铁素体系耐热钢焊接热影响区相变行为的CSLM原位观察
收稿日期: 2023-02-07
修回日期: 2023-04-06
网络出版日期: 2023-04-23
基金资助
国家重点研发计划项目(2022YFE0123300);国家自然科学基金项目(U20A20277;52050410341;52150610494);江西省自然科学基金项目(20232BAB214054)
Phase Transformation Behaviors in the Heat-Affected Zones of Ferritic Heat-Resistant Steels Enabled by In Situ CSLM Observation
Received date: 2023-02-07
Revised date: 2023-04-06
Online published: 2023-04-23
Supported by
National Key Research and Development Program of China(2022YFE0123300);National Natural Science Foundation of China(U20A20277;52050410341;52150610494);Jiangxi Provincial Natural Science Foundation(20232BAB214054)
铁素体系耐热钢焊接时热影响区的相变行为会严重影响焊接件的室温组织,在后续严苛的条件下运行服役时会对电站安全稳定运行产生严重威胁。高温激光扫描共聚焦显微镜(CSLM)能够重现热影响区焊接热循环,实现对微观组织演变的原位观察以及相变动力学的量化分析,具有优化焊接工艺和促进耐热钢铁材料发展的潜力。本工作利用CSLM对P11、P22、P91 3种典型Cr-Mo铁素体耐热钢热影响区连续冷却过程中的相变行为进行了原位表征,研究板条组织的生长特征与相变动力学。结果表明,根据形核位置能量势垒的高低,贝氏体板条依次在原奥氏体晶界、夹杂物、晶粒内部畸变区域、先前的贝氏体板条、晶粒内部的自由表面上形核;同时,依附于原奥氏体晶界和先前贝氏体生长的贝氏体板条以及在原奥氏体晶粒内部呈放射状切变生长的马氏体板条均通过碰撞晶界或其他板条的方式停止生长,并形成交叉互锁的结构。随着温度的降低,粗晶热影响区中板条的生长速率明显高于细晶热影响区,这主要归因于过冷度的增加和原奥氏体晶粒尺寸的增大。
关键词: 铁素体耐热钢; 热影响区; 固态相变; 原位观察; 高温激光扫描共聚焦显微镜
申洋 , 谷征满 , 王聪 . 铁素体系耐热钢焊接热影响区相变行为的CSLM原位观察[J]. 金属学报, 2024 , 60(6) : 802 -816 . DOI: 10.11900/0412.1961.2023.00045
Fossil-fired thermal power generation has dominated China's electricity production for a long time, contributing to around 70% of the total capacity. Developing long-life ultra-supercritical thermal power units is essential for improving coal-fired power generation efficiency, reducing harmful gas emissions, and achieving national energy conservation and emission reduction targets. The assembly and manufacture of advanced heat-resistant steel grades are required to address the above demands, serving as crucial components driving the technological advancement of thermal power units. Heat-resistant steel grades P11, P22, and P91, which are Cr-Mo based ferritic, possess a range of highly attractive properties, such as excellent mechanical properties, excellent corrosion resistance, and relatively low construction costs. These steel grades are widely used in pressure vessels and pipelines focused on high-temperature applications. Fusion welding techniques are invariably necessary to weld such heat-resistant-grade steels before they are positioned in high-temperature service. However, it is worth noting that drastic solid-state phase transformations in the heat-affected zones (HAZs) during thermal welding cycles can profoundly influence the heterogeneous microstructures of welded joints, determining their final mechanical properties to a large extent. Furthermore, it seriously threatens the safe and stable operation of thermal power plants. High-temperature confocal scanning laser microscopy (CSLM) revolutionized traditional metallographic experiments, enabling real-time morphology and quantitative analysis tracking. This innovation has facilitated investigations into the kinetic phase transformation process and microstructure evolution in steels at high temperatures. In this work, the kinetics of phase transformation and microstructural evolution in the HAZs of P11, P22, and P91 ferritic heat-resistant steels during continuous cooling processes were systematically investigated using CSLM. The results revealed that bainite laths preferentially nucleate in the order of increasing difficulty in the energy barrier on austenite grain boundaries, inclusions, internal grain distortion areas, previous bainite laths, and grain interiors. Meanwhile, the growth characteristics of bainite/martensite laths were documented as the phase transformation progressed. It is revealed that bainite laths attach to prior austenite grain boundaries and the previous bainite, while martensite laths grow radially inside the prior austenite grains. Both bainite and martensite laths cease growing when they encounter grain boundaries or other laths, eventually forming an interlocking microstructure. Additionally, the growth rates of bainite/martensite laths in the HAZs of P11, P22, and P91 ferritic heat-resistant steels exhibited considerable variations as the temperature decreased. The analysis revealed that as the temperature decreased, the growth rate of laths in the coarse-grained heat-affected zone was considerably higher than that in the fine-grained heat-affected zone, which can be attributed to the increase in the degree of supercooling and prior austenite grain size.
