固溶后处理对GH4706合金时效析出相演化及力学性能的影响
收稿日期: 2024-03-24
修回日期: 2024-08-04
网络出版日期: 2024-09-26
基金资助
国家重点研发计划项目(2022YFB3705102)
Effects of Solution Post-Treatment on Precipitation Evolution During Aging of GH4706 Alloy and Its Mechanical Properties
Received date: 2024-03-24
Revised date: 2024-08-04
Online published: 2024-09-26
Supported by
National Key Research and Development Program of China(2022YFB3705102)
针对大尺寸涡轮盘固溶后处理冷却速率受限的问题,以直径1500 mm的GH4706合金盘锻件为对象,研究了980 ℃固溶4 h后分别进行空冷(AA)、炉冷至825 ℃稳定化处理后空冷(FSA)、炉冷至825 ℃后空冷(FA)和炉冷至825 ℃后石棉冷却(FAs) 4种固溶后处理对合金时效析出相演化特征及力学性能的影响。结果表明,降低980~825 ℃间的冷速,促进了晶界η相的析出和长大,消耗了Ni、Ti元素,抑制了大尺寸η相周围γ'/γ"相析出,形成了胞状组织;降低825~600 ℃间的冷速,显著加速了γ'/γ"相长大呈立方状;FSA、FA和FAs处理后胞状组织体积分数分别为4.1%、1.0%和1.8%。AA和FA处理基本不影响合金的室温拉伸性能,FSA处理小幅降低了合金的拉伸塑性,FAs处理大幅损害了合金的室温屈服强度。胞状组织加速了室温冲击时合金中裂纹的形成和扩展,造成FSA处理合金冲击韧性较AA处理降低64%。但胞状组织可阻碍合金650 ℃持久实验过程中裂纹扩展并抑制微孔长大聚集,提高了合金的持久寿命。FAs处理时由于大尺寸γ'/γ"相降低了合金强度,从而缩短持久寿命。FA处理使合金析出了适量的胞状组织,显著提高了合金持久寿命,同时保持良好的室温拉伸和冲击性能,具有优异的综合性能。
王冲 , 王磊 , 段然 , 田强 , 黄烁 , 赵光普 . 固溶后处理对GH4706合金时效析出相演化及力学性能的影响[J]. 金属学报, 2025 , 61(11) : 1638 -1652 . DOI: 10.11900/0412.1961.2024.00090
GH4706 alloy is used for industrial gas turbine disks owing to its excellent properties, including high creep resistance, tensile strength, toughness, and microstructural stability up to approximately 650 oC. However, the increasing weight and size of large turbine disks have limited the cooling rate following the solution treatment, which hinders the control of the microstructure and mechanical properties of large GH4706 alloy disks. Herein, four solution post-treatments were conducted on a 1500-mm-diameter disk manufactured from GH4706 alloy after being treated at 980 oC for 4 h: air cooling + air cooling (AA), furnace cooling to 825 oC and stabilization treatment followed by air cooling (FSA), furnace cooling to 825 oC followed by air cooling (FA), and furnace cooling to 825 oC followed by asbestos cooling (FAs). The evolution of precipitates during aging (including for γ'/γ" coprecipitation and η phase) and their effects on mechanical properties were analyzed. Results indicated that reducing the cooling rate from 980 oC to 825 oC promoted the precipitation and growth of the η phase, leading to Ni and Ti consumptions. This inhibited γ'/γ" coprecipitation around the large η phase, thereby favoring the formation of a cellular microstructure. Further reduction in cooling rate from 825 oC to 600 oC substantially accelerated the growth of γ'/γ" coprecipitates into cubic forms. The volume fractions of the cellular microstructure in the FSA, FA, and FAs treatments were 4.1%, 1.0%, and 1.8%, respectively. The AA and FA treatments had negligible effects on the tensile properties of GH4706 alloy at room temperature; meanwhile, the FSA treatment slightly decreased tensile ductility. The FAs treatment led to a notable reduction in yield strength at room temperature. In impact testing at room temperature, the cellular microstructure accelerated crack initiation and propagation, resulting in a 64% lower impact toughness of GH4706 alloy for the FSA treatment compared to that for the AA treatment. However, during stress rupture testing at 650 oC, the cellular microstructure effectively hindered crack propagation and the growth and aggregation of micropores, thereby extending the rupture life. However, the FAs treatment reduced the rupture life due to strength loss caused by the large γ'/γ" coprecipitates. The FA treatment fostered an optimal level of cellular microstructure, thereby increasing the rupture life while maintaining excellent tensile and impact properties at room temperature, demonstrating remarkable overall mechanical properties.
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