Liquid metal embrittlement (LME) refers to the
phenomenon wherein the ductility of a solid metal markedly decreases upon
contact with a liquid metal. This issue is a critical constraint in the
development of lead-cooled fast reactors (LFRs). The commonly accepted
mechanism involves the adsorption of liquid Pb–Bi atoms at the crack tips of
solid metals, which alters the bonding interactions, lowers the critical stress
for rupture, and ultimately causes embrittlement. 9Cr ferritic/martensitic
steels are considered potential candidate materials for LFRs. In this study,
the slow strain rate tensile behavior of P92 steel was investigated in liquid
lead–bismuth eutectic (LBE), focusing on the effects of temperature (150–500 °C),
strain rate (4 × 10
−7–4 × 10
−4 s
−1), and dissolved oxygen concentration (from 10
−10 mass
fraction to oxygen saturation). The results showed that no significant
embrittlement occurred in oxygen-saturated conditions. In contrast, high
embrittlement sensitivity was observed in oxygen-deficient LBE at low strain
rates. At high oxygen concentrations, a protective oxide film forms on the
surface, effectively isolating the solid metal from liquid LBE, thereby
preventing embrittlement. However, this protective effect diminishes
significantly if the integrity of the oxide film is compromised. High strain
rates promote mechanical damage to the oxide layer, which facilitates LME. In
oxygen-poor LBE, the protective oxide film barely forms, leading to direct
exposure of the steel matrix to the liquid LBE. This exposure causes
dissolution corrosion, where pits formed by metal dissolution act as crack
initiation sites owing to localized stress concentration, promoting LME.
Interestingly, excessively high strain rates can accelerate crack
propagation to such an extent that the crack tip
advances before sufficient adsorption of Pb/Bi atoms occurs. This rapid
progression inhibits the embrittling action of the liquid metal, thereby
reducing the LME effect under low dissolved oxygen conditions.