研究论文

锂离子电池用微米厚度超薄集流体Cu箔和Al箔疲劳强度及损伤行为

  • 程福来 ,
  • 罗雪梅 ,
  • 胡炳利 ,
  • 张滨 ,
  • 张广平
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  • 1 中国科学院金属研究所 沈阳材料科学国家研究中心 沈阳 110016
    2 中国科学技术大学 材料科学与工程学院 沈阳 110016
    3 东北大学 材料科学与工程学院 材料各向异性与织构教育部重点实验室 沈阳 110819
程福来,男,1997年生,博士生
张广平,gpzhang@imr.ac.cn,主要从事金属材料疲劳与断裂研究;
罗雪梅,xmluo@imr.ac.cn,主要从事金属材料疲劳与断裂研究

收稿日期: 2022-10-14

  修回日期: 2023-02-14

  网络出版日期: 2023-02-27

基金资助

国家自然科学基金项目(52071319)

Fatigue Strength and Damage Behavior of Micron-Thick Ultrathin Current Collector Cu Foil and Al Foil for Lithium-Ion Battery

  • CHENG Fulai ,
  • LUO Xuemei ,
  • HU Bingli ,
  • ZHANG Bin ,
  • ZHANG Guangping
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  • 1 Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    2 School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
    3 Key Laboratory for Anisotropy and Texture of Materials, Ministry of Education, School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China
ZHANG Guangping, professor, Tel:(024)23971938, E-mail: gpzhang@imr.ac.cn;
LUO Xuemei, associate professor, Tel:(024)83978029, E-mail: xmluo@imr.ac.cn

Received date: 2022-10-14

  Revised date: 2023-02-14

  Online published: 2023-02-27

Supported by

National Natural Science Foundation of China(52071319)

摘要

随着高性能、高能量密度锂离子电池的飞速发展,锂离子电池用集流体金属箔轻薄化已成为行业技术升级的一个重要方向,随着集流体厚度的减小,其疲劳失效问题变得日益突出。本工作通过拉-拉疲劳实验和EBSD技术研究了循环载荷作用下锂离子电池用集流体Cu箔和Al箔的高周疲劳强度及失效行为。结果表明,Cu箔疲劳裂纹主要萌生于较大晶粒内部的滑移带处,并沿滑移带扩展。基于对损伤晶粒微观结构的观察和统计分析,获得了Cu箔疲劳裂纹萌生和材料微观结构(晶粒尺寸及其变异系数、晶粒取向、Schmid因子(Ω))的统计关系图。Al箔由于表面含有轧制缺陷,其疲劳裂纹优先在表面加工缺陷处萌生。通过极值统计法成功预测了Al箔样品中可能的缺陷分布以及存在的最大缺陷尺寸,并基于Kitagawa-Takahashi图建立了缺陷尺寸与疲劳极限之间的关系。

本文引用格式

程福来 , 罗雪梅 , 胡炳利 , 张滨 , 张广平 . 锂离子电池用微米厚度超薄集流体Cu箔和Al箔疲劳强度及损伤行为[J]. 金属学报, 2024 , 60(4) : 522 -536 . DOI: 10.11900/0412.1961.2022.00523

Abstract

With the rapid development of high-performance and high-energy-density lithium-ion batteries, lightweight current collector metal foils for lithium-ion batteries have become a crucial direction of industrial technological advancements. As the thickness of the current collector decreases, the fatigue failure problem becomes increasingly prominent. Once the fatigue failure of the current collector occurs, it will have a catastrophic impact on the electrochemical and safety performances of lithium-ion batteries. Here, to further clarify the fatigue damage mechanism of current collector foils, the high cycle fatigue strength and fatigue failure behavior of current collector Cu and Al foils for lithium-ion batteries under cyclic loading were experimentally investigated using tensile-tensile fatigue test and the EBSD technique. Results show that the fatigue cracks of the Cu foils mainly originate from the slip bands with larger grain sizes and propagate along the slip bands. Based on the microstructure observation and analysis of damaged grains, a statistical relationship between fatigue crack initiation and microstructure (grain size and its coefficient of variation, grain orientation, and Schmid factor (Ω)) of the Cu foils was obtained. Due to the presence of rolled defects on the surface of Al foils, the fatigue cracks are preferentially initiated at the surface defects. Extreme value statistics accurately predicted the possible defect population and the largest defect size in the Al foils, and the relationship between the defect size and fatigue limit was established using the Kitagawa-Takahashi diagram.

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