研究论文

Mn / N比对22%CrNi型双相不锈钢多道次焊接热影响区组织和力学性能的影响

  • 郭孟雨 ,
  • 杨银辉 ,
  • 高梓豪 ,
  • 曹建春 ,
  • 吴诗裕 ,
  • 陈晓雨
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  • 昆明理工大学 材料科学与工程学院 昆明 650093
郭孟雨,女,2000年生,硕士生
杨银辉,yyhyanr@sina.com,主要从事不锈钢材料设计、热变形、焊接性及强韧化等研究

收稿日期: 2024-07-04

  修回日期: 2024-11-07

  网络出版日期: 2024-12-23

基金资助

国家自然科学基金项目(51861019)

Effect of Mn / N Ratio on the Microstructure and Mechanical Properties of Multi-Pass Welding HAZ of 22%Cr Low Nickel Type Duplex Stainless Steel

  • GUO Mengyu ,
  • YANG Yinhui ,
  • GAO Zihao ,
  • CAO Jianchun ,
  • WU Shiyu ,
  • CHEN Xiaoyu
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  • School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China
YANG Yinhui, professor, Tel: 13518726308, E-mail: yyhyanr@sina.com

Received date: 2024-07-04

  Revised date: 2024-11-07

  Online published: 2024-12-23

Supported by

National Natural Science Foundation of China(51861019)

摘要

在焊接热循环过程中,Mn / N质量比对节Ni型双相不锈钢(DSS)的转变奥氏体形成、析出相形成和两相(δγ相)比例有较大影响,探究其对多道次焊接热影响区(HAZ)组织转变的影响有利于改善HAZ的综合力学性能。本工作基于2205 DSS对比研究了Mn / N比对DSS固溶态和多道次焊接热影响区(HAZ)组织演变和力学性能的影响。结果表明,高的N含量(Mn / N比为3.77)促进HAZ形成了高体积分数(58.7%)的部分转变奥氏体(PTA),其抗拉强度和延伸率分别为836 MPa和39.5%,具有高的强塑性。Mn / N比增至17.80时,HAZ中δ/γ相界上形成胞状Cr2N,魏氏体奥氏体(WA)数量增多导致相界附近铁素体位错墙的形成,使延伸率相对固溶态明显降低。高Mn / N比(65.91) DSS的HAZ中晶界转变奥氏体(GBA)数量先增后减,晶内奥氏体(IGA)和WA数量增多,抑制了Cr2N析出且强塑性降低。与2205 DSS (Mn / N比为3.06)相比,较低Mn / N比DSS焊接HAZ冲击断口以脆性断裂为主。当Mn / N比为3.77时,高N固溶和Cr2N析出对奥氏体相的共同强化增大了DSS中HAZ两相硬度差,且大尺寸(Cr, Mn)O夹杂也一定程度促进了裂纹萌生,使其冲击功降至24.2 J。高Mn / N比则会导致HAZ中形成较多的GBA和WA分割细化铁素体,形成细小IGA而阻碍裂纹扩展,且少量细小σ相的析出提高了铁素体硬度,降低两相硬度差,冲击功增加至134.8 J。

本文引用格式

郭孟雨 , 杨银辉 , 高梓豪 , 曹建春 , 吴诗裕 , 陈晓雨 . Mn / N比对22%CrNi型双相不锈钢多道次焊接热影响区组织和力学性能的影响[J]. 金属学报, 2026 , 62(7) : 1257 -1272 . DOI: 10.11900/0412.1961.2024.00225