| 1 | Liu Z D, Chen Z Z, He X K, et al. Systematical innovation of heat resistant materials used for 630-700oC advanced ultra-supercritical (A-USC) fossil fired boilers [J]. Acta Metall. Sin., 2020, 56: 539 |
| 刘正东, 陈正宗, 何西扣 等. 630~700℃超超临界燃煤电站耐热管及其制造技术进展 [J]. 金属学报, 2020, 56: 539 | |
| 2 | He H S, Yu L M, Liu C X, et al. Research progress of a novel martensitic heat-resistant steel G115 [J]. Acta Metall. Sin., 2022, 58: 311 |
| 何焕生, 余黎明, 刘晨曦 等. 新一代马氏体耐热钢G115的研究进展 [J]. 金属学报, 2022, 58: 311 | |
| 3 | Liu Z D, Cheng S C, Bao H S, et al. Localization of boiler steel technology in China used for ultra super critical power plants [J]. Iron Steel, 2009, 44(6): 1 |
| 刘正东, 程世长, 包汉生 等. 超超临界火电机组用锅炉钢技术国产化问题 [J]. 钢铁, 2009, 44(6): 1 | |
| 4 | Liu Z D, Cheng S C, Tang G B, et al. The state-of-the-art of steel technology used for Chinese power plants and its future [J]. Iron Steel, 2011, 46(3): 1 |
| 刘正东, 程世长, 唐广波 等. 中国电站用钢技术现状和未来发展 [J]. 钢铁, 2011, 46(3): 1 | |
| 5 | Laha K, Chandravathi K S, Parameswaran P, et al. Type IV cracking susceptibility in weld joints of different grades of Cr-Mo ferritic steel [J]. Metall. Mater. Trans., 2009, 40A: 386 |
| 6 | Hua Y, Chen J G, Yu L M, et al. Microstructure evolution and mechanical properties of dissimilar material diffusion-bonded joint for high Cr ferrite heat-resistant steel and austenitic heat-resistant steel [J]. Acta Metall. Sin., 2022, 58: 141 |
| 化 雨, 陈建国, 余黎明 等. 高Cr铁素体耐热钢与奥氏体耐热钢的异种材料扩散连接接头组织演变及力学性能 [J]. 金属学报, 2022, 58: 141 | |
| 7 | Zou X D, Zhao D P, Sun J C, et al. An integrated study on the evolution of inclusions in EH36 shipbuilding steel with Mg addition: From casting to welding [J]. Metall. Mater. Trans., 2018, 49B: 481 |
| 8 | Shen Y, Leng J, Wang C. On the heterogeneous microstructure development in the welded joint of 12MnNiVR pressure vessel steel subjected to high heat input electrogas welding [J]. J. Mater. Sci. Technol., 2019, 35: 1747 |
| 9 | Wu Y W, Yuan X B, Kaldre I, et al. TiO2-assisted microstructural variations in the weld metal of EH36 shipbuilding steel subject to high heat input submerged arc welding [J]. Metall. Mater. Trans., 2023, 54B: 50 |
| 10 | Wang Y Y, Kannan R, Zhang L, et al. Microstructural analysis of the as-welded heat-affected zone of a grade 91 steel heavy section weldment [J]. Weld. J., 2017, 96: 203 |
| 11 | Lee K, Lee S, Na H, et al. Ghost microstructure evolution and identification in the coarse grain heat affected zone of 2.25Cr-1Mo-V-Ti steel using tint etching [J]. Mater. Charact., 2016, 121: 31 |
| 12 | Abd El-Azim M E, Ibrahim O H, El-Desoky O E. Long term creep behaviour of welded joints of P91 steel at 650oC [J]. Mater. Sci. Eng., 2013, A560: 678 |
| 13 | Wang X, Wang X, Zhang Y L, et al. Microstructure and creep fracture behavior in HR3C/T92 dissimilar steel welds [J]. Mater. Sci. Eng., 2021, A799: 140128 |
| 14 | Wang C, Zhang J. Fine-tuning weld metal compositions via flux optimization in submerged arc welding: an overview [J]. Acta Metall. Sin., 2021, 57: 1126 |
| 王 聪, 张 进. 埋弧焊中焊剂对焊缝金属成分调控的研究进展 [J]. 金属学报, 2021, 57: 1126 | |
| 15 | Wang Y Y, Kannan R, Li L J. Characterization of as-welded microstructure of heat-affected zone in modified 9Cr-1Mo-V-Nb steel weldment [J]. Mater. Charact., 2016, 118: 225 |
| 16 | Quidort D, Brechet Y J M. A model of isothermal and non isothermal transformation kinetics of bainite in 0.5%C steels [J]. ISIJ Int., 2002, 42: 1010 |
| 17 | Ueshima Y, Mizoguchi S, Matsumiya T, et al. Analysis of solute distribution in dendrites of carbon steel with δ/γ transformation during solidification [J]. Metall. Mater. Trans., 1986, 17B: 845 |
