研究论文

低碳低合金钢焊缝熔覆金属针状铁素体的回火稳定性

  • 胡富昇 ,
  • 成林 ,
  • 侯廷平 ,
  • 程石 ,
  • 宋峰雨 ,
  • 吴开明
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  • 1.武汉科技大学 高性能钢铁材料及其应用省部共建协同创新中心 武汉 430081
    2.武汉科技大学 冶金工业过程系统科学湖北省重点实验室 武汉 430081
    3.武汉科技大学 国际钢铁研究院 武汉 430081
    4.龙岩学院 物理与机电工程学院 龙岩 364012
胡富昇,男,1988年生,硕士生
吴开明,wukaiming@wust.edu.cn,主要从事钢铁材料相变及应用性能的研究

收稿日期: 2024-05-07

  修回日期: 2024-05-31

  网络出版日期: 2024-10-31

基金资助

国家自然科学基金项目(U20A20279);国家重点研发计划项目(2022YFB4201500);山东泰山产业领军人才工程蓝色人才专项项目(2020007)

High-Temperature Stability of Acicular Ferrite in a Low-Carbon Low-Alloy Steel Weld Metal

  • HU Fusheng ,
  • CHENG Lin ,
  • HOU Tingping ,
  • CHENG Shi ,
  • SONG Fengyu ,
  • WU Kaiming
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  • 1.State Collaborative Innovation Center for Advanced Steels, Wuhan University of Science and Technology, Wuhan 430081, China
    2.Hubei Province Key Laboratory of Systems Science on Metallurgical Processing, Wuhan University of Science and Technology, Wuhan 430081, China
    3.International Research Institute for Steel Technology, Wuhan University of Science and Technology, Wuhan 430081, China
    4.College of Physics, Mechanical and Electrical Engineering, Longyan University, Longyan 364012, China
WU Kaiming, professor, Tel: 13100610041, E-mail: wukaiming@wust.edu.cn

Received date: 2024-05-07

  Revised date: 2024-05-31

  Online published: 2024-10-31

Supported by

National Natural Science Foundation of China(U20A20279);Key Research and Development Project of China(2022YFB4201500);Shandong Taishan Industrial Leading Talent Project Blue Talent Special Foundation Project(2020007)

摘要

长时间回火(时效)后保持钢材的优异力学性能是全球性技术挑战。本工作对低合金高强钢焊缝金属中的针状铁素体在高温下进行长时间回火,通过OM、SEM-EBSD、HRTEM、冲击和拉伸测试等手段研究其显微组织演变及其对力学性能的影响,同时从材料动力学角度对实验结果进行了分析和讨论。结果表明,经580~700 ℃、1~12 h不同时间回火后,针状铁素体的位错密度及组织尺寸均未发生明显变化,析出相密度随着回火温度的升高而增加,钉扎了晶界和位错,阻碍了针状铁素体的粗化,提高了析出强化作用。640~700 ℃回火时,抗拉强度增加明显且在700 ℃左右时达到峰值。材料动力学分析结果表明,形核率-温度曲线和析出-温度-时间曲线的鼻温都在700 ℃左右,析出相在640~730 ℃时大量形成,析出强化作用明显增强。高密度位错和Mo的添加提高了碳化物形核率且细化了TiC,Mo的添加还提高了动力学曲线NrT和PPT的“鼻温”并使析出开始时间提前,改善了针状铁素体的高温回火力学性能。

本文引用格式

胡富昇 , 成林 , 侯廷平 , 程石 , 宋峰雨 , 吴开明 . 低碳低合金钢焊缝熔覆金属针状铁素体的回火稳定性[J]. 金属学报, 2026 , 62(4) : 599 -610 . DOI: 10.11900/0412.1961.2024.00135