Abstract

Variations in the Mn / N ratio greatly affect the formation of reformed austenite and precipitation and two-phase ratio in duplex stainless steel (DSS) during the welding thermal cycle. Therefore, investigating the influence of the Mn / N ratio on the multipass welding heat-affected zone (HAZ) microstructure is beneficial for enhancing the comprehensive mechanical properties of the HAZ of low-nickel-type DSS thick plates. This study comparatively investigated the effect of Mn / N ratio on the microstructure evolution and mechanical properties of DSS in the solution-treated and multi-pass welded HAZ, with 2205 DSS as a reference. The higher nitrogen content (Mn / N ratio = 3.77) resulted in substantial partial transformed austenite formation with a high volume fraction of 58.7%, yielding a tensile strength of 836 MPa and an elongation of 39.5%, indicating its high strength and plasticity. As the Mn / N ratio increases to 17.80, an increase in the Widmanstätten austenite (WA) amount caused cellular Cr2N formation at the δ/γ phase interfaces and dislocation walls in ferrite for HAZ, considerably decreasing elongation compared to the solid solution state. For DSS with a high Mn / N ratio of 65.91, the grain boundary austenite (GBA) amount initially increased and then decreased, while the intragranular austenite (IGA) and WA amounts increased in HAZ, inhibiting Cr2N precipitation and reducing ductility and strength. Compared with the 2205 DSS (Mn / N ratio = 3.06), the fracture surfaces of DSS with lower Mn / N ratios exhibited brittle fracture. The combined strengthening effect of the high-nitrogen solid solution and Cr2N precipitation on the austenite phase increased the hardness difference between the two phases in the HAZ of the DSS with Mn / N ratio of 3.77. In addition, the formation of some large (Cr, Mn)O inclusions promoted crack initiation to some extent, lowering the impact energy to 24.2 J. High Mn / N ratio led to more GBA and WA segmented ferrite refinement, as well as the formation of small amounts of IGA, which hindered crack propagation. Moreover, the precipitation of a small amount of the σ phase increased the hardness of ferrite, reduced the hardness difference between the two phases, and increased the impact energy to 134.8 J.

