Research paper

Design and Performance of 690 MPa Grade Low-Carbon Microalloyed Construction Structural Steel with High Strength and Toughness

  • Wenting ZHU ,
  • Junjun CUI ,
  • Zhenye CHEN ,
  • Yang FENG ,
  • Yang ZHAO ,
  • Liqing CHEN
Expand
  • 1.State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819, China
    2.Technical Department, Technology Research Institute of HBIS, Shijiazhuang 050000, China
    3.School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China

Received date: 2020-06-03

  Revised date: 2020-07-13

  Online published: 2020-11-15

Supported by

National Natural Science Foundation of China(51904071);Fundamental Research Funds for the Central Universities(N180703011);Key Research and Development Program of Hebei Province(18211019D);Start-Up Project of Doctor Scientific Research of Liaoning Province(2020-BS-271)

Abstract

The rapid development of high-rise buildings has increasingly brought requirements for construction steels with high strength and toughness. For high-rise building structural steels with low yield ratio, good weldability and excellent resistance to fire and corrosion are generally required. However, high grade construction steels with comprehensive properties are yet to be developed. In this study, a 690 MPa grade functionally structured fire and corrosion resistant high strength construction steel was designed based on the thermodynamic calculations of the JMatPro software and interactions among chemical elements. The chemical composition (mass fraction, %) of the designed steel was Fe-0.08C-0.3Si-1.1Mn-0.12(Nb + V + Ti)-1.6(Cr + Cu + Ni + Mo)-0.002B-0.004N. After laboratory melting and a thermomechanical controlled process (TMCP), the microstructure features, strengthening and toughening mechanisms, mechanical properties, and fire and corrosion resistances were characterized and analyzed by EPMA, EBSD, and performance testing. Results show that the microstructure of this low-carbon microalloyed steel at its TMCP state is mainly composed of bainite ferrite, granular bainite, and lath-like bainite. The yield strength, tensile strength, total elongation, and yield ratio at room temperature are 700 MPa, 878 MPa, 20%, and 0.80, respectively, and this steel possesses good low-temperature toughness. This low-carbon microalloyed steel meets requirements for fire resistance at elevated temperatures up to 600oC for 3 h. It is disclosed that the granular bainite plays a positive role in improving corrosion resistance under marine environment. A further analysis shows that the tested steel possesses excellent strength and toughness resulting from the cumulative effects of precipitation strengthening, grain refinement strengthening, dislocation strengthening, and solid solution strengthening. Moreover, after observation and analysis of crack initiation and propagation underneath the fractured surface of low-temperature impacted samples, the microvoids prefer to nucleate at high-angle boundaries containing brittle phases and grow in a Z-type to cross lath-like bainite to consume more energy. Multiple crack deflections are beneficial for toughness improvements.

Cite this article

Wenting ZHU , Junjun CUI , Zhenye CHEN , Yang FENG , Yang ZHAO , Liqing CHEN . Design and Performance of 690 MPa Grade Low-Carbon Microalloyed Construction Structural Steel with High Strength and Toughness[J]. Acta Metall Sin, 2021 , 57(3) : 340 -352 . DOI: 10.11900/0412.1961.2020.00195

