AlCr1.3TiNi2 共晶高熵合金的高温摩擦学性能及磨损机理
收稿日期: 2021-12-30
修回日期: 2022-04-23
网络出版日期: 2022-06-07
基金资助
国家自然科学基金项目(51822402);国家自然科学基金项目(U20A20278);国家自然科学基金项目(52001051);国家重点研发计划项目(2018YFA0702901);国家重点研发计划项目(2019YFA0209901);辽宁省兴辽英才计划项目(XLYC1807047);宁波市“科技创新2025”重大专项项目(2019B10086);中国博士后科学基金项目(2021T140082)
Tribological Properties and Wear Mechanism of AlCr1.3TiNi2 Eutectic High-Entropy Alloy at Elevated Temperature
Received date: 2021-12-30
Revised date: 2022-04-23
Online published: 2022-06-07
Supported by
National Natural Science Foundation of China(51822402);National Natural Science Foundation of China(U20A20278);National Natural Science Foundation of China(52001051);National Key Research and Development Program of China(2018YFA0702901);National Key Research and Development Program of China(2019YFA0209901);Liaoning Revitalization Talents Program(XLYC1807047);Major Special Project of "Scientific and Technological Innovation 2025" in Ningbo(2019B10086);China Postdoctoral Science Foundation(2021T140082)
采用电磁悬浮熔炼+直接铸造的方法制备了千克级的AlCr1.3TiNi2共晶高熵合金,借助TEM、APT等表征手段分析了该合金的微观组织与成分分布,使用HT-1000摩擦试验机对比研究了该合金与GH4169镍基高温合金的高温摩擦学性能。结果表明:该共晶高熵合金具有超细的层片状共晶组织(层片间距约350 nm),其共晶两相为晶格错配度只有约2%的bcc相与L21相,L21相中还存在大量的纳米析出相;≤ 600℃时,共晶高熵合金的磨损机理以磨粒磨损为主,其磨损率均低于GH4169合金;800℃时,共晶高熵合金的磨痕表面塑性变形加剧,其摩擦系数明显高于GH4169合金,但2者的磨损率相差不大。GH4169合金高温耐磨性的提高得益于其磨损表面氧化物膜的形成,而共晶高熵合金出色的耐磨性主要与其良好的高温组织稳定性及力学性能有关。
苗军伟 , 王明亮 , 张爱军 , 卢一平 , 王同敏 , 李廷举 . AlCr1.3TiNi2 共晶高熵合金的高温摩擦学性能及磨损机理[J]. 金属学报, 2023 , 59(2) : 267 -276 . DOI: 10.11900/0412.1961.2021.00589
Eutectic high-entropy alloys (EHEAs) have been explored as possible options for high-temperature applications due to their controlled microstructure and excellent mechanical properties. In particular, EHEAs possess good liquidity and castability, allowing their possibility for real-size industrial manufacturing. However, despite their importance as a structural material index, the tribological properties were rarely investigated in the EHEAs field. In this study, a kilogram-scale AlCr1.3TiNi2 EHEA was produced using electromagnetic levitation melting and direct casting approach. The EHEA's microstructure and chemical composition were investigated using a TEM and APT techniques. The AlCr1.3TiNi2 EHEA's tribological properties were examined from room temperature to 800oC using a rotational ball-on-disk tribometer (HT-1000). Meanwhile, for comparison, a GH4169 nickel-base superalloy was chosen. The corresponding wear mechanisms were also thoroughly discussed. The findings exhibit that the as-cast AlCr1.3TiNi2 EHEA, which had an ultrafine lamellar structure, consisted of a disordered bcc phase and an ordered L21 phase with lattice misfit of approximately 2%. The average interlamellar spacing was about 350 nm. Additionally, a large number of nanoprecipitates contains in the L21 lamellae central region. Below 600oC, the AlCr1.3TiNi2 EHEA's primary wear mechanism was abrasive wear, and its wear rate was lower than that of the GH4169 alloy. At 800oC, distinct plastic deformation features were observed on the worn surface of EHEA. The EHEA exhibited a much higher friction coefficient than that of the GH4169 alloy at 800oC, but their wear rates were similar. The wear resistance improvement of GH4169 alloy at high temperature was ascribed to the formation of oxide film on its worn surface, and the AlCr1.3TiNi2 EHEA's excellent wear resistance mainly resulted from good structure stability and high hot hardness. Current findings offer new insights into the industrial application of EHEA in high-temperature fields.
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