基于不同 α / β 团簇式比例的Ti-Al-V合金的铸态组织和力学性能

  • 朱智浩 ,
  • 陈志鹏 ,
  • 刘田雨 ,
  • 张爽 ,
  • 董闯 ,
  • 王清
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  • 1大连理工大学 三束材料改性教育部重点实验室 大连 116024
    2沈阳铸造研究所有限公司 高端装备轻合金铸造技术国家重点实验室 沈阳 110022
    3大连交通大学 材料科学与工程学院 大连 116028
朱智浩,男,1994年生,博士生
董 闯,dong@dlut.edu.cn,主要从事材料的原子结构模型及成分设计研究

收稿日期: 2021-11-22

  修回日期: 2022-03-07

  网络出版日期: 2022-06-28

基金资助

国家重点基础研究项目(2020JCJQZD165);大连市科技创新基金重点学科重大课题项目(2020JJ25CY004)

Microstructure and Mechanical Properties of As-Cast Ti-Al-V Alloys with Different Proportion of α / β Clusters

  • ZHU Zhihao ,
  • CHEN Zhipeng ,
  • LIU Tianyu ,
  • ZHANG Shuang ,
  • DONG Chuang ,
  • WANG Qing
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  • 1Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China
    2State Key Laboratory of Light Alloy Casting Technology for High-End Equipment, Shenyang Research Institute of Foundry Co., Ltd. CAM, Shenyang 110022, China
    3School of Materials Science and Engineering, Dalian Jiaotong University, Dalian 116028, China

Received date: 2021-11-22

  Revised date: 2022-03-07

  Online published: 2022-06-28

Supported by

National Basic Research Program of China(2020JCJQZD165);Key Discipline and Major Project of Dalian Science and Technology Innovation Foundation(2020JJ25CY004)

摘要

在课题组前期工作基础上,设计并铜模吸铸了满足α-{[Al-Ti12](AlTi2)}17 - n + β-{[Al-Ti14](V2Ti)}n 团簇式的合金系列,通过改变β相团簇式的个数n,获得组织覆盖αβ的Ti-(3.19~7.45)Al-(0~12.03)V系列合金,进而表征了铸态组织和室温拉伸力学性能。结果表明,随着n增加,铸态组织由单一α (α'马氏体)经双相态直到单相βα'马氏体形态由板条状逐渐转变为细片状和针状,当n = 5时开始出现β相,n = 8时α'马氏体数量最多且呈针状,当n = 12时α相完全消失,形成单一β相。相应地,合金强度呈先上升而后下降的趋势,塑性变化趋势则相反,这源自细小针状α'马氏体提升强度而降低塑性的作用。当n = 8时,合金的强度达到最大(比Ti-6Al-4V提高了90 MPa),抗拉强度约为1019 MPa、屈服强度约为867 MPa、延伸率与Ti-6Al-4V持平(约为4%),尤其是比强度和比硬度均优于Ti-6Al-4V,达到了230 kN·m/kg和0.76 GPa·cm3/g,分别提升了9%和5%。

本文引用格式

朱智浩 , 陈志鹏 , 刘田雨 , 张爽 , 董闯 , 王清 . 基于不同 α / β 团簇式比例的Ti-Al-V合金的铸态组织和力学性能[J]. 金属学报, 2023 , 59(12) : 1581 -1589 . DOI: 10.11900/0412.1961.2021.00503

Abstract

The dual-cluster composition formula of the widely-used α + β Ti-6Al-4V and α-{[Al-Ti12](AlTi2)}12 + β-{[Al-Ti14](V2Ti)}5, reported in our previous work, indicates that all Ti alloys are composed of α and β units. In this study, Ti-(3.19-7.45)Al-(0-12.03)V (mass fraction, %) alloys are designed following composition formula of [Al-Ti12](AlTi2)}17 - n + β-{[Al-Ti14](V2Ti)}n by changing n value (number of β cluster units). The alloys as prepared by copper mould suction-casting cover microstructures ranging from pure α to pure β. In the as-cast state, as the n value increases, the microstructure changes from single α phase (α' martensite), via α + β dual-phase, and finally to single β phase. The morphology of α' martensite gradually changes from plate-like to lamellar and needle-like. Ti-6Al-4V alloy corresponds to n = 5, where β phase begins to appear. When n = 8, needle-like α' martensite shows the highest content. When n = 12, α phase disappears completely and is replaced by β phase. Correspondingly, the strength of the alloys increases first and then decreases, while the plasticity changes inversely, due to the presence of fine-needle α' martensite. Among all the compositions, Ti-5.28Al-6.14V alloy (n = 8) shows the highest strength (about 90 MPa higher than Ti-6Al-4V), with tensile strength of 1019 MPa, yield strength of 867 MPa. Its specific strength and hardness of 230 kN·m/kg and 0.76 GPa·cm3/g increased by 9% and 5%, respectively, are both superior to Ti-6Al-4V.

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