Mg含量对再生Al-7Si-0.4Fe合金富铁相形态演变及力学性能的影响

  • 杨冬阳 ,
  • 宋东福 ,
  • 赵愈亮 ,
  • 杨雄 ,
  • 陈菲 ,
  • 张卫文
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  • 1 广东省科学院新材料研究所 广东省金属强韧化技术与应用重点实验室  广州 510650

    2 华南理工大学 国家金属材料近净成型工程技术研究中心  广州 510640

    3 东莞理工学院 机械工程学院  东莞 523808 

    4 广东天丞车轮科技有限公司  江门 529259

收稿日期: 2025-04-07

  修回日期: 2025-06-08

  网络出版日期: 2025-07-17

基金资助

广东省自然科学基金项目;国家自然科学基金;广东省基金面上项目;清远市科技计划项目;上海同步辐射设施BL13W1线站机时

Effect of Mg content on morphology evolution and mechanical properties of Fe-rich phase in regenerated Al-7Si-0.4Fe alloy

  • YANG Dong-Yang ,
  • SONG Dong-Fu ,
  • ZHAO Yu-Liang ,
  • YANG Xiong ,
  • CHEN Fei ,
  • ZHANG Wei-Wen
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  • 1 Guangdong Provincial Key Laboratory of Metal Toughening Technology and Application, Institute of New Materials, Guangdong Academy of Sciences, Guangzhou 510650, China

    2 School of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou 510640, China

    3 School of Mechanical Engineering, Dongguan University of Technology, Dongguan 523808, China 

    4 China Wheel (TAISHAN) Co. Ltd., Jiangmen  529259, China

Received date: 2025-04-07

  Revised date: 2025-06-08

  Online published: 2025-07-17

摘要

为了实现再生Al-Si-Mg合金的高强韧化,本工作采用SEM、TEM、DSC、热力学计算和同步辐射X射线断层扫描等手段,研究了Mg含量对Al-7Si-0.4Fe-xMg合金组织和性能的影响。结果表明,随着Mg含量的增加,初生α-Al的二次枝晶间距减小,富Fe相的二维形貌由细小针状逐渐转变为粗针状、汉字状和块状,而三维形貌由复杂的珊瑚状逐渐转变为独立的片状和多分支结构。随着Mg含量增加,富Fe相的类型则由单一的β-Fe相转变成β-Fe与π-Fe的混合类型,π-Fe相的数量、体积分数和球形度显著增加,而β-Fe相的数量和体积分数逐渐降低。当Mg含量为0.7%时,β-Fe的数量和体积分数较0.1%Mg合金降低了95.3%和73.6%,但等效直径增加73%。DSC结果显示Mg含量的增加降低了共晶硅的形成温度,促进了β-Fe相的粗化,同时促进了β-Fe相与熔体的包晶反应,形成了大量小尺寸和高球形度的π-Fe相。随着Mg含量的增加,合金的抗拉和屈服强度逐渐提高,而塑性逐渐降低。Al–7Si–0.4Fe–0.7Mg合金的抗拉强度、屈服强度和塑性分别达到197 MPa、135 MPa和10.9%,其抗拉强度和屈服强度较不含Mg合金分别提高了36.8%和137.0%,但伸长率降低了51.1%。β-Fe相的粗化加速了裂纹的扩展,对合金塑性造成了不利的影响。

本文引用格式

杨冬阳 , 宋东福 , 赵愈亮 , 杨雄 , 陈菲 , 张卫文 . Mg含量对再生Al-7Si-0.4Fe合金富铁相形态演变及力学性能的影响[J]. 金属学报, 0 : 0 -0 . DOI: 10.11900/0412.1961.2025.00102

Abstract

The influence of Mg content on the microstructure and properties of recycled Al-7Si alloys using scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermodynamic software Jmat Pro, and synchrotron radiation X-ray computed tomography (SRXCT). The results show that as Mg content increases, the secondary dendrite arm spacing of the primary α-Al phase decreases. The morphology of the Fe-rich phase evolves from fine needle-like to coarse needle-like, Chinese-script, and granular forms, accompanied by a transition from a single β-Fe phase to a mixed structure of β-Fe and π-Fe phases. The three-dimensional (3D) morphology of the Fe-rich phase transforms from complex coral-like to independent flake-like and multi-branched structures. Simultaneously, the number, volume fraction, and sphericity of the π-Fe phase significantly increase. In contrast, the number and volume fraction of the β-Fe phase decrease by 95.3% and 73.6%, respectively, despite a 73% increase in its equivalent diameter. The increase of Mg content lowers the eutectic silicon formation temperature, promoting the coarsening of the β-Fe phase. When the Mg content is 0.4% and above, the β-Fe phase undergoes a peritectic reaction with the melt, resulting in the formation of a large number of small-sized, highly spherical π-Fe phases, which significantly reduces the volume fraction of the β-Fe phase. The 0.7Mg alloy demonstrates substantial improvements in tensile and yield strengths, increasing by 36.8% and 137%, respectively, compared to the Mg-free alloy. However, its elongation decreases by 51.1%. The formation of large-sized β-Fe phases intensifies crack propagation, leading to a marked reduction in the plasticity of high-Mg Al-7Si alloys. This study revealed the influence mechanisms of Mg content on the type and morphology of Fe-rich phases in Al-Si alloys with high Fe content.
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