晶粒尺寸与晶体取向对CrCoNi中熵合金孪晶界疲劳开裂行为的影响
收稿日期: 2024-06-24
修回日期: 2024-08-09
网络出版日期: 2024-11-12
基金资助
国家自然科学基金项目(52371101);辽宁省兴辽英才计划项目(XLYC2203105)
Effects of Grain Size and Crystallographic Orientation on Fatigue Cracking at Twin Boundaries in CrCoNi Medium-Entropy Alloy
Received date: 2024-06-24
Revised date: 2024-08-09
Online published: 2024-11-12
Supported by
National Natural Science Foundation of China(52371101);Liaoning Revitalization Talents Pro-gram(XLYC2203105)
CrCoNi中熵合金拥有超越大多数fcc多主元合金和传统合金的优异综合力学性能,具有巨大的发展潜力以及广泛的应用前景。为确保该合金的长期稳定且安全使用,有必要充分探索其疲劳特性和损伤机理。细晶强化是该合金的主要强化方式,明确不同晶粒尺寸下孪晶界疲劳的开裂规律对减少沿晶疲劳开裂、提高材料疲劳性能具有重要意义。本工作采用滑移形貌法研究了两种晶粒尺寸CrCoNi中熵合金在低周疲劳条件下的孪晶界疲劳开裂行为。结果表明,对于任意给定的晶粒尺寸,CrCoNi中熵合金从滑移带开裂到孪晶界开裂之间的转变随着基体与孪晶之间Schmid因子差的增加而变化;随着孪晶界两侧滑移带Schmid因子差的增加,孪晶界面开裂变得更加容易。孪晶界开裂所需的Schmid因子差随晶粒尺寸增加而减小;随着晶粒尺寸增加,较小Schmid因子差使孪晶界附近产生较大的位错塞积,导致孪晶界损伤加剧而易疲劳开裂。
关键词: CrCoNi中熵合金; 疲劳开裂; 孪晶界; 晶粒尺寸; 滑移带
王玉洁 , 李琳琳 , 张振军 , 张哲峰 . 晶粒尺寸与晶体取向对CrCoNi中熵合金孪晶界疲劳开裂行为的影响[J]. 金属学报, 2026 , 62(7) : 1246 -1256 . DOI: 10.11900/0412.1961.2024.00211
The CrCoNi medium-entropy alloy is known to demonstrate superior comprehensive mechanical properties relative to most fcc multiple-principal-elemental alloys. To ensure the long-term stability and safety of this alloy in practical applications, its fatigue characteristics and damage mechanisms must be thoroughly explored. Grain refinement is a crucial method for strengthening this alloy, and the effect of grain size on twin-boundary (TB) fatigue cracking must be clarified to reduce the intergranular fatigue cracks and improve fatigue performance. By conducting SEM measurements, the fatigue cracking behaviors at TBs in a CrCoNi medium-entropy alloy with two different grain sizes were systematically studied employing the slipping morphology method under low-cycle fatigue tests. The surface roughness around the TBs of the fatigued samples was characterized via laser confocal microscopy and white-light interference microscopy to quantify variations in the surface damage levels. Irrespective of grain size, the transition from slip-band cracking to TB cracking was observed to vary with the increasing difference in the Schmid factors (DSF) between the matrix and twin. Further, the propensity for TB cracking was facilitated by the escalation of DSF. Moreover, the magnitude of the required DSF for TB cracking was influenced by the grain size. The requirement of DSF for TB cracking decreased with increasing grain size. With the increase in grain size, even the minimal DSF is expected to result in the significant pilling up of dislocations near the TBs, thereby worsening the damage and rendering these boundaries favorable sites for fatigue cracking.
