Acta Metall Sin  1989, Vol. 25 Issue (1): 104-110    DOI:

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SYNERGISTIC EXTRACTION OF Cd(II) WITH PRIMARY AMINE N-1923 AND NEUTRAL ORGANOPHOSPHORUS REAGENTS

MA Genxiang;LI Deqian Changchun Institute of Applied Chemistry; Academia Sinica

MA Genxiang;LI Deqian Changchun Institute of Applied Chemistry; Academia Sinica. SYNERGISTIC EXTRACTION OF Cd(II) WITH PRIMARY AMINE N-1923 AND NEUTRAL ORGANOPHOSPHORUS REAGENTS. Acta Metall Sin, 1989, 25(1): 104-110.

Abstract References Related Articles Recommended Metrics Download:  PDF(472KB)  Export:  BibTeX | EndNote (RIS)       Abstract  The synergistic extraction of Cd (Ⅱ) with primary amine N--1923and neutral organophosphorus reagents (TBP, DBBP, B) from hydrochloric acidhas been investigated at μ=0.5, t=25℃. The compositions of the synergisticextraction complexes and the mechanism of the synergistic extraction have beendatermined by the methods of slope and constant mole. The synergistic extractioncomplexes with composition (RNH_3C1)_2. CdCl_2.B have been demonstrated. Thesynergistic extraction reactions and additional reaction of Cd (Ⅱ) have beenproposed as follows:CdCl_2+2RNH_3Cl_(o)+B_(o)?(RNH_3Cl)_2. CdCl_2.B_(o)(RNH_3Cl)_3. CdCl_2_(o)+B_(o)?(RNH_3Cl)_2.CdCl_2.B_(o)+RNH_3Cl_(o)In addition, the equilibrium constants and the thermodynamic functions of the syn-ergistic extraction reactions have been calculated. The IR and NMR spectra of thesynergistic extraction complexes of cadmium (Ⅱ) have been studied as well. Key words:  primary amine      neutral organophosphorus reagent      synergistic extraction      cadmium      Received:  18 January 1989      Service E-mail this article Add to citation manager E-mail Alert RSS （） Articles by authors URL:  https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y1989/V25/I1/104 1 徐光宪,王文清,吴谨光,高宏成,施鼐.萃取化学原理,上海科学技术出版社,1984． 175 2 陈建海,王文清.铀矿冶,1984;3(4) :30 3 Cattrall R W, Slater S J E. Coord Chem Rev, 1973; (11) : 227 4 Rao V M, Sastri M N. Talanta, 1980; (27) : 771 5 乐少明,李德谦,倪嘉缵.无机化学,1987;3(4) :51 6 Yu Shuchiou, Chen Chiayung, International Solvent Extraction Conference, Denver, Colorado USA, August 26-September 2, 1983: 409 7 Mooiman M B, Miller J D. Hydrometallurgy, 1986; (16) : 245 8 Yu Shuqiu, Yu Kening, Chen Jiayong. Chin J Met Sci Technol, 1987; 3 (3) : 131 9 Du Preez Rene, Preston Johns S. Afr J Chem, 1986; 39 (2) : 89 10 Sillen L G. Stability Constants of Metal-ion Complexes, Supplement No.1, The Chemical Society, Burlington House, London, W1V OBN, 1971: 180 [1] LIU Huizhou;YU Shuqiu;CHEN Jiayong Institute of Chemical Metallurgy; Academia Sinica; Beijing. MECHANISM OF EXTRACTION AND STRIPPING OF Fe(Ⅲ) WITH PRIMARY AMINE N1923 AS EXTRACTANT AND n-OCTANE AS DILUENT[J]. 金属学报, 1991, 27(4): 84-87. [2] HAN Shumin;MA Genxiang;LI Deqian Changchun Institute of Applied Chemistry; Academia Sinica. SYNERGISTIC AND ANTAGONISTIC EFFECTS OF Zn(Ⅱ) EXTRACTION WITHHEH/EHP AND PRIMARY AMINE N_(1923)[J]. 金属学报, 1991, 27(2): 83-88. [3] TANG Zhizhong;LIU Minzhi;XIAo Yaotian Chengdu University of Science and Technology Institute of Metal Research Academia Sinica; Shenyang. EFFECT OF MICROSTRUCTURES OF HIGH STRENGTH STEEL ON SUSCEPTIBILITY OF CADMIUM EMBRITTLEMENT[J]. 金属学报, 1989, 25(2): 40-44. No Suggested Reading articles found! Viewed Full text Abstract Cited   Shared      Discussed