Acta Metall Sin  1994, Vol. 30 Issue (21): 413-419    DOI:

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MICROSTRUCTURES OF CRYSTALLITES IN NANOCRYSTALLINE Ni-P ALLOYS

SUI Manling (Northeastern University;Internattonal Centre for Materials Physics.Chinese Academy of Sciences; Shenyang);LU Ke (National Laboratoryfor RSA Insti tute of Metal Research; Chinese Academy of Sciences;Shenyang)

SUI Manling (Northeastern University;Internattonal Centre for Materials Physics.Chinese Academy of Sciences; Shenyang);LU Ke (National Laboratoryfor RSA Insti tute of Metal Research; Chinese Academy of Sciences;Shenyang). MICROSTRUCTURES OF CRYSTALLITES IN NANOCRYSTALLINE Ni-P ALLOYS. Acta Metall Sin, 1994, 30(21): 413-419.

Abstract References Related Articles Recommended Metrics Download:  PDF(483KB)  Export:  BibTeX | EndNote (RIS)       Abstract  Different grain-sized nanocrystalline Ni-P alloy samples with two crystalline phases of a Ni solid solution and a Ni_3P compound have been synthesized by the crystallization method. By means of the X-ray diffraction technique, variations of the lattice parameters of these two nanophases with the grain size were determined. It was found that the values of the lattice parameters for the two nanophases obviously deviated from the equilibrium data for the corresponding perfect crystals. Analysis of the experimental results indicated that the P concentration in the Ni(P) solution nanophase was much enhanced, being about 10－1 5 times as much as the equilibrium solubility, and a highly supersaturated Ni(P)solid solution formed in the nanophase samples. For the Ni_3P nanophase, an evident lattice distortion was detected, and the lattice distortion of the Ni_3P nanophase increases with a reduction in grain size, which might be oringinated from an enhancement of the vacancies in the nanometer-sized crystallites. Key words:  nanocrystalline materials      crystallization method      highly supersaturated solid solution. lattice distortion      Service E-mail this article Add to citation manager E-mail Alert RSS （） Articles by authors URL:  https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y1994/V30/I21/413 1GleiterH．ProgMaterSci,1989,33:2232SiegelRW．In:FujitaFEed．,PhysicsofNewMaterials,Springer-Verlag:Heidelberg,19923LuK,WangJT,WeiWD．JApplPhys,1991:69:522;ScrMetallMater．1990:24:23194SuiML,LuK,HeYZ．PhilosMag,1991:B63:9335DonnayJDH,OndikHMeds．,CrystalDataDeterminativeTables(3rdEd),NBSJCPDS,1973;26LuK,LuckR,PredelB．ZMetallkd,1993;48:7407CahnRW,HaasenP．PhyscalMetallurgy(3rdEd),Amsterdam:ElsevierSciPubl,1983:9808MutscheleT,KirchheimR．ScriplaMetall,1987;2l:2819HahnH,HoflerHJ,AverbackRS．Proc．DIMETA-88,198810TakamuraJ-I．In:CahnRWed．,PhyscalMetaliurgy,Amsterdam:North-Holland,1965:68111LuiXD,LuK,HuZQ．NanostructuredMater,1993:2:58112董振富,卢柯,魏文铎．金属学报,1993:印刷中13GaffetE,HarmelinM．JLess-commMetals,1991:157:201z [1] Xiaoyan SONG. CELLULAR AUTOMATON SIMULATION STUDY ON NANOGRAIN GROWTH BASED ON THERMODYNAMIC FUNCTIONS OF NANOCRYSTALLINE[J]. 金属学报, 2008, 44(4): 495-500 . [2] SUI Manling(Department of Materials Science and Engineering; Northeastern University; Shenyang 110006)Coerespondent: SUI Manling; Fax:(024)3890488; Tel: (024)3893000-7740; E-mail: misui mail.neu.edu.cn. AN INVESTIGATUIB ON THE RECOVERY BEHMIORS OF THE LATTICE DISTORTIONS IN AN Ni_3P/Ni NANOPHASE MATERIAL[J]. 金属学报, 1998, 34(6): 650-654. [3] LI Bolin;ZHU Min; LI Long; LUO Kanchang;LI Zuxin (South China University of Technology; Guangzhou 510641)(Manuscript received 1996-03-19; in revised form 1996-07-15). HARDENNING AND SOFTENNING EFFECTS OF Fe-Cu NANOCRYSTALLINE SUPERSATURATED SOLID SOLUTION FORMED BY MECHANICAL ALLOYING[J]. 金属学报, 1997, 33(4): 420-426. [4] LU Ke; ZHOU Fei (State Key Laboratory for RSA; Institute of Metal Research;Chinese Academy of Sciences; Shenyang 110015). RECENT RESEARCH PROGRESS ON NANOCRYSTALLINE MATERIALS[J]. 金属学报, 1997, 33(1): 99-106. [5] CHEN Da(Shanghai Jiaotong University; Shanghai;200030). A DIFFUSION MODEL IN NANOCRYSTALLINE MATERIALS[J]. 金属学报, 1995, 31(8): 340-345. [6] PING Dehai; LI Douxing; YE Hengqiang(Laboratory of Atomic Imaging of Solids;Institute of Metal Research; Chinese Academy of Sciences; Shenyang 110015). WU Xijun(Zhejiang University; Hangzhou 310014) (Manuscript received 94-06-30). ^MICROSTRUCTURE OF NANOCRYSTALLINE MATERIALS[J]. 金属学报, 1995, 31(2): 79-84. [7] LU Ke; LIU Xuedong;ZHANG Haoyue; HU Zhuangqi(State Key Laboratory forRSA; Institute of Metal Research; Chinese Academy of Sciences; Shenyang 110015)(Manuscript received 94-05-10). LATTICE EXPANSION IN NANOCRYSTALLINE PURE Ni[J]. 金属学报, 1995, 31(2): 74-78. [8] SUI Manling (Northeastern University; International Centre for Materials Physics;Chinese Academy of Sciences; Shenyang);LU Ke (Institute of Meial Research; Chinese Academy of Sciences; Shenyang). INTERFACIAL EXCESS VOLUME IN NANOCRYSTALLINE Ni-P ALLOYS WITH DIFFERENT GRAIN SIZES[J]. 金属学报, 1994, 30(15): 121-125. [9] LU Ke (National Key Laboratory for RSA; Institurte of Metal Research;Chinese Academy of Sciences;Shenyang). PHASE TRANSFORMATION FROM AN AMORPHOUS ALLOY INTO NANOCRYSTALLINE MATERIALS[J]. 金属学报, 1994, 30(13): 1-21. No Suggested Reading articles found! Viewed Full text Abstract Cited   Shared      Discussed