研究论文

回火温度对1000 MPaNiCrMoV低碳合金钢微观组织和低温韧性的影响

  • 周成 ,
  • 赵坦 ,
  • 叶其斌 ,
  • 田勇 ,
  • 王昭东 ,
  • 高秀华
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  • 1.东北大学 轧制技术及连轧自动化国家重点实验室 沈阳 110819
    2.鞍钢集团 海洋装备用金属材料及其应用国家重点实验室 鞍山 114009
    3.江苏省(沙钢)钢铁研究院 张家港 215625
周 成,男,1985年生,博士生

收稿日期: 2021-04-07

  修回日期: 2021-12-06

  网络出版日期: 2021-12-16

基金资助

辽宁省科技重大专项项目(2020JH1/10100001);海洋装备用金属材料及其应用国家重点实验室开放课题项目

Effects of Tempering Temperature on Microstructure and Low-Temperature Toughness of 1000 MPa Grade NiCrMoV Low Carbon Alloyed Steel

  • Cheng ZHOU ,
  • Tan ZHAO ,
  • Qibin YE ,
  • Yong TIAN ,
  • Zhaodong WANG ,
  • Xiuhua GAO
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  • 1.State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819, China
    2.State Key Laboratory of Metal Material for Marine Equipment and Application, Ansteel Group Corporation, Anshan 114009, China
    3.Institute of Research of Iron and Steel, Sha-Steel, Zhangjiagang 215625, China
ZHAO Tan, senior engineer, Tel: (0412)6721020, E-mail: ansteel_zhaotan@163.com
YE Qibin, senior engineer, Tel: (0512)58953958, E-mail: yeqb-iris@shasteel.cn;

Received date: 2021-04-07

  Revised date: 2021-12-06

  Online published: 2021-12-16

Supported by

Major Research and Development Project of Liaoning Province(2020JH1/10100001);State Key Laboratory of Metal Material for Marine Equipment and Application

摘要

利用SEM、TEM、EBSD等技术手段研究了回火温度(450~650℃)对NiCrMoV低碳合金钢显微组织的影响,并通过拉伸和冲击实验测试其力学性能,同时利用相变仪和DICTRA模拟方法分别分析了两相区回火过程中奥氏体逆相变过程和合金元素的配分行为。结果表明,NiCrMoV低碳合金钢经热轧-在线淬火后的显微组织由板条马氏体和自回火马氏体组成。回火温度从450℃升高到550℃,马氏体板条发生回复,马氏体-奥氏体(M-A)组元逐渐分解;经两相区600℃回火后,在回火马氏体边界处形成了4.8% (体积分数)的残余奥氏体;提高两相区回火温度到650℃,显微组织由层状分布的新鲜马氏体和临界铁素体组成。随着回火温度升高,NiCrMoV低碳合金钢在-80℃的冲击功呈现先增加后降低的趋势,在600℃回火时达到峰值160 J;同时,NiCrMoV低碳合金钢在600℃回火时获得了最佳的强塑性匹配,屈服强度1030 MPa,抗拉强度1104 MPa,延伸率18%。相变仪分析结果表明NiCrMoV低碳合金钢经600℃回火后逆转变奥氏体全部保留到室温,而在650℃回火后逆转变奥氏体发生相变并转变成新鲜马氏体。DICTRA模拟结果证明奥氏体稳定化元素C、Ni和Mn在600℃等温回火过程中的富集程度要显著高于650℃等温回火。

本文引用格式

周成 , 赵坦 , 叶其斌 , 田勇 , 王昭东 , 高秀华 . 回火温度对1000 MPaNiCrMoV低碳合金钢微观组织和低温韧性的影响[J]. 金属学报, 2022 , 58(12) : 1557 -1569 . DOI: 10.11900/0412.1961.2021.00147

Abstract

The low carbon alloyed steel has been widely used in the shipbuilding and offshore structures owing to its high strength and toughness at low temperatures. To optimize the microstructure and mechanical properties of low carbon alloyed steel as well as investigate the relationship between them, this study focuses on the microstructure evolution and corresponding mechanical properties of a 1000 MPa grade NiCrMoV low carbon alloyed steel during tempering in the range of 450-650oC. Microstructures of lath martensite and autotempered martensite were obtained after hot rolling followed by direct water cooling to room temperature. The evolution of lath martensite and retained austenite on tempering was characterized using SEM and TEM. The distribution of the retained austenite was investigated using EBSD. The result shows that when the tempering temperature of the NiCrMoV low carbon alloyed steel is increased from