δ-铁素体对钠冷快堆用316KD奥氏体不锈钢热变形行为和动态再结晶的影响
收稿日期: 2022-01-27
修回日期: 2022-03-16
网络出版日期: 2022-09-26
基金资助
国家自然科学基金项目(51871218);中科院青年创新促进会项目(2018227);中核集团青年英才计划项目
Effect of δ-Ferrite on Hot Deformation and Recrystallization of 316KD Austenitic Stainless Steel for Sodium-Cooled Fast Reactor Application
Received date: 2022-01-27
Revised date: 2022-03-16
Online published: 2022-09-26
Supported by
National Natural Science Foundation of China(51871218);Youth Innovation Promotion Association CAS(2018227);CNNC Science Fund for Talented Young Scholars
奥氏体不锈钢中δ-铁素体的存在显著影响热加工过程中奥氏体晶粒度的控制,造成晶粒不均匀现象,关于δ-铁素体对奥氏体动态再结晶行为的影响机制尚不清楚。本工作利用Gleeble-3800热力模拟试验机在1423 K、0.1 s-1条件下进行了铸态样品和均质化处理态样品的热压缩实验,结合SEM、EBSD和TEM等研究了δ-铁素体对热变形行为和动态再结晶的影响。结果表明:1473 K均质化处理14 h可基本消除δ-铁素体,同时伴随着奥氏体晶粒的显著长大,计算表明δ-铁素体向奥氏体的转变速率主要受控于Cr在奥氏体中的扩散。铸态样品变形过程中,δ-铁素体内部、δ-铁素体/奥氏体界面处的塑性变形先于奥氏体相,高温下较软δ-铁素体的存在,造成铸态样品的流变应力明显低于均质化处理态无δ-铁素体样品。随着变形的进行,δ-铁素体易发生动态回复,动态回复引起的软化导致流变应力显著下降。均质化处理态样品的动态再结晶机制是原始奥氏体晶界弓出形核的不连续动态再结晶。而δ-铁素体的存在促进了δ-铁素体/奥氏体界面附近奥氏体的动态再结晶,其机制为连续动态再结晶。铸态样品中的原始奥氏体晶界为不连续动态再结晶的形核位置,2种动态再结晶机制的耦合作用使得铸态样品的动态再结晶程度显著高于均质化处理态样品。
陈胜虎 , 王琪玉 , 姜海昌 , 戎利建 . δ-铁素体对钠冷快堆用316KD奥氏体不锈钢热变形行为和动态再结晶的影响[J]. 金属学报, 2024 , 60(3) : 367 -376 . DOI: 10.11900/0412.1961.2022.00039
The sodium-cooled fast reactor is the most mature reactor among generation-IV nuclear reactors. A carbon/nitrogen-controlled 316KD austenitic stainless steel has been developed for the construction of pressure vessels and internals in Chinese CFR600 demonstration reactor. During their industrial production, δ-ferrite is present in large-scale billets because of the combined effect of non-equilibrium segregation and low cooling rate. For large-scale billets containing δ-ferrite, inhomogeneous grain-size distributions are observed in the product after hot working. Extensive studies on the recrystallization of the austenite phase in austenitic stainless steels during hot deformation were conducted. However, the effect of δ-ferrite on the recrystallization behavior of the austenite phase remains unclear. In this study, uniaxial hot compression tests of 316KD austenitic stainless steels involving as-cast and homogenized conditions were conducted at 1423 K and 0.1 s-1 using a Gleeble-3800 thermal-mechanical simulator, and the effect of δ-ferrite on hot deformation and recrystallization was analyzed by SEM, EBSD, and TEM. Results showed that δ-ferrite could be nearly eliminated through δ-ferrite→austenite transformation after homogenization at 1473 K for 14 h, whereas austenite grain showed evident growth. The elimination of δ-ferrite was a Cr-diffusion-controlled process through kinetic analysis. Plastic deformation occurred preferentially in δ-ferrite and at the δ-ferrite/austenite interface, and subsequently in austenite during hot deformation. The flow stress of as-cast samples was much lower than that of homogenized samples at the same strain because of the presence of soft δ-ferrite. Dynamic recovery occurred easier in δ-ferrite, and the resulting dynamic softening remarkably reduced flow stress with an increase in strain. Discontinuous dynamic recrystallization characterized by original austenite grain boundary bulging was the dominant mechanism in homogenized samples. However, the presence of δ-ferrite promoted the occurrence of continuous dynamic recrystallization in austenite near the δ-ferrite/austenite interface in as-cast samples. Compared with the homogenized samples, a higher degree of recrystallization was observed in as-cast samples because of the combined effects of continuous dynamic recrystallization and discontinuous dynamic recrystallization.