Abstract

Maintaining steel’s high mechanical properties after a long period of tempering (aging) is a worldwide challenge. This study investigates the microstructure and mechanical properties of a low-carbon, low-alloy steel weld metal consisting of acicular ferrite (AF) using OM, SEM, EBSD, TEM, and impact and tensile tests. The precipitation kinetics is used to analyze and discuss the experimental results to study the microstructure evolution and its effect on the mechanical properties of the low-carbon, low-alloy steel weld metal consisting of AF after tempering for a long time in a high-temperature environment. The results show that after tempering at 580-700 oC for 1-12 h, the dislocation density and size of the AF showed no noticeable change, indicating that the microstructure of the AF was very stable after high-temperature, long-time tempering. Precipitates increase along with the increase in tempering temperature, pin grain boundaries and dislocations, hinder the coarsening of AF, and thus increasing the precipitation strengthening effect. The tensile strength increased at 640-700 oC and peaked at about 700 oC. The kinetics curves and calculations indicate that the “nose” temperatures of both the nucleation rate-temperature (NrT) and precipitation-temperature-time (PPT) curves are about 700 oC; precipitation occurs in large amounts at about 640-730 ℃ and thus provides a strong precipitation strengthening effect. High-density dislocation and Mo addition increase the nucleation rate and refine the precipitates of TiC. Adding Mo increases the “nose” temperature of the NrT and PTT curves and brings forward the precipitation start time, thus improving the high-temperature tempering mechanical properties of AF.