| 18 | Mayr P, Palmer T A, Elmer J W, et al. Formation of delta ferrite in 9 wt pct Cr steel investigated by in-situ X-ray diffraction using synchrotron radiation [J]. Metall. Mater. Trans., 2010, 41A: 2462 |
| 19 | Yu X H, Babu S S, Lippold J C, et al. In-situ observations of martensitic transformation in blast-resistant steel [J]. Metall. Mater. Trans., 2012, 43A: 1538 |
| 20 | Mu W Z, Hedstr?m P, Shibata H, et al. High-temperature confocal laser scanning microscopy studies of ferrite formation in inclusion-engineered steels: A review [J]. JOM, 2018, 70: 2283 |
| 21 | Shen Y, Chen B, Wang C. In situ observation and growth kinetics of bainite laths in the coarse-grained heat-affected zone of 2.25Cr-1Mo heat-resistant steel during simulated welding [J]. Metall. Mater. Trans., 2021, 52A: 14 |
| 22 | Xuan C J, Mu W Z. Dissolution kinetics of arbitrarily-shaped alumina in oxide melt: An integration of phase-field modelling and real-time observation study [J]. J. Alloys Compd., 2020, 834: 155168 |
| 23 | Mu W Z, Shibata H, Hedstr?m P, et al. Ferrite formation dynamics and microstructure due to inclusion engineering in low-alloy steels by Ti2O3 and TiN addition [J]. Metall. Mater. Trans., 2016, 47B: 2133 |
| 24 | Zou X D, Sun J C, Matsuura H, et al. In situ observation of the nucleation and growth of ferrite laths in the heat-affected zone of EH36-Mg shipbuilding steel subjected to different heat inputs [J]. Metall. Mater. Trans., 2018, 49B: 2168 |
| 25 | Ko T, Cottrell S A. The formation of bainite [J]. J. Iron Steel Inst., 1952, 172: 307 |
| 26 | Terasaki H, Komizo Y I. Diffusional and displacive transformation behaviour in low carbon-low alloy steels studied by a hybrid in situ observation system [J]. Scr. Mater., 2011, 64: 29 |
| 27 | Swallow E, Bhadeshia H K D H. High resolution observations of displacements caused by bainitic transformation [J]. Mater. Sci. Technol., 1996, 12: 121 |
| 28 | Bhadeshia H K D H, Christian J W. Bainite in steels [J]. Metall. Mater. Trans., 1990, 21A: 767 |
| 29 | Chang L C, Bhadeshia H K D H. Microstructure of lower bainite formed at large undercoolings below bainite start temperature [J]. Mater. Sci. Technol., 1996, 12: 233 |
| 30 | Singh K, Kumar A, Singh A. Effect of prior austenite grain size on the morphology of nano-bainitic steels [J]. Metall. Mater. Trans., 2018, 49A: 1348 |
| 31 | Ricks R A, Howell P R, Barritte G S. The nature of acicular ferrite in HSLA steel weld metals [J]. J. Mater. Sci., 1982, 17: 732 |
| 32 | Mao C L, Liu C X, Yu L M, et al. Discontinuous lath martensite transformation and its relationship with annealing twin of parent austenite and cooling rate in low carbon RAFM steel [J]. Mater. Des., 2021, 197: 109252 |
| 33 | Samanta S, Biswas P, Giri S, et al. Formation of bainite below the MS temperature: Kinetics and crystallography [J]. Acta Mater., 2016, 105: 390 |
| 34 | Xu Z Y, Jin X J, Zhang J H, et al. Phase Transformation in Materials [M]. Beijing: Higher Education Press, 2013: 87 |
| 徐祖耀, 金学军, 张骥华 等. 材料相变 [M]. 北京: 高等教育出版社, 2013: 87 | |
| 35 | Sarizam M, Komizo Y. Effects of holding temperature on bainite transformation in Cr-Mo steel [J]. J. Mech. Eng. Sci., 2014, 7: 1103 |
| 36 | Zhang S H, Hattori N, Enomoto M, et al. Ferrite nucleation at ceramic/austenite interfaces [J]. ISIJ Int., 1996, 36: 1301 |
| 37 | Mao G J, Cao R, Guo X L, et al. In situ observation of kinetic processes of lath bainite nucleation and growth by laser scanning confocal microscope in reheated weld metals [J]. Metall. Mater. Trans., 2017, 48A: 5783 |
| 38 | Pan X Q, Zhi J J, Fan Z J, et al. Morphology and crystallography of microstructures in Mg-deoxidized offshore engineering steels after simulated welding thermal cycles [J]. Ironmak. Steelmak., 2022, 49: 541 |
