MICROSTRUCTURE AND CRYSTAL ORIENTATION OF THE STEADY GROWTH ZONE IN THE DIRECTION ALLY SOLIDIFIED Ni-Fe-Ga-Co MAGNETIC SHAPE MEMORY ALLOYS

  • LIU Qinghua ,
  • HUANG Yujin ,
  • LIU Jian ,
  • HU Qiaodan ,
  • LI Jianguo
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  • 1) School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240
    2) Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201

Received date: 2012-11-14

  Revised date: 2013-02-04

  Online published: 2013-04-11

Abstract

Ni-Fe-Ga-Co is a new ferromagnetic shape memory alloy system, which is promising for magnetically controlled actuators and refrigerators. In order to improve its performance, single crystal or polycrystals with preferred orientation are required. To prepare these crystals, directional solidification is the most effective way. In this work, directionally solidified Ni52Fe17Ga27Co4 ferromagnetic shape memory alloys were prepared by zone melting liquid metal cooling (ZMLMC) method. The preferred crystal orientation and microstructure in the steady growth zone under three different conditions were studied. It is indicated that under low temperature gradient and high growth velocity, the solidified crystals grew along <100> direction and primary γ phase was formed during the unstable growth; under high temperature gradient and low growth velocities, the coarse columnar crystals had uniform sizes, single martensitic phase and well-developed preferred orientation, i.e. along (222) planes of the martensite. It is deduced that the condition for stable crystal growth is high temperature gradient and low growth velocity. Under this condition, giant martensitic single-variant sets in the oriented columnar crystals were revealed, which is meaningful for potential large magnetic field-induced strain. EBSD results revealed that there was no micro-twin inside the martensitic twins and the twinning plane turned out to be (110) and (110). Additionally, magnetic domains intersecting with martensitic lamellae were observed.

Cite this article

LIU Qinghua , HUANG Yujin , LIU Jian , HU Qiaodan , LI Jianguo . MICROSTRUCTURE AND CRYSTAL ORIENTATION OF THE STEADY GROWTH ZONE IN THE DIRECTION ALLY SOLIDIFIED Ni-Fe-Ga-Co MAGNETIC SHAPE MEMORY ALLOYS[J]. Acta Metall Sin, 2013 , 29(4) : 391 -398 . DOI: 10.3724/SP.J.1037.2012.00683

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