| 1 | Sofu T. A review of inherent safety characteristics of metal alloy sodium-cooled fast reactor fuel against postulated accidents [J]. Nucl. Eng. Technol., 2015, 47: 227 |
| 2 | Dai Y N, Zheng X T, Ding P S. Review on sodium corrosion evolution of nuclear-grade 316 stainless steel for sodium-cooled fast reactor applications [J]. Nucl. Eng. Technol., 2021, 53: 3474 |
| 3 | Aoto K, Dufour P, Yang H Y, et al. A summary of sodium-cooled fast reactor development [J]. Prog. Nucl. Energy, 2014, 77: 247 |
| 4 | Yan C G, Li Y P, Wang M Z. Type 316 austenitic steels for reactor vessel and internals in sodium fast reactors and their creep rupture properties [J]. J. Iron Steel Res., 2018, 30: 935 |
| 燕春光, 李雅平, 王明政. 钠冷快堆堆容器堆内构件用316型不锈钢及其持久断裂性能 [J]. 钢铁研究学报, 2018, 30: 935 | |
| 5 | Schaeffler A L. Constitution diagram for stainless steel weld metal [J]. Met. Prog., 1949, 56: 680 |
| 6 | Delong W T. Ferrite in austenitic stainless steel weld metal [J]. Weld. J., 1974, 53: 273s |
| 7 | Espy R H. Weldability of nitrogen-strengthened stainless steels [J]. Weld. J., 1982, 61: 149s |
| 8 | Wang Q Y, Chen S H, Rong L J. δ-Ferrite formation and its effect on the mechanical properties of heavy-section AISI 316 stainless steel casting [J]. Metall. Mater. Trans., 2020, 51A: 2998 |
| 9 | Wang Q Y, Chen S H, Lv X L, et al. Role of δ-ferrite in fatigue crack growth of AISI 316 austenitic stainless steel [J]. J. Mater. Sci. Technol., 2022, 114: 7 |
| 10 | Zhou Y H, Liu Y C, Zhou X S, et al. Precipitation and hot deformation behavior of austenitic heat-resistant steels: A review [J]. J. Mater. Sci. Technol., 2017, 33: 1448 |
| 11 | Zhou Y H, Liu Y C, Zhou X S, et al. Processing maps and microstructural evolution of the type 347H austenitic heat-resistant stainless steel [J]. J. Mater. Res., 2015, 30: 2090 |
| 12 | Guo B F, Ji H P, Liu X G, et al. Research on flow stress during hot deformation process and processing map for 316LN austenitic stainless steel [J]. J. Mater. Eng. Perform., 2012, 21: 1455 |
| 13 | Mataya M C, Nilsson E R, Brown E L, et al. Hot working and recrystallization of as-cast 316L [J]. Metall. Mater. Trans., 2003, 34A: 1683 |
| 14 | Dehghan-Manshadi A, Barnett M R, Hodgson P D. Hot deformation and recrystallization of austenitic stainless steel: Part I. Dynamic recrystallization [J]. Metall. Mater. Trans., 2008, 39A: 1359 |
| 15 | Wang S L, Zhang M X, Wu H C, et al. Study on the dynamic recrystallization model and mechanism of nuclear grade 316LN austenitic stainless steel [J]. Mater. Charact., 2016, 118: 92 |
| 16 | Chen L, Wang L M, Du X J, et al. Hot deformation behavior of 2205 duplex stainless steel [J]. Acta Metall. Sin., 2010, 46: 52 |