Key words: CrCoNi medium-entropy alloy; fatigue cracking; twin boundary; grain size; slip band
| [1] | Yeh J W, Chen S K, Lin S J, et al. Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes [J]. Adv. Eng. Mater., 2004, 6: 299 |
| [2] | George E P, Raabe D, Ritchie R O. High-entropy alloys [J]. Nat. Rev. Mater., 2019, 4: 515 |
| [3] | Cantor B, Chang I T H, Knight P, et al. Microstructural development in equiatomic multicomponent alloys [J]. Mater. Sci. Eng., 2004, A375-377: 213 |
| [4] | Cantor B. Multicomponent and high entropy alloys [J]. Entropy, 2014, 16: 4749 |
| [5] | Otto F, Dlouhy A, Somsen C, et al. The influences of temperature and microstructure on the tensile properties of a CoCrFeMnNi high-entropy alloy [J]. Acta Mater., 2013, 61: 5743 |
| [6] | Gali A, George E P. Tensile properties of high- and medium-entropy alloys [J]. Intermetallics, 2013, 39: 74 |
| [7] | Gludovatz B, Hohenwarter A, Catoor D, et al. A fracture-resistant high-entropy alloy for cryogenic applications [J]. Science, 2014, 345: 1153 |
| [8] | Gludovatz B, Hohenwarter A, Thurston K V S, et al. Exceptional damage-tolerance of a medium-entropy alloy CrCoNi at cryogenic temperatures [J]. Nat. Commun., 2016, 7: 10602 |
| [9] | Laplanche G, Kostka A, Reinhart C, et al. Reasons for the superior mechanical properties of medium-entropy CrCoNi compared to high-entropy CrMnFeCoNi [J]. Acta Mater., 2017, 128: 292 |
| [10] | Zhang Z J, Sheng H W, Wang Z J, et al. Dislocation mechanisms and 3D twin architectures generate exceptional strength-ductility-toughness combination in CrCoNi medium-entropy alloy [J]. Nat. Commun., 2017, 8: 14390 |
| [11] | Heczko M, Mazánová V, Slone C E, et al. Role of deformation twinning in fatigue of CrCoNi medium-entropy alloy at room temperature [J]. Scr. Mater., 2021, 202: 113985 |
| [12] | Miao J, Slone C E, Smith T M, et al. The evolution of the deformation substructure in a Ni-Co-Cr equiatomic solid solution alloy [J]. Acta Mater., 2017, 132: 35 |
| [13] | Chu S F, Zhang F, Chen D K, et al. Atomic-scale in situ observations of reversible phase transformation assisted twinning in a CrCoNi medium-entropy alloy [J]. Nano Lett., 2024, 24: 3624 |
| [14] | Wu Z, Bei H, Pharr G M, et al. Temperature dependence of the mechanical properties of equiatomic solid solution alloys with face-centered cubic crystal structures [J]. Acta Mater., 2014, 81: 428 |
| [15] | Suresh S. Fatigue of Materials [M]. 2nd Ed., Cambridge: Cambridge University Press, 1998: 156 |
| [16] | Zhang Z F, Wang Z G. Grain boundary effects on cyclic deformation and fatigue damage [J]. Prog. Mater. Sci., 2008, 53: 1025 |
| [17] | Liu W, Wang Z G, Xia Y B. Mechanism of initiation and propagation of intergranular cracks during fatigue process [J]. Ordnance Mater. Sci. Eng., 1990, (5): 1 |
| 刘 蔚, 王中光, 夏月波. 疲劳过程中沿晶裂纹萌生与扩展的机理 [J]. 兵器材料科学与工程, 1990, (5): 1 | |
| [18] | Mughrabi H. Microstructural mechanisms of cyclic deformation, fatigue crack initiation and early crack growth [J]. Philos. Trans. Roy. Soc., 2015, 373A: 20140132 |
| [19] | Zhang Z J, Li L L, Zhang P, et al. Fatigue cracking at twin boundary: Effect of dislocation reactions [J]. Appl. Phys. Lett., 2012, 101: 011907 |
| [20] | Lu L, Shen Y F, Chen X H, et al. Ultrahigh strength and high electrical conductivity in copper [J]. Science, 2004, 304: 422 |
| [21] | Lu K, Lu L, Suresh S. Strengthening materials by engineering coherent internal boundaries at the nanoscale [J]. Science, 2009, 324: 349 |
| [22] | Li L L, Zhang Z J, Zhang P, et al. Higher fatigue cracking resistance of twin boundaries than grain boundaries in Cu bicrystals [J]. Scr. Mater., 2011, 65: 505 |
| [23] | Sangid M D, Maier H J, Sehitoglu H. A physically based fatigue model for prediction of crack initiation from persistent slip bands in polycrystals [J]. Acta Mater., 2011, 59: 328 |