References

1 Ishii T, Fujisawa S, Ohmori A. Overview and application of steel materials for high-rise buildings [J]. JFE Tech. Rep., No.14, 2009: 1
2 Sakumoto Y. Recent trends and future direction in the technology for structural steels used in buildings [J]. Nippon Steel Tech. Rep., No.97, 2008: 8
3 Yu Q B, Zhao X P, Sun B, et al. Yield-strength ratio of steel plate for high-rise building [J]. Iron Steel, 2007, 42(11): 74
3 于庆波, 赵贤平, 孙 斌等. 高层建筑用钢板的屈强比 [J]. 钢铁, 2007, 42(11): 74
4 Kato B. Role of strain-hardening of steel in structural performance [J]. ISIJ Int., 1990, 30: 1003
5 Kim Y, Lee J, Park J, et al. Effect of Si content on wettability of dual phase high strength steels by liquid Zn-0.23 wt.%Al [J]. Met. Mater. Int., 2011, 17: 607
6 Huang G, Wu K M. The effect of relaxing on the grain refinement of low carbon high strength microalloyed steel produced by compact strip production [J]. Met. Mater. Int., 2011, 17: 847
7 Prasad S N, Mediratta S R, Sarma D S. Influence of austenitisation temperature on the structure and properties of weather resistant steels [J]. Mater. Sci. Eng., 2003, A358: 288
8 Prasad S N, Sarma D S. Influence of thermomechanical treatment on microstructure and mechanical properties of a microalloyed (Nb+V) weather-resistant steel [J]. Mater. Sci. Eng., 2005, A399: 161
9 Zhao Y T, Yang S W, Shang C J, et al. The mechanical properties and corrosion behaviors of ultra-low carbon microalloying steel [J]. Mater. Sci. Eng., 2007, A454-455: 695
10 Baker T N. Processes, microstructure and properties of vanadium microalloyed steels [J]. Mater. Sci. Technol., 2009, 25: 1083
11 Lee S I, Lee J, Hwang B. Microstructure-based prediction of yield ratio and uniform elongation in high-strength bainitic steels using multiple linear regression analysis [J]. Mater. Sci. Eng., 2019, A758: 56
12 Hulka K, Kern A, Schriever U. Application of niobium in quenched and tempered high-strength steels [J]. Mater. Sci. Forum., 2005, 500-501: 519
13 Yang H, Yang H, Qu J B. Effect of heat treatment on microstructure and mechanical properties of a 690 MPa grade high strength steel with low yield ratio [J]. Trans. Mater. Heat Treat., 2013, 34(5): 137
13 杨 浩, 杨 汉, 曲锦波. 热处理工艺对690 MPa级低屈强比高强钢组织性能的影响 [J]. 材料热处理学报, 2013, 34(5): 137
14 Tong M W. Development of 550/690MPa high strength-toughness construction steels with low yield ratio and research of its anti-fracture performance [D]. Wuhan: Wuhan University of Science and Technology, 2016
14 童明伟. 550/690MPa级高强韧低屈强比结构钢开发及抗断能力研究 [D]. 武汉: 武汉科技大学, 2016
15 Keiji U, Shigeru E, Takayuki I. 780 MPa grade steel plates with low yield ratio by microstructural control of dual phase [J]. JFE Technical Report, 2007, (18): 23
15 植田 圭治, 遠藤 茂, 伊藤 高幸. 硬質第2相分散組織制御型低YR780MPa級鋼板 [J]. JFE技報, 2007, (18): 23
16 Hui Y J, Zhao A M, Zhao Z Z, et al. Study on ultra-low carbon bainite steel with low yield ratio for engineering machinery [J]. Trans. Mater. Heat Treat., 2012, 33(Suppl.II):92
16 惠亚军, 赵爱民, 赵征志等. 低屈强比超低碳贝氏体型工程机械用钢的研究 [J]. 材料热处理学报, 2012, 33(增刊II):92
17 Zhou Y L, Chen J, Xu Y, et al. Effects of Cr, Ni and Cu on the corrosion behavior of low carbon microalloying steel in a Cl? containing environment [J]. J. Mater. Sci. Technol., 2013, 29: 168
18 Misra R D K, Nathani H, Hartmann J E, et al. Microstructural evolution in a new 770 MPa hot rolled Nb-Ti microalloyed steel [J]. Mater. Sci. Eng., 2005, A394: 339
19 Hu J, Du L X, Wang W H, et al. Microstructural control and mechanical properties of 590 MPa grade hot-rolled V-N high strength steel [J]. J. Northeast. Univ. (Nat. Sci.), 2013, 34: 820
19 胡 军, 杜林秀, 王万慧等. 590 MPa级热轧V-N高强车轮钢组织性能控制 [J]. 东北大学学报(自然科学版), 2013, 34: 820
20 Xu M, Sun X J, Liu Q Y, et al. Microstructural evolution and precipitation of V(C, N) in a low-carbon V-bearing steel [J]. Iron Steel Vanad. Titan., 2005, 26(2): 25
20 徐 曼, 孙新军, 刘清友等. 低碳含钒钢组织变化及V(C, N)析出规律 [J]. 钢铁钒钛, 2005, 26(2): 25
21 Kanga J S, Seol J B, Park C G. Three-dimensional characterization of bainitic microstructures in low-carbon high-strength low-alloy steel studied by electron backscatter diffraction [J]. Mater. Charact., 2013, 79: 110
22 Sung H K, Lee D H, Shin S Y, et al. Effect of finish cooling temperature on microstructure and mechanical properties of high-strength bainitic steels containing Cr, Mo, and B [J]. Mater. Sci. Eng., 2015, A624: 14
23 Ohmori Y, Ohtani H, Kunitake T. Tempering of the bainite and the bainite/martensite duplex structure in a low-carbon low-alloy steel [J]. Met. Sci., 1974, 8: 357
24 Bhadeshia H K D H. Models for the Elementary Mechanical Properties of Steel Welds [M]. London: Institute of Materials, 1997: 229
25 Yong Q L. Secondary Phases in Steels [M]. Beijing: Metallurgy Industry Press, 2006: 159
25 雍岐龙. 钢铁材料中的第二相 [M]. 北京: 冶金工业出版社, 2006: 159
26 Kim Y W, Song S W, Seo S J, et al. Development of Ti and Mo micro-alloyed hot-rolled high strength sheet steel by controlling thermomechanical controlled processing schedule [J]. Mater. Sci. Eng., 2013, A565: 430
27 Tang X C, Wang X F, Zhang Z J. Research on precipitation behavior and strengthening mechanism of low carbon bainitic high strength steel [J]. Hot Work. Technol., 2018, 47(16): 92
27 唐兴昌, 王向飞, 张志坚. 低碳贝氏体高强钢的析出行为及强化机理研究 [J]. 热加工工艺, 2018, 47(16): 92
28 Hall E O. The deformation and ageing of mild steel: III Discussion of results [J]. Proc. Phys. Soc., 1951, 64B: 747
29 Petch N J, Stables P. Delayed fracture of metals under static load [J]. Nature, 1952, 169: 842
30 Bhadeshia H K D H. Bainite in Steels: Transformations, Microstructure and Properties [M]. 2nd Ed., London: IOM Communications, 2001: 1
31 Gladman T. Precipitation hardening in metals [J]. Mater. Sci. Technol., 1999, 15: 30
32 Hu J, Du L X, Xie H, et al. Microstructure and mechanical properties of TMCP heavy plate microalloyed steel [J]. Mater. Sci. Eng., 2014, A607: 122
33 Cui J J, Zhu W T, Chen Z Y, et al. Effect of simulated cooling time on microstructure and toughness of CGHAZ in novel high-strength low-carbon construction steel [J]. Sci. Technol. Weld. Joining, 2020, 25: 169
34 Chen J, Tang S, Liu Z Y, et al. Microstructural characteristics with various cooling paths and the mechanism of embrittlement and toughening in low-carbon high performance bridge steel [J]. Mater. Sci. Eng., 2013, A559: 241
Outlines

/