参考文献

[1] Guo L Q, Zhao X M, Li M, et al. Annealing effects on the microstructure and magnetic domain structures of duplex stainless steel studied by in situ technique [J]. Appl. Surf. Sci., 2012, 259: 213
[2] Ramkumar K D, Mishra D, Raj B G, et al. Effect of optimal weld parameters in the microstructure and mechanical properties of autogeneous gas tungsten arc weldments of super-duplex stainless steel UNS S32750 [J]. Mater. Des., 2015, 66: 356
[3] Yang R Z, Zhai R Z, Ren S F, et al. Evolution and healing mechanism of 1Cr22Mn16N high nitrogen austenitic stainless steel interface microstructure during plastic deformation bonding [J]. Acta Metall. Sin., 2024, 60: 915
  杨瑞泽, 翟汝宗, 任少飞 等. 1Cr22Mn16N高氮奥氏体不锈钢塑性变形连接中界面组织演化及愈合机制 [J]. 金属学报, 2024, 60: 915
[4] Luo H, Dong C F, Xiao K, et al. Characterization of passive film on 2205 duplex stainless steel in sodium thiosulphate solution [J]. Appl. Surf. Sci., 2011, 258: 631
[5] Su S, Han P, Yang S W, et al. Crystallographic understanding of the effect of Ni content on the hardenability of high-strength low-alloy steel [J]. Acta Metall. Sin., 2024, 60: 789
  苏 帅, 韩 鹏, 杨善武 等. Ni含量对高强度低合金钢淬透性影响的晶体学认识 [J]. 金属学报, 2024, 60: 789
[6] Su Y S, Yang Y H, Cao J C, et al. Research on hot working behavior of low-nickel duplex stainless steel 2101 [J]. Acta Metall. Sin., 2018, 54: 485
  苏煜森, 杨银辉, 曹建春 等. 节Ni型2101双相不锈钢的高温热加工行为研究 [J]. 金属学报, 2018, 54: 485
[7] Garzón C M, Ramirez A J. Growth kinetics of secondary austenite in the welding microstructure of a UNS S32304 duplex stainless steel [J]. Acta Mater., 2006, 54: 3321
[8] Le J J, Liu L, Liu F, et al. Interdiffusion kinetics of the intermetallic coatings on AZ91D magnesium alloy formed in molten salts at lower temperatures [J]. J. Alloys Compd., 2014, 610: 173
[9] Ramirez A J, Lippold J C, Brandi S D. The relationship between chromium nitride and secondary austenite precipitation in duplex stainless steels [J]. Metall. Mater. Trans., 2003, 34A: 1575
[10] Tan H, Wang Z Y, Jiang Y M, et al. Influence of welding thermal cycles on microstructure and pitting corrosion resistance of 2304 duplex stainless steels [J]. Corros. Sci., 2012, 55: 368
[11] Hertzman S, Brolund B, Ferreira P J. An experimental and theoretical study of heat-affected zone austenite reformation in three duplex stainless steels [J]. Metall. Mater. Trans., 1997, 28A: 277
[12] Wessman S, Selleby M. Evaluation of austenite reformation in duplex stainless steel weld metal using computational thermodynamics [J]. Weld. World, 2014, 58: 217
[13] Sun Y T, Wu X Y, Wu X, et al. Influence of multi-pass welding on the microstructure evolution and corrosion resistance of a super duplex stainless steel [J]. Int. J. Electrochem. Sci., 2016, 11: 9666
[14] Zhang Z Q, Jing H Y, Xu L Y, et al. Investigation on microstructure and impact toughness of different zones in duplex stainless steel welding joint [J]. J. Mater. Eng. Perform., 2017, 26: 134
[15] Zhang Z Q, Jing H Y, Xu L Y, et al. Influence of microstructure and elemental partitioning on pitting corrosion resistance of duplex stainless steel welding joints [J]. Appl. Surf. Sci., 2017, 394: 297
[16] Ramirez A J, Brandi S D, Lippold J C. Secondary austenite and chromium nitride precipitation in simulated heat affected zones of duplex stainless steels [J]. Sci. Technol. Weld. Join., 2004, 9: 301
[17] Varbai B, Adonyi Y, Baumer R, et al. Weldability of duplex stainless steels—Thermal cycle and nitrogen effects [J]. Weld J., 2019, 98: 78
[18] Wang Y, Wang Y F, Wang Z H. Enhancing yield strength of high nitrogen austenitic stainless steel [J]. J. Constr. Steel Res., 2021, 187: 106927
[19] Hosseini V A, Wessman S, Hurtig K, et al. Nitrogen loss and effects on microstructure in multipass TIG welding of a super duplex stainless steel [J]. Mater. Des., 2016, 98: 88
[20] Han Z C, Wang S G, Hu J H, et al. Effect of welding process parameters on structure and property of 2205 duplex stainless steel weld joint [J]. J. Mater. Eng., 2008, (8): 48
  韩志诚, 王少刚, 胡经洪 等. 焊接工艺对2205双相不锈钢接头组织与性能的影响 [J]. 材料工程, 2008, (8): 48
[21] Yang J, Dong H G, Xia Y Q, et al. Carbide precipitates and mechanical properties of medium Mn steel joint with metal inert gas welding [J]. J. Mater. Sci. Technol., 2021, 75: 48
[22] Wang H H, Meng L, Luo Q, et al. Superior cryogenic toughness of high-Mn austenitic steel by welding thermal cycles: The role of grain boundary evolution [J]. Mater. Sci. Eng., 2020, A788: 139573
[23] García-García V, Mejía I, Reyes-Calderón F. Experimental and FEM study of Ti-containing TWIP steel weldability [J]. J. Mater. Process. Technol., 2018, 261: 107
[24] Han K, Yoo J, Lee B, et al. Hot ductility and hot cracking susceptibility of Ti-modified austenitic high Mn steel weld HAZ [J]. Mater. Chem. Phys., 2016, 184: 118
