研究论文

热处理对电弧定向能量沉积Al-Zn-Mg-Cu-Sc合金显微组织与力学性能的影响

  • 秦凤明 ,
  • 李亚菲 ,
  • 李亚杰 ,
  • 赵晓东 ,
  • 梁上上 ,
  • 陈金秋
展开
  • 太原科技大学 材料科学与工程学院 太原 030024
秦凤明,女,1988年生,副教授,博士
李亚杰,liyajie1207@126.com,主要从事金属增材制造方面的研究

收稿日期: 2025-02-24

  修回日期: 2025-05-19

  网络出版日期: 2025-06-25

基金资助

中央引导地方科技发展资金项目(YDZJSX20231A045);中央引导地方科技发展资金项目(YDZJSX2024D053);太原科技大学科研启动资金项目(20-232074);太原科技大学科研启动资金项目(20212011);太原科技大学科研启动资金项目(20222063);山西省自然科学基金项目(202303021212216)

Effect of Heat Treatment on the Microstructural Characteristics and Mechanical Properties of Al-Zn-Mg-Cu-Sc Alloy Prepared via Wire-Arc Directed Energy Deposition Process

  • QIN Fengming ,
  • LI Yafei ,
  • LI Yajie ,
  • ZHAO Xiaodong ,
  • LIANG Shangshang ,
  • CHEN Jinqiu
Expand
  • School of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, China

Received date: 2025-02-24

  Revised date: 2025-05-19

  Online published: 2025-06-25

Supported by

Central Government Guides Local Funds for Science and Technology Development(YDZJSX20231A045);Central Government Guides Local Funds for Science and Technology Development(YDZJSX2024D053);Start-up Fund for Scientific Research of Taiyuan University of Science and Technology(20-232074);Start-up Fund for Scientific Research of Taiyuan University of Science and Technology(20212011);Start-up Fund for Scientific Research of Taiyuan University of Science and Technology(20222063);Natural Science Foundation of Shanxi Province(202303021212216)

摘要

研究热处理对电弧定向能量沉积Al-Zn-Mg-Cu-Sc合金显微组织与力学性能的影响,对于优化该合金增材制造工艺、提升其综合性能具有重要意义。本工作以自制7075-Sc焊丝为原材料,采用冷金属过渡(CMT)工艺制备了无裂纹的Al-Zn-Mg-Cu-Sc厚壁合金构件。结果表明,沉积态合金由细小的等轴晶组成,平均尺寸约14 μm,晶界有连续第二相分布。在470 ℃、4 h的固溶工艺下,第二相溶解70.2%,残余第二相主要为Al7Cu2Fe和Al2Mg3Zn3。在120 ℃进行人工时效后,力学性能测试结果表明最佳时效时间为18 h。经过470 ℃、4 h固溶和120 ℃、18 h时效处理后,合金的屈服强度、抗拉强度、伸长率分别为475.2 MPa、542.1 MPa和5.2%,与沉积态合金相比分别提高了52.8%、36.5%和36.8%。

本文引用格式

秦凤明 , 李亚菲 , 李亚杰 , 赵晓东 , 梁上上 , 陈金秋 . 热处理对电弧定向能量沉积Al-Zn-Mg-Cu-Sc合金显微组织与力学性能的影响[J]. 金属学报, 2025 , 61(10) : 1542 -1554 . DOI: 10.11900/0412.1961.2025.00048

Abstract

Wire-arc directed energy deposition (DED) shows considerable potential for fabricating structural components from Al-Zn-Mg-Cu-Sc alloys. However, its layer-by-layer deposition nature leads to continuous grain boundary second-phase networks, grain coarsening, elemental microsegregation, and residual stress accumulation during solidification of 7075-Sc aluminum alloys, significantly compromising their mechanical properties and industrial viability. As a precipitation-strengthened alloy, 7075 can be optimized through heat treatment to control the morphology and distribution of secondary phases, thereby improving mechanical performance. Nevertheless, the inhomogeneous as-deposited microstructure proves difficult to fully homogenize using conventional heat treatment, necessitating precise temperature control and tailored aging schedules for effective thermal processing. In this study, crack-free, thick-walled Al-Zn-Mg-Cu-Sc alloy components were fabricated using custom 7075-Sc welding wire and the cold metal transfer process. Microstructural analysis revealed that the as-deposited alloy consists of fine equiaxed grains with an average diameter of approximately 14 μm and a continuous grain boundary second-phase distribution. Solution treatment at 470 oC results in a markedly reduced dissolution rate of the secondary phases over time, with a 4 h duration identified as optimal. Under this condition, 70.2% of the secondary phases are dissolved; the remaining phases are predominantly Al7Cu2Fe and Al2Mg3Zn3. Subsequent artificial aging at 120 oC showed that an aging time of 18 h yields optimal mechanical properties. Following the combined solution and aging treatments, the alloy exhibited a yield strength of 475.2 MPa, tensile strength of 542.1 MPa, and elongation of 5.2%. These values represent increases of 52.8%, 36.5%, and 36.8%, respectively, compared to the as-deposited alloy.