| 陈 雷, 王龙妹, 杜晓建 等. 2205双相不锈钢的高温变形行为 [J]. 金属学报, 2010, 46: 52 | |
| 17 | Ni K, Yang Y H, Cao J C, et al. Softening behavior of 18.7Cr-1.0Ni-5.8Mn-0.2N low nickel-type duplex stainless steel during hot compression deformation under large strain [J]. Acta Metall. Sin., 2021, 57: 224 |
| 倪 珂, 杨银辉, 曹建春 等. 18.7Cr-1.0Ni-5.8Mn-0.2N节Ni型双相不锈钢的大变形热压缩软化行为 [J]. 金属学报, 2021, 57: 224 | |
| 18 | Fang Y L, Liu Z Y, Zhang W N, et al. Microstructure evolution of lean duplex stainless steel 2101 during hot deformation [J]. Acta Metall. Sin., 2010, 46: 641 |
| 方轶琉, 刘振宇, 张维娜 等. 节约型双相不锈钢2101高温变形过程中微观组织演化 [J]. 金属学报, 2010, 46: 641 | |
| 19 | Dehghan-Manshadi A, Hodgson P D. Effect of δ-ferrite co-existence on hot deformation and recrystallization of austenite [J]. J. Mater. Sci., 2008, 43: 6272 |
| 20 | Dehghan-Manshadi A, Barnett M R, Hodgson P D. Microstructural evolution during hot deformation of duplex stainless steel [J]. Mater. Sci. Technol., 2007, 23: 1478 |
| 21 | Ruitenberg G, Woldt E, Petford-Long A K. Comparing the Johnson-Mehl-Avrami-Kolmogorov equations for isothermal and linear heating conditions [J]. Thermochim. Acta, 2001, 378: 97 |
| 22 | Ham F S. Theory of diffusion-limited precipitation [J]. J. Phys. Chem. Solids, 1958, 6: 335 |
| 23 | Alberry P J, Haworth C W. Interdiffusion of Cr, Mo, and W in iron [J]. Met. Sci., 1974, 8: 407 |
| 24 | Ponge D, Gottstein G. Necklace formation during dynamic recrystallization: Mechanisms and impact on flow behavior [J]. Acta Mater., 1998, 46: 69 |
| 25 | Pi?ol-Juez A, Iza-Mendia A, Gutiérrez I. δ /γ Interface bondary sliding as a mechanism for strain accommodation during hot deformation in a duplex stainless steel [J]. Metall. Mater. Trans., 2000, 31A: 1671 |
| 26 | Chen S H, Rong L J. Effect of silicon on the microstructure and mechanical properties of reduced activation ferritic/martensitic steel [J]. J. Nucl. Mater., 2015, 459: 13 |
| 27 | Yanushkevich Z, Belyakov A, Kaibyshev R. Microstructural evolution of a 304-type austenitic stainless steel during rolling at temperatures of 773-1273 K [J]. Acta Mater., 2015, 82: 244 |
| 28 | Arun Babu K, Mozumder Y H, Saha R, et al. Hot-workability of super-304H exhibiting continuous to discontinuous dynamic recrystallization transition [J]. Mater. Sci. Eng., 2018, A734: 269 |
| 29 | Dehghan-Manshadi A, Hodgson P D. Dependency of recrystallization mechanism to the initial grain size [J]. Metall. Mater. Trans., 2008, 39A: 2830 |
| 30 | Gourdet S, Montheillet F. A model of continuous dynamic recrystallization [J]. Acta Mater., 2003, 51: 2685 |
| 31 | Gourdet S, Montheillet F. Effects of dynamic grain boundary migration during the hot compression of high stacking fault energy metals [J]. Acta Mater., 2002, 50: 2801 |
/
| 〈 |
|
〉 |