Effect of Co Content on the Structure and Magnetic Properties of Melt-Spun Fe55-xCoxPt15B30 Alloys
Received date: 2016-11-02
Online published: 2017-03-13
Supported by
Supported by National Natural Science Foundation of China (Nos.51571047 and 51171034)
Fe-Pt-B nanocomposite magnets have attracted much attention because of their excellent hard magnetic properties, in which the face-centered-tetragonal FePt (L10) phase ensures high coercivity (iHc) and the Fe2B phase provides high magnetic saturation. A high iHc, however, is hard to reach at low Pt concentrations in these nanocomposite magnets. It is known that a high concentration of B favors the formation of L10 phase in Fe-Pt-B alloys with low Pt concentration, but the annealed microstructure is usually coarse-grained due to their low amorphous-forming abilities, and the magnetic properties get deteriorated. Replacement of Fe with Co is expected to enhance the amorphous-forming ability of Fe-Pt-B alloys with low Pt and high B concentrations, and to improve their magnetic properties. In this work, the structure and magnetic properties of as-quenched and annealed Fe55-xCoxPt15B30 (x=0~45, atomic fraction, %) alloys have been investigated. Melt-spun ribbons were prepared by melt spinning, followed by vacuum annealing at different temperatures. The structure and magnetic properties of the samples were examined by XRD, TEM and a vibrating sample magnetometer (VSM). The results indicate that single amorphous phase is formed in the alloys at x=15~45. After appropriate annealing, a nanocomposite structure consisting of L10 and (Fe, Co)2B phases is obtained at x=0 and 15, and an additional (Fe, Co)B phase gets formed at x=30 and 45. A fine microstructure with mean grain size of ~18 nm has been obtained in the annealed alloys with x=15~45. In these nanocomposite alloys, the best hard magnetic property with an energy product of 94.4 kJ/m3 is reached at x=15. With increasing Co content, the iHc gradually increases to a maximum value of 413.7 kA/m at x=30, and then decreases at higher Co contents, which are attributed to the change of the magnetocrystalline anisotropy in L10 phases with different c/a ratios.
Dianguo MA , Yingmin WANG , Kunio YUBUTA , Yanhui LI , Wei ZHANG . Effect of Co Content on the Structure and Magnetic Properties of Melt-Spun Fe55-xCoxPt15B30 Alloys[J]. Acta Metall Sin, 2017 , 53(5) : 609 -614 . DOI: 10.11900/0412.1961.2016.00485
| [1] | Kneller E F, Hawig R.The exchange-spring magnet: A new material principle for permanent magnets[J]. IEEE Trans. Magn., 1991, 27: 3588 |
| [2] | Skomski R, Coey J M D. Nucleation field and energy product of aligned two-phase magnets-progress towards the '1 MJ/m3' magnet[J]. IEEE Trans. Magn., 1993, 29: 2860 |
| [3] | Skomski R.Aligned two-phase magnets: permanent magnetism of the future? (invited)[J]. J. Appl. Phys., 1994, 76: 7059 |
| [4] | Coehoorn R, de Mooij D B, de Waard C. Meltspun permanent magnet materials containing Fe3B as the main phase[J]. J. Magn. Magn. Mater., 1989, 80: 101 |
| [5] | Ding J, Liu Y, Street R, et al.High magnetic performance in isotropic α-Fe+Sm2Fe17Nx[J]. J. Appl. Phys., 1994, 75: 1032 |
| [6] | Goll D, Seeger M, Kronmüller H.Magnetic and microstructural properties of nanocrystalline exchange coupled PrFeB permanent magnets[J]. J. Magn. Magn. Mater., 1998, 185: 49 |
| [7] | Watanabe K, Masumoto H.On the high-energy product Fe-Pt permanent magnet alloys[J]. Trans. Jpn. Inst. Met., 1983, 24: 627 |
| [8] | Cebollada A, Weller D, Sticht J, et al.Enhanced magneto-optical Kerr effect in spontaneously ordered FePt alloys: Quantitative agreement between theory and experiment[J]. Phys. Rev., 1994, 50B: 3419 |
| [9] | Zhang W, Louzguine D V, Inoue A.Synthesis and magnetic properties of Fe-Pt-B nanocomposite permanent magnets with low Pt concentrations[J]. Appl. Phys. Lett., 2004, 85: 4998 |
| [10] | Chang C W, Chang H W, Chiu C H, et al.Fe-B/FePt-type nanocomposite ribbons with high permanent magnetic properties[J]. J. Magn. Magn. Mater., 2005, 292: 120 |
| [11] | Zhang W, Ma D G, Li Y H, et al.Structure and magnetic properties of melt-spun Fe-Pt-B alloys with high B concentrations[J]. J. Alloys Compd., 2014, 615: S252 |
| [12] | Zhang B W, Xie H W.Effect of alloying elements on the amorphous formation and corrosion resistance of electroless Ni-P based alloys[J]. Mater. Sci. Eng., 2000, A281: 286 |
| [13] | Xu K, Ling H B, Li Q, et al.Effects of Co substitution for Fe on the glass forming ability and properties of Fe80P13C7 bulk metallic glasses[J]. Intermetallics, 2014, 51: 53 |
| [14] | Inoue A, Zhang W. Nanocrystalline Fe-Pt-B base hard magnets with high coercive force obtained from amorphous precursor [J]. J. Appl. Phys., 2005, 97: 10H308 |
| [15] | Chang C W, Chang H W, Hsieh C C, et al.Effect of B content on the magnetic properties, phase evolution, and aftereffect of nanocrystalline FeCoPtB ribbons[J]. J. Appl. Phys., 2009, 105 |
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