Ca、Mg掺杂下夹杂物对C70S6非调质钢点蚀行为的影响
收稿日期: 2021-08-30
修回日期: 2021-11-01
网络出版日期: 2022-04-18
基金资助
国家重点研发计划项目(2018YFB0704400);国家自然科学基金项目(51901046)
Effect of Inclusions on Pitting Corrosion of C70S6 Non-Quenched and Tempered Steel Doped with Ca and Mg
Received date: 2021-08-30
Revised date: 2021-11-01
Online published: 2022-04-18
Supported by
National Key Research and Development Program of China(2018YFB0704400);National Natural Science Foundation of China(51901046)
孙阳庭 , 李一唯 , 吴文博 , 蒋益明 , 李劲 . Ca、Mg掺杂下夹杂物对C70S6非调质钢点蚀行为的影响[J]. 金属学报, 2022 , 58(7) : 895 -904 . DOI: 10.11900/0412.1961.2021.00362
As one of the energy-saving steels, non-quenched and tempered steel commonly requires the addition of alloying elements to improve its properties. The inclusions related to those elements have significant influence on the properties of the steels. In this work, the potentiodynamic polarization curves of C70S6 non-quenched and tempered steel and its Mg-Ca doped samples were measured by solution modification, and the samples before and after the test were characterized by SEM-EDS. The results show that the MnS inclusions in the samples act as active sites for pitting. The doped Ca and Mg elements make the distribution of inclusions more dispersed and the content of MnS in each inclusion lower, leading to the better pitting resistance of the doped specimens.
Key words： non quenched and tempered steel; inclusion; pitting corrosion
| 1 | Li X C. Accelerate implementation of green manufacturing of the steel industry to improve level of green development [J]. Metall. Econ. Manage., 2019, (2): 4 |
| 1 | 李新创. 加快钢铁“绿色制造”提升绿色发展水平 [J]. 冶金经济与管理, 2019, (2): 4 |
| 2 | Luo Z M. Application and prospect of non-quenched tempered steel [J]. Fujian Metall., 2018, 47(4): 52 |
| 2 | 罗灶明. 非调质钢的应用及展望 [J]. 福建冶金, 2018, 47(4): 52 |
| 3 | Zhang Q, Ma Q. Application status and prospect of non-quenched and tempered steel in construction machinery [J]. MW Met. Form., 2014, (15): 62 |
| 3 | 张 坤, 马 强. 非调质钢在工程机械上的应用现状及展望 [J]. 金属加工 (热加工), 2014, (15): 62 |
| 4 | Wu W. Application and development of non-quenched and tempered steel for automotive parts [J]. World Iron Steel, 2009, 9(4): 62 |
| 4 | 吴 玮. 汽车零部件用非调质钢的应用和发展 [J]. 世界钢铁, 2009, 9(4): 62 |
| 5 | Liu S H, Wang X H, Dai G W, et al. Investigation on non-metallic inclusions in hot forging steels of high cleanliness [J]. Iron Steel, 2008, 43(5): 35 |
| 5 | 刘石虹, 王新华, 戴观文 等. 高洁净度汽车用非调质钢中非金属夹杂物研究 [J]. 钢铁, 2008, 43(5): 35 |
| 6 | Lu J L, Wang Y P, Wang Q M, et al. Effect of MnS inclusions distribution on intragranular ferrite formation in medium carbon non-quenched and tempered steel for large-sized crankshaft [J]. ISIJ Int., 2019, 59: 524 |
| 7 | Wang L W, Xin J C, Cheng L J, et al. Influence of inclusions on initiation of pitting corrosion and stress corrosion cracking of X70 steel in near-neutral pH environment [J]. Corros. Sci., 2019, 147: 108 |
| 8 | Qi Y F, Li J, Shi C B, et al. Precipitation and growth of MnS inclusion in an austenitic hot-work die steel during ESR solidification process [J]. Metall. Res. Technol., 2019, 116: 322 |
| 9 | Zhang T S, Min Y, Liu C J, et al. Effect of Mg addition on the evolution of inclusions in Al-Ca deoxidized melts [J]. ISIJ Int., 2015, 55: 1541 |
| 10 | Lu P Y, Wu H J, Yue F, et al. Effect of calcium treatment on change behavior of inclusions in sulfur-containing non-quenched and tempered steel [J]. Steelmaking, 2015, 31(2): 30 |
| 10 | 陆鹏雁, 吴华杰, 岳 峰 等. 钙处理对含硫非调质钢中夹杂物演变行为的影响 [J]. 炼钢, 2015, 31(2): 30 |
