Acta Metall Sin  1992, Vol. 28 Issue (2): 52-58    DOI:

Current Issue | Archive | Adv Search |

KINETICS OF OXYGEN EVOLUTION REACTION ON PbO_2-Ti/MNO_2 ELECTRODE AND THE ELECTROCATALYSIS

CHEN Zhenfang;JIANG Hanying;SHU Yude;CHEN Xinmin Central South University of Technology

CHEN Zhenfang;JIANG Hanying;SHU Yude;CHEN Xinmin Central South University of Technology. KINETICS OF OXYGEN EVOLUTION REACTION ON PbO_2-Ti/MNO_2 ELECTRODE AND THE ELECTROCATALYSIS. Acta Metall Sin, 1992, 28(2): 52-58.

Abstract References Related Articles Recommended Metrics Download:  PDF(552KB)  Export:  BibTeX | EndNote (RIS)       Abstract  The kinetics of oxygen evolution reaction (OER) on PbO_2--Ti/ MnO_2 elec-trode has been studied using galvanistatic technique. In terms of kinetic parameters, the reac-tion path of OER is proposed. The electrocatalytic activity of lead dioxide and manganese dioxide has been discussed according to the theory of molecular orbit and quantum chemistry calculation. It is concluded that the electrocatalytic activity of manganese dioxide is higher than that of lead dioxid, which is in agreement with the experimental result. Key words:  manganese dioxide      lead dioxide      oxygen evolution reaction      electrocatalysis      Received:  18 February 1992      Service E-mail this article Add to citation manager E-mail Alert RSS （） Articles by authors URL:  https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y1992/V28/I2/52 1 陈振方,蒋汉瀛,舒余德,陈新民.有色金属(冶炼部分),1989;(3) :16 2 陈振方,蒋汉瀛,舒余德,陈新民.中南矿冶学院学报,1991;22(2) 3 杨建军,舒余德,蒋汉瀛.中南矿冶学院学报,1987;18(1) :98 4 Morita M, Iwakura C, Tamura H. Electrochim Acta, 1977; 22: 325 5 陈振方.中南工业大学博士学位论文,1991年 6 陈振方,蒋汉瀛,舒余德,陈新民.化工冶金,1991;12:122 7 朱荣昭,徐正炎,金世雄,王振武.科学记录,1958;新辑2:439 8 Bockris J O'M, Huq AKNS. Proc R Soc London, 1956; A237: 277 9 Ruetschi P, Delahay P. J Chem Phys, 1955; 23(3) : 556 10 Boden F P, Rided E. Proc R Soc London, 1928; A120: 59 11 Bockris J O'M, Otagawa T. J Electrocheni Soc, 1984; 131(2) : 290 [1] ZHONG Xiaocong, JIANG Liangxing, LÜ Xiaojun, LAI Yanqing, LI Jie, LIU Yexiang. EFFECTS OF CHLORIDE ION ON THE ELECTRO- CHEMICAL BEHAVIOR OF Pb-Ag-RE ALLOY ANODE[J]. 金属学报, 2015, 51(3): 378-384. [2] ZHAO Yue, HONG Bo,FAN Louzhen. ELECTRODEPOSITION OF PtRu/MWCNTs AND PtRuNi/MWCNTs AND THEIR PERFORMANCE IN DIRECT METHANOL FUEL CELLS[J]. 金属学报, 2013, 49(6): 699-706. No Suggested Reading articles found! Viewed Full text Abstract Cited   Shared      Discussed