[25] Yoo J, Kim B, Park Y, et al. Microstructural evolution and solidification cracking susceptibility of Fe-18Mn-0.6C-xAl steel welds [J]. J. Mater. Sci., 2015, 50: 279
[26] Wang J, Uggowitzer P J, Magdowski R, et al. Nickel-free duplex stainless steels [J]. Scr. Mater., 1998, 40: 123
[27] Taiwade R V, Patil A P, Ghugal R D, et al. Effect of welding passes on heat affected zone and tensile properties of AISI 304 stainless steel and chrome-manganese austenitic stainless steel [J]. ISIJ Int., 2013, 53: 102
[28] Lavenstein S, Gu Y J, Madisetti D, et al. The heterogeneity of persistent slip band nucleation and evolution in metals at the micrometer scale [J]. Science, 2020, 370: eabb2690
[29] Xie X F, Jiang W C, Liu R M, et al. Evolution of phase ratio and its effect on residual stress for 2205 duplex stainless steel multipass welded joints by thermo-metallurgical-mechanical model [J]. Int. J. Press. Vessels Pip., 2024, 211: 105283
[30] Chu J H, Nian Y, Zhang L Q, et al. Formation, evolution and remove behavior of manganese-containing inclusions in medium/high manganese steels [J]. J. Mater. Res. Technol., 2023, 22: 1505
[31] Pandey C, Mahapatra M M, Kumar P, et al. Microstructure and mechanical property relationship for different heat treatment and hydrogen level in multi-pass welded P91 steel joint [J]. J. Manuf. Process., 2017, 28: 220
[32] Chen T H, Yang J R. Microstructural characterization of simulated heat affected zone in a nitrogen-containing 2205 duplex stainless steel [J]. Mater. Sci. Eng., 2002, A338: 166
[33] Kellai A, Lounis A, Kahla S, et al. Effect of root pass filler metal on microstructure and mechanical properties in the multi-pass welding of duplex stainless steels [J]. Int. J. Adv. Manuf. Technol., 2018, 95: 3215
[34] Eghlimi A, Shamanian M, Raeissi K. Effect of current type on microstructure and corrosion resistance of super duplex stainless steel claddings produced by the gas tungsten arc welding process [J]. Surf. Coat. Technol., 2014, 244: 45
[35] Haghdadi N, Breen A J, Chen H, et al. New insights into the character of austenite-ferrite boundaries in an additively manufactured duplex stainless steel [J]. Scr. Mater., 2024, 245: 116049
[36] Jang Y H, Kim S S, Lee J H. Effect of different Mn contents on tensile and corrosion behavior of CD4MCU cast duplex stainless steels [J]. Mater. Sci. Eng., 2005, A369: 302
[37] Ferreira V H M M, Coury F G, De Araujo Santana D, et al. Novel high nitrogen austenitic stainless steels: From high-throughput screening to experimental validation and properties relationship [J]. J. Mater. Res. Technol., 2024, 30: 640
[38] Yang Y H, Pan X Y. Effect of Mn / N ratio on microstructure and mechanical behavior of simulated welding heat affected zone in 22% Cr lean duplex stainless steel [J]. Mater. Sci. Eng., 2022, A835: 142676
[39] Krawczynska A T, Brynk T, Gierlotka S, et al. Mechanical properties of nanostructured 316LVM stainless steel annealed under pressure [J]. Mech. Mater., 2013, 767: 25
[40] Kartik B, Veerababu R, Sundararaman M, et al. Satyanarayana. Effect of high temperature ageing on microstructure and mechanical properties of a nickel-free high nitrogen austenitic stainless steel [J]. Mater. Sci. Eng., 2015, A642: 288
[41] Lee T H, Kim S J, Takaki S. Time-temperature-precipitation characteristics of high-nitrogen austenitic Fe-18Cr-18Mn-2Mo-0.9N steel [J]. Metall. Mater. Trans., 2006, 37A: 3445
[42] Zhou J Q, Han X P. Effects of ultrafine grains on fracture toughness of nanocrystalline materials [J]. J. Eng. Mech., 2014, 31: 229
  周剑秋, 韩雪平. 超细晶粒对纳晶材料断裂韧性的影响 [J]. 工程力学, 2014, 31: 229
[43] Zhang W Y, Jiang W C, Li H J, et al. Effect of tensile overload on fatigue crack behavior of 2205 duplex stainless steel: Experiment and finite element simulation [J]. Int. J. Fatigue., 2019, 128: 105199
[44] Cui C, Weng Z J, Gu K X, et al. The strengthening role of post-welded cryogenic treatment on the performance and microstructure of 304 austenitic stainless steel weldments [J]. J. Mater. Res. Technol., 2024, 29: 5576
[45] Mohammed R, Reddy G, Rao K. Microstructure and pitting corrosion of shielded metal arc welded high nitrogen stainless steel [J]. Def. Technol., 2015, 11: 237
[46] Whitcroft C S, Martin J W. The influence of chromium content on the precipitation of γ' (ordered NI3Ti) in some austenitic steels [J]. Mater. Charact., 1997, 39: 91
[47] Chen J H, Cao R. Micromechanism of cleavage fracture of weld metals [J]. Acta Metall. Sin., 2017, 53: 1427
  陈剑虹, 曹 睿. 焊缝金属解理断裂微观机理 [J]. 金属学报, 2017, 53: 1427
[48] Zhang Z Q, Jing H Y, Xu L Y, et al. Investigation on microstructure evolution and properties of duplex stainless steel joint multi-pass welded by using different methods [J]. Mater. Des., 2016, 109: 670
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