参考文献

[1] Liang W, Geng R M, Zhi J G, et al. Oxide metallurgy technology in high strength steel: A review [J]. Materials, 2022, 15: 1350
[2] Jorge J C F, De Souza L F G, Mendes M C, et al. Microstructure characterization and its relationship with impact toughness of C-Mn and high strength low alloy steel weld metals—A review [J]. J. Mater. Res. Technol., 2021, 10: 471
[3] Babu S S. The mechanism of acicular ferrite in weld deposits [J]. Curr. Opin. Solid State Mater. Sci., 2004, 8: 267
[4] Loder D, Michelic S K, Bernhard C. Acicular ferrite formation and its influencing factors—A review [J]. J. Mater. Sci. Res., 2017, 6: 24
[5] Lee T K, Kim H J, Kang B Y, et al. Effect of inclusion size on the nucleation of acicular ferrite in welds [J]. ISIJ Int., 2000, 40: 1260
[6] Wu K M. Three-dimensional analysis of acicular ferrite in a low-carbon steel containing titanium [J]. Scr. Mater., 2006, 54: 569
[7] Wu K M, Li Z G. Intragranular ferrite and microstructure control in low carbon microalloyed steels [J]. J. Iron Steel Res., 2007, 19(10): 1
  吴开明, 李自刚. 低碳微合金钢中的晶内铁素体及组织控制 [J]. 钢铁研究学报, 2007, 19(10): 1
[8] Abson D J. Acicular ferrite and bainite in C-Mn and low-alloy steel arc weld metals [J]. Sci. Technol. Weld. Joining, 2018, 23: 635
[9] Xu S S, Zhao Y, Chen D, et al. Nanoscale precipitation and its influence on strengthening mechanisms in an ultra-high strength low-carbon steel [J]. Int. J. Plast., 2019, 113: 99
[10] Goto H, Miyazawa K I, Tanaka K. Effect of oxygen content on size distribution of oxides in steel [J]. ISIJ Int., 1995, 35: 286
[11] Wang Z M, Zhu X Y, Liu W Q. Influence of Mo on tempering precipitation in Nb-Mo-V microalloyed steels [J]. Chin. J. Mater. Res., 2010, 24: 217
  王泽民, 朱晓勇, 刘文庆. Mo对Nb-Mo-V微合金化钢中碳化物析出的影响 [J]. 材料研究学报, 2010, 24: 217
[12] Chen C Y, Yen H W, Kao F H, et al. Precipitation hardening of high-strength low-alloy steels by nanometer-sized carbides [J]. Mater. Sci. Eng., 2009, A499: 162
[13] Bardella L. A comparison between crystal and isotropic strain gradient plasticity theories with accent on the role of the plastic spin [J]. Eur. J. Mech., 2009, 28A: 638
[14] Dutta B, Palmiere E J, Sellars C M. Modelling the kinetics of strain induced precipitation in Nb microalloyed steels [J]. Acta Mater., 2001, 49: 785
[15] Liu W J. A new theory and kinetic modeling of strain-induced precipitation of Nb(CN) in microalloyed austenite [J]. Metall. Mater. Trans., 1995, 26A: 1641
[16] Adrian H. Thermodynamic model for precipitation of carbonitrides in high strength low alloy steels containing up to three microalloying elements with or without additions of aluminium [J]. Mater. Sci. Technol., 1992, 8: 406
[17] Zheng W, Wu Z H, Li G Q, et al. Effect of Al content on the characteristics of inclusions in Al-Ti complex deoxidized steel with calcium treatment [J]. ISIJ Int., 2014, 54: 1755
[18] Yen H W, Chen C Y, Wang T Y, et al. Orientation relationship transition of nanometre sized interphase precipitated TiC carbides in Ti bearing steel [J]. Mater. Sci. Technol., 2010, 26: 421
[19] Zhao D W, Cao J C, Zhou X L, et al. Study on first principle of complex precipitation of titanium and molybdenum in micro-alloyed steel [J]. Hot Work. Technol., 2012, 41(8): 35
  赵冬伟, 曹建春, 周晓龙 等. 微合金钢中钛钼复合析出的第一性原理研究 [J]. 热加工工艺, 2012, 41(8): 35
[20] Jang J H, Lee C H, Heo Y U, et al. Stability of (Ti, M)C (M = Nb, V, Mo and W) carbide in steels using first-principles calculations [J]. Acta Mater., 2012, 60: 208
[21] Cahn J W. Nucleation on dislocations [J]. Acta Metall., 1957, 5: 169
[22] Perrard F, Deschamps A, Maugis P. Modelling the precipitation of NbC on dislocations in α-Fe [J]. Acta Mater., 2007, 55: 1255
[23] Perez M, Courtois E, Acevedo D, et al. Precipitation of niobium carbonitrides in ferrite: Chemical composition measurements and thermodynamic modelling [J]. Philos. Mag. Lett., 2007, 87: 645
[24] Park S H, Yue S, Jonas J J. Continuous-cooling-precipitation kinetics of Nb(CN) in high-strength low-alloy steels [J]. Metall. Trans., 1992, 23A: 1641
[25] Avrami M. Kinetics of phase change. I General theory [J]. J. Chem. Phys., 1939, 7: 1103
[26] Avrami M. Kinetics of phase change. II Transformation-time relations for random distribution of nuclei [J]. J. Chem. Phys., 1940, 8: 212
[27] Wang Z Q, Yong Q L, Sun X J, et al. An analytical model for the kinetics of strain-induced precipitation in titanium micro-alloyed steels [J]. ISIJ Int., 2012, 52: 1661
[28] Wu Q L, Yang C D, Xue F, et al. Effect of Mo addition on the microstructure and wear resistance of in situ TiC/Al composite [J]. Mater. Des., 2011, 32: 4999
[29] Zhu A W, Starke E A. Strengthening effect of unshearable particles of finite size: A computer experimental study [J]. Acta Mater., 1999, 47: 3263
[30] Monnet G. Constitutive flow equation for cast austenite-ferrite stainless steels [J]. Metall. Mater. Trans., 2023, 54A: 53
[31] Alexandrov D V. Kinetics of particle coarsening with allowance for Ostwald ripening and coagulation [J]. J. Phys.: Condens. Matter, 2016, 28: 035102
[32] Brailsford A D, Wynblatt P. The dependence of Ostwald ripening kinetics on particle volume fraction [J]. Acta Metall., 1979, 27: 489
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