| 39 | Hu H J, Xu G, Nabeel M, et al. In situ study on interrupted growth behavior and crystallography of bainite [J]. Metall. Mater. Trans., 2021, 52A: 817 |
| 40 | Lee S J, Park J S, Lee Y K. Effect of austenite grain size on the transformation kinetics of upper and lower bainite in a low-alloy steel [J]. Scr. Mater., 2008, 59: 87 |
| 41 | Chen R C, Zheng Z Z, Li N, et al. In-situ investigation of phase transformation behaviors of 300M steel in continuous cooling process [J]. Mater. Charact., 2018, 144: 400 |
| 42 | Luo H W, Wang X H, Liu Z B, et al. Influence of refined hierarchical martensitic microstructures on yield strength and impact toughness of ultra-high strength stainless steel [J]. J. Mater. Sci. Technol., 2020, 51: 130 |
| 43 | Furuhara T, Kawata H, Morito S, et al. Crystallography of upper bainite in Fe-Ni-C alloys [J]. Mater. Sci. Eng., 2006, A431: 228 |
| 44 | Terasaki H, Komizo Y I. Correlation between the microstructural development of bainitic ferrite and the characteristics of martensite-austenite constituent [J]. Metall. Mater. Trans., 2013, 44A: 5289 |
| 45 | Wright S I, Nowell M M, Field D P. A review of strain analysis using electron backscatter diffraction [J]. Microsc. Microanal., 2011, 17: 316 |
| 46 | Saraf L. Kernel average misorientation confidence index correlation from FIB sliced Ni-Fe-Cr alloy surface [J]. Microsc. Microanal., 2011, 17: 424 |
| 47 | Kang S, Yoon S, Lee S J. Prediction of bainite start temperature in alloy steels with different grain sizes [J]. ISIJ Int., 2014, 54: 997 |
| 48 | Zheng Y F, Wu R M, Li X C, et al. Continuous cooling transformation behaviour and bainite formation kinetics of new bainitic steel [J]. Mater. Sci. Technol., 2017, 33: 454 |
| 49 | Steven W, Haynes A G. The temperature of formation of martensite and bainite in low-alloy steels [J]. J. Iron Steel Inst., 1956, 183: 349 |
| 50 | Andrews K W. Empirical formulae for the calculation of some transformation temperatures [J]. J. Iron Steel Inst., 1965, 203: 721 |
| 51 | Hu Z W, Xu G, Hu H J, et al. In situ measured growth rates of bainite plates in an Fe-C-Mn-Si superbainitic steel [J]. Int. J. Miner. Metall. Mater., 2014, 21: 371 |
| 52 | Lambert-Perlade A, Gourgues A F, Pineau A. Austenite to bainite phase transformation in the heat-affected zone of a high strength low alloy steel [J]. Acta Mater., 2004, 52: 2337 |
| 53 | Endo A, Chauhan H S, Nakamura Y, et al. Relationship between growth rate and undercooling in Pt-added Y1Ba2Cu3O7 - x [J]. J. Mater. Res., 1996, 11: 1114 |
| 54 | Liang G F, Ali Y, You G Q, et al. Effect of cooling rate on grain refinement of cast aluminium alloys [J]. Materialia, 2018, 3: 113 |
| 55 | Celada-Casero C, Sietsma J, Santofimia M J. The role of the austenite grain size in the martensitic transformation in low carbon steels [J]. Mater. Des., 2019, 167: 107625 |
| 56 | Hu F, Hodgson P D, Wu K M. Acceleration of the super bainite transformation through a coarse austenite grain size [J]. Mater. Lett., 2014, 122: 240 |
| 57 | Xu G, Liu F, Wang L, et al. A new approach to quantitative analysis of bainitic transformation in a superbainite steel [J]. Scr. Mater., 2013, 68: 833 |
| 58 | Liu D K, Yang J, Zhang Y H. In-situ observation of bainite transformation in CGHAZ of 420 MPa grade offshore engineering steel with different Mo contents [J]. ISIJ Int., 2022, 62: 714 |
| 59 | Kong J H, Xie C S. Effect of molybdenum on continuous cooling bainite transformation of low-carbon microalloyed steel [J]. Mater. Des., 2006, 27: 1169 |
| 60 | Hu H J, Xu G, Zhou M X, et al. Effect of Mo content on microstructure and property of low-carbon bainitic steels [J]. Metals, 2016, 6: 173 |
/
| 〈 |
|
〉 |