| [24] | Li L L, Zhang Z J, Zhang P, et al. Controllable fatigue cracking mechanisms of copper bicrystals with a coherent twin boundary [J]. Nat. Commun., 2014, 5: 3536 |
| [25] | Wang A G, An X H, Gu J, et al. Effect of grain size on fatigue cracking at twin boundaries in a CoCrFeMnNi high-entropy alloy [J]. J. Mater. Sci. Technol., 2020, 39: 1 |
| [26] | Zhang Z J, Zhang P, Li L L, et al. Fatigue cracking at twin boundaries: Effects of crystallographic orientation and stacking fault energy [J]. Acta Mater., 2012, 60: 3113 |
| [27] | Zhang P, Zhang Z J, Li L L, et al. Twin boundary: Stronger or weaker interface to resist fatigue cracking? [J]. Scr. Mater., 2012, 66: 854 |
| [28] | Li L L, Zhang Z J, Zhang P, et al. A review on the fatigue cracking of twin boundaries: Crystallographic orientation and stacking fault energy [J]. Prog. Mater. Sci., 2023, 131: 101011 |
| [29] | Zhang Z J. Investigations on the effects of stacking fault energy (SFE) on the strength-ductility cooperation and fatigue behaviors of single phase Cu-Zn alloys [D]. Shenyang: Institute of Metal Research, Chinese Academy of Sciences, 2013 |
| 张振军. 层错能对单相铜锌合金强度塑性匹配及疲劳行为影响研究 [D]. 沈阳: 中国科学院金属研究所, 2013 | |
| [30] | Thompson A W, Backofen W A. The effect of grain size on fatigue [J]. Acta Metall., 1971, 19: 597 |
| [31] | Wang Y J, Yu T, Wang Z G, et al. Low cycle fatigue behaviors of CrCoNi medium-entropy alloy with different grain sizes [J]. Int. J. Fatigue, 2024, 180: 108105 |
| [32] | Lu K J, Chauhan A, Walter M, et al. Superior low-cycle fatigue properties of CoCrNi compared to CoCrFeMnNi [J]. Scr. Mater., 2021, 194: 113667 |
| [33] | Zhang P. Investigations on tension, fatigue, fracture, strength and hardness of single-phase Cu-Zn alloys [D]. Shenyang: Institute of Metal Research, Chinese Academy of Sciences, 2011 |
| 张 鹏. 单相铜锌合金的拉伸、疲劳、断裂、强度与硬度研究 [D]. 沈阳: 中国科学院金属研究所, 2011 | |
| [34] | Antolovich S D, Armstrong R W. Plastic strain localization in metals: Origins and consequences [J]. Prog. Mater. Sci., 2014, 59: 1 |
| [35] | Figueroa J C, Laird C. Crack initiation mechanisms in copper polycrystals cycled under constant strain amplitudes and in step tests [J]. Mater. Sci. Eng., 1983, 60: 45 |
| [36] | Tanaka K, Mura T. A dislocation model for fatigue crack initiation [J]. J. Appl. Mech., 1981, 48: 97 |
| [37] | Sangid M D, Maier H J, Sehitoglu H. The role of grain boundaries on fatigue crack initiation—An energy approach [J]. Int. J. Plast., 2011, 27: 801 |
| [38] | Essmann U, G?sele U, Mughrabi H. A model of extrusions and intrusions in fatigued metals I. Point-defect production and the growth of extrusions [J]. Philos. Mag., 1981, 44A: 405 |
| [39] | D?rr G, Blochwitz C. Microcracks in fatigued FCC polycrystals by interaction between persistent slip bands and grain boundaries [J]. Cryst. Res. Technol., 1987, 22: 113 |
| [40] | Kobayashi S, Inomata T, Kobayashi H, et al. Effects of grain boundary- and triple junction-character on intergranular fatigue crack nucleation in polycrystalline aluminum [J]. J. Mater. Sci., 2008, 43: 3792 |
| [41] | Zhang Z F, Wang Z G. Comparison of fatigue cracking possibility along large- and low-angle grain boundaries [J]. Mater. Sci. Eng., 2000, A284: 285 |
| [42] | Thompson A L. The influence of grain and tlin boundaries in fatigue cracking [J]. Acta Metall., 1972, 20: 1085 |
| [43] | Liang F L, Laird C. Control of intergranular fatigue cracking by slip homogeneity in copper ii: Effect of loading mode [J]. Mater. Sci. Eng., 1989, A117: 103 |
| [44] | Hall E O. The deformation and ageing of mild steel: III Discussion of results [J]. Proc. Phys. Soc., 1951, 64B: 747 |
| [45] | Petch N J. The cleavage strengh of polycrystals [J]. J. Iron Steel Int., 1953, 174: 25 |
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