of laves phase on the mechanical properties of wrought and cast + HIP Inconel 718 [A]. Superalloys 718, 625 and Various Derivatives [C]. Warrendale, PA: The Minerals, Metals & Materials Society, 1991: 375 |
| 27 | Deng Q, Du J H, Zhuang J Y, et al. As-cast microstructure and segregation improvement of alloy GH742y [J]. J. Iron Steel Res., 2007, 19( 5): 89 |
| 27 | 邓 群, 杜金辉, 庄景云等. GH742y合金的铸态组织及铸态偏析的改善 [J]. 钢铁研究学报, 2007, 19( 5): 89 |
| 28 | Li X X, Jia C L, Zhang Y, et al. Incipient melting phase and its dissolution kinetics for a new superalloy [J]. Trans. Nonferrous Met. Soc., 2020, 30: 2107 |
| 29 | Ding Y T, Dou Z Y, Gao Y B, et al. Phase transformation during metling and solidifying process of homogenized superalloy GH3625 [J]. Chin. J. Mater. Res., 2017, 31: 853 |
| 29 | 丁雨田, 豆正义, 高钰璧等. 均匀化态GH3625合金熔化和凝固过程中的相变 [J]. 材料研究学报, 2017, 31: 853 |
| 30 | Gao Y B, Ding Y T, Chen J J, et al. Effect of twin boundaries on the microstructure and mechanical properties of Inconel 625 alloy [J]. Mater. Sci. Eng., 2019, A767: 138361 |
| 31 | Jiang H, Dong J X, Zhang M C, et al. Evolution of twins and substructures during low strain rate hot deformation and contribution to dynamic recrystallization in alloy 617B [J]. Mater. Sci. Eng., 2016, A649: 369 |
| 32 | Gleiter H. The formation of annealing twins [J]. Acta Metall., 1969, 17: 1421 |
| 33 | Li Z G. Evolution of annealing twin boundary and mechanical behavior in a nickel-iron based wrought alloy [D]. Shanghai: Shanghai Jiao Tong University, 2015 |
| 33 | 李志刚. 一种镍铁基变形高温合金中退火孪晶界的演变与力学行为 [D]. 上海: 上海交通大学, 2015 |
| 34 | Mandal S, Bhaduri A K, Sarma V S. Role of twinning on dynamic recrystallization and microstructure during moderate to high strain rate hot deformation of a Ti-modified austenitic stainless steel [J]. Metall. Mater. Trans., 2012, 43A: 2056 |
| 35 | Liu C T, Zhu J H, Brady M P, et al. Physical metallurgy and mechanical properties of transition-metal Laves phase alloys [J]. Intermetallics, 2000, 8: 1119 |
| 36 | Malitckii E, Remes H, Lehto P, et al. Strain accumulation during microstructurally small fatigue crack propagation in bcc Fe-Cr ferritic stainless steel [J]. Acta Mater., 2018, 144: 51 |
| 37 | Liu X G, Xu H, Gao X. Fracture failure analysis of automotive main axle [J]. Found. Technol., 2018, 39: 933 |
| 37 | 刘晓光, 徐 浩, 高 鑫. 汽车主轴的断裂失效分析 [J]. 铸造技术, 2018, 39: 933 |
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