参考文献

[1] Williams J C, Starke E A. Progress in structural materials for aerospace systems [J]. Acta Mater., 2003, 51: 5775
[2] Panigrahi S K, Jayaganthan R. Development of ultrafine grained high strength age hardenable Al 7075 alloy by cryorolling [J]. Mater. Des., 2011, 32: 3150
[3] Dursun T, Soutis C. Recent developments in advanced aircraft aluminium alloys [J]. Mater. Des. (1980-2015), 2014, 56: 862
[4] DebRoy T, Wei H L, Zuback J S, et al. Additive manufacturing of metallic components—Process, structure and properties [J]. Prog. Mater. Sci., 2018, 92: 112
[5] Zhang J L, Song B, Wei Q S, et al. A review of selective laser melting of aluminum alloys: Processing, microstructure, property and developing trends [J]. J. Mater. Sci. Technol., 2019, 35: 270
[6] Oko O E, Mbakaan C, Barki E. Experimental investigation of the effect of processing parameters on densification, microstructure and hardness of selective laser melted 7075 aluminium alloy [J]. Mater. Res. Express, 2020, 7: 036512
[7] Bartsch H, Kühne R, Citarelli S, et al. Fatigue analysis of wire arc additive manufactured (3D printed) components with unmilled surface [J]. Structures, 2021, 31: 576
[8] Wu B T, Pan Z X, Ding D H, et al. A review of the wire arc additive manufacturing of metals: Properties, defects and quality improvement [J]. J. Manuf. Processes, 2018, 35: 127
[9] Zhao Y N, Guo Q Y, Liu C X, et al. Effects of subsequent heat treatment on microstructure and high-temperature mechanical properties of laser 3D printed GH4099 alloy [J]. Acta Metall. Sin., 2025, 61: 165
  赵亚楠, 郭乾应, 刘晨曦 等. 后续热处理对激光3D打印GH4099合金微观组织和高温力学性能的影响 [J] 金属学报, 2025, 61: 165
[10] Xia X C, Zhang E K, Ding J, et al. Research progress on laser cladding of refractory high-entropy alloy coatings [J]. Acta Metall. Sin., 2025, 61: 59
  夏兴川, 张恩宽, 丁 俭 等. 激光熔覆难熔高熵合金涂层研究进展 [J] 金属学报, 2025, 61: 59
[11] Yu Z L, Yuan T, Xu M, et al. Microstructure and mechanical properties of Al-Zn-Mg-Cu alloy fabricated by wire?+?arc additive manufacturing [J]. J. Manuf. Processes, 2021, 62: 430
[12] Wang L W, Wu T, Wang D L, et al. A novel heterogeneous multi-wire indirect arc directed energy deposition for in-situ synthesis Al-Zn-Mg-Cu alloy: Process, microstructure and mechanical properties [J]. Addit. Manuf., 2023, 72: 103639
[13] Cai X Y, Xia Y H, Dong B L, et al. Effects of deposition paramaters on the microstructure evolution of wire arc additive manufactured Al-Zn-Mg-Cu alloy [J]. J. Mater. Res. Technol., 2023, 26: 1572
[14] Ren L L, Gu H M, Wang W, et al. Effect of Sc content on the microstructure and properties of Al-Mg-Sc alloys deposited by wire arc additive manufacturing [J]. Met. Mater. Int., 2021, 27: 68
[15] Xia Y H, Cai X Y, Dong B L, et al. Wire arc additive manufacturing of Al-Mg-Sc alloy: An analysis of the effect of Sc on microstructure and mechanical properties [J]. Mater. Charact., 2023, 203: 113116
[16] Dong B L, Xia Y H, Cai X Y, et al. Addition of Sc in wire-based directed energy deposition of Al-Mg-Zn-Cu alloy: Microalloying to refine grains and improve mechanical properties [J]. Addit. Manuf., 2023, 67: 103494
[17] Klein T, Schnall M, Gomes B, et al. Wire-arc additive manufacturing of a novel high-performance Al-Zn-Mg-Cu alloy: Processing, characterization and feasibility demonstration [J]. Addit. Manuf., 2021, 37: 101663
[18] Miao J L, Chen J Q, Ting X, et al. Effect of solution treatment on porosity, tensile properties and fatigue resistance of Al-Cu alloy fabricated by wire arc additive manufacturing [J]. J. Mater. Res. Technol., 2024, 28: 1864
[19] Hao S, Guo X P, Cui J Y, et al. Study on the solid solution temperature of achieving ultra-high strength in wire-arc additive manufactured Al-Zn-Mg-Cu aluminum alloy [J]. Mater. Charact., 2023, 201: 112975
[20] Fu R, Lu W J, Guo Y L, et al. Achieving high strength-ductility of Al-Zn-Mg-Cu alloys via hot-wire arc additive manufacturing enabled by strengthening precipitates [J]. Addit. Manuf., 2022, 58: 103042