| 11 | Shen P, Fu J X. Morphology study on inclusion modifications using Mg-Ca treatment in resulfurized special steel [J]. Materials, 2019, 12: 197 |
| 12 | Yan Z Y, Zhang H, Yang Y Y. Improvement of microstructure and properties of non-quenched and tempered steel for hot forging with calcium treatment [J]. Hot Working Technol., 2016, 45(13):127 |
| 12 | 闫治宇, 张 晗, 杨瑶瑶. Ca处理对含硫热锻微合金非调质钢组织性能改善的研究 [J]. 热加工工艺, 2016, 45(13): 127 |
| 13 | Liu Q. Study on the corrosion behavior induced by typical inclusions in 304 stainless steel [D]. Beijing: University of Science and Technology Beijing, 2018 |
| 13 | 刘 青. 304不锈钢中典型夹杂物诱发腐蚀行为研究 [D]. 北京: 北京科技大学, 2018 |
| 14 | Choi J Y, Kim S K, Kang Y B, et al. Compositional evolution of oxide inclusions in austenitic stainless steel during continuous casting [J]. Steel Res. Int., 2015, 86: 284 |
| 15 | Ha H Y, Park C J, Kwon H S. Effects of non-metallic inclusions on the initiation of pitting corrosion in 11% Cr ferritic stainless steel examined by micro-droplet cell [J]. Corros. Sci., 2007, 49: 1266 |
| 16 | Ånmark N, Karasev A, Jönsson P G. The effect of different non-metallic inclusions on the machinability of steels [J]. Materials, 2015, 8: 751 |
| 17 | Wranglen G. Pitting and sulphide inclusions in steel [J]. Corros. Sci., 1974, 14: 331 |
| 18 | Wei J, Dong J H, Ke W, et al. Influence of inclusions on early corrosion development of ultra-low carbon Bainitic steel in NaCl solution [J]. Corrosion, 2015, 71: 1467 |
| 19 | Wang L W, Xin J C, Cheng L J, et al. Influence of inclusions on initiation of pitting corrosion and stress corrosion cracking of X70 steel in near-neutral pH environment [J]. Corros. Sci., 2019, 147: 108 |
| 20 | Gong Y, Yang C, Yao C, et al. Acidic/caustic alternating corrosion on carbon steel pipes in heat exchanger of ethylene plant [J]. Mater. Corros., 2011, 62: 967 |
| 21 | Shi J J, Sun W, Geng G Q. Corrosion resistances of passive films on low-carbon rebar and fine-grained rebar in alkaline media [J]. Acta Metall. Sin., 2011, 47: 449 |
| 21 | 施锦杰, 孙 伟, 耿国庆. 普通低碳钢与细晶粒钢钝化膜在碱性介质中的耐蚀性 [J]. 金属学报, 2011, 47: 449 |
| 22 | Fu H, Chen C Y, Li J Q, et al. Effect of sodium thiosulfate on corrosion behavior of Q235 steel in alkaline solution [J]. Hot Working Technol., 2017, 46(8): 87 |
| 22 | 付慧, 陈朝轶, 李军旗 等. 硫代硫酸钠对Q235钢碱性腐蚀行为的影响 [J]. 热加工工艺, 2017, 46(8): 87 |
| 23 | Li T S, Scully J R, Frankel G S. Localized corrosion: Passive film breakdown vs. pit growth stability: Part III. A unifying set of principal parameters and criteria for pit stabilization and salt film formation [J]. J. Electrochem. Soc., 2018, 165: C762 |
| 24 | Liu Y, Zong N F. Effects of Al-Mg alloy treatment on behavior and size of inclusions in SUH 409L stainless steel [J]. Metall. Res. Technol., 2018, 115: 111 |
| 25 | He B, Li J, Shi C B, et al. Effect of Mg addition on carbides in H13 steel during electroslag remelting process [J]. Metall. Res. Technol., 2018, 115: 501 |
| 26 | Pang Z X, Zhu R, Chen P D, et al. Formation of MgO-based inclusions during AOD and ladle treatment of Al-killed 2205 duplex stainless steel [J]. Metall. Res. Technol., 2017, 114: 211 |
| 27 | Sun H, Wu L P, Xie J B, et al. Inclusions modification and improvement of machinability in a non-quenched and tempered steel with Mg treatment [J]. Metall. Res. Technol., 2020, 117: 208 |
| 28 | Liu P, Zhang Q H, Li X R, et al. Insight into the triggering effect of (Al, Mg, Ca, Mn)-oxy-sulfide inclusions on localized corrosion of weathering steel [J]. J. Mater. Sci. Technol., 2021, 64: 99 |
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