[21] Zou X L, Yan H, Chen X H. Evolution of second phases and mechanical properties of 7075 Al alloy processed by solution heat treatment [J]. Trans. Nonferrous Met. Soc. China, 2017, 27: 2146
[22] Dai Y X, Yan L M, Hao J P. Microstructure and intermetallic phase evolution during the homogenization of an Al-Zn-Mg-Cu-Zr-Nd aluminum alloy [J]. Adv. Eng. Mater., 2023, 25: 2201288
[23] Cheng S X, Liu F C, Xu Y, et al. Effects of arc oscillation on microstructure and mechanical properties of AZ31 magnesium alloy prepared by CMT wire-arc directed energy deposition [J]. Mater. Sci. Eng., 2023, A864: 144539
[24] Bi J, Lei Z L, Chen Y B, et al. Microstructure and mechanical properties of a novel Sc and Zr modified 7075 aluminum alloy prepared by selective laser melting [J]. Mater. Sci. Eng., 2019, A768: 138478
[25] Yu J, Kim J Y. Effects of residual S on Kirkendall void formation at Cu/Sn-3.5Ag solder joints [J]. Acta Mater., 2008, 56: 5514
[26] Toda H, Hidaka T, Kobayashi M, et al. Growth behavior of hydrogen micropores in aluminum alloys during high-temperature exposure [J]. Acta Mater., 2009, 57: 2277
[27] Lin B, Wang K, Liu F, et al. An intrinsic correlation between driving force and energy barrier upon grain boundary migration [J]. J. Mater. Sci. Technol., 2018, 34: 1359
[28] Feng J, Ye B, Zuo L J, et al. Effects of Zr, Ti and Sc additions on the microstructure and mechanical properties of Al-0.4Cu-0.14Si-0.05Mg-0.2Fe alloys [J]. J. Mater. Sci. Technol., 2018, 34: 2316
[29] Marquis E A, Seidman D N. Nanoscale structural evolution of Al3Sc precipitates in Al(Sc) alloys [J]. Acta Mater., 2001, 49: 1909
[30] Chung T F, Yang Y L, Huang B M, et al. Transmission electron microscopy investigation of separated nucleation and in-situ nucleation in AA7050 aluminium alloy [J]. Acta Mater., 2018, 149: 377
[31] Dong B L, Cai X Y, Xia Y H, et al. Step solution treatment of a wire-arc directed energy deposited Al-Zn-Mg-Cu alloy: Defects suppression and mechanical property improvement [J]. Virtual Phys. Prototyp., 2024, 19: e2382170
[32] Yang W H, Zhang Y L, Yang H F, et al. Effect of non-isothermal retrogression and re-aging treatment on microstructure evolution and mechanical properties of Al-Zn-Mg-Cu alloy [J]. J. Mater. Res. Technol., 2024, 31: 1728
[33] Liu Y, Jiang D M, Li W J. The effect of multistage ageing on microstructure and mechanical properties of 7050 alloy [J]. J. Alloys Compd., 2016, 671: 408
[34] Wang Z, Wang S G, Zhang C C, et al. Effect of post-weld heat treatment on microstructure and mechanical properties of 7055 aluminum alloy electron beam welded joint [J]. Mater. Res. Express, 2020, 7: 066528
[35] Scheiber D, Jechtl T, Svoboda J, et al. On solute depletion zones along grain boundaries during segregation [J]. Acta Mater., 2020, 182: 100
[36] Ogura T, Hirosawa S, Cerezo A, et al. Atom probe tomography of nanoscale microstructures within precipitate free zones in Al-Zn-Mg(-Ag) alloys [J]. Acta Mater., 2010, 58: 5714
[37] Zhao H, De Geuser F, Kwiatkowski da Silva A, et al. Segregation assisted grain boundary precipitation in a model Al-Zn-Mg-Cu alloy [J]. Acta Mater., 2018, 156: 318
[38] Krug M E, Mao Z G, Seidman D N, et al. Comparison between dislocation dynamics model predictions and experiments in precipitation-strengthened Al-Li-Sc alloys [J]. Acta Mater., 2014, 79: 382
[39] Li Y J, Ma C R, Qin F M, et al. The microstructure and mechanical properties of 316L austenitic stainless steel prepared by forge and laser melting deposition [J]. Mater. Sci. Eng., 2023, A870: 144820
[40] Liu D H, Wu D J, Ma G Y, et al. Effect of post-deposition heat treatment on laser-TIG hybrid additive manufactured Al-Cu alloy [J]. Virtual Phys. Prototyp., 2020, 15: 445
[41] Ma K K, Wen H M, Hu T, et al. Mechanical behavior and strengthening mechanisms in ultrafine grain precipitation-strengthened aluminum alloy [J]. Acta Mater., 2014, 62: 141
[42] Booth-Morrison C, Dunand D C, Seidman D N. Coarsening resistance at 400 oC of precipitation-strengthened Al-Zr-Sc-Er alloys [J]. Acta Mater., 2011, 59: 7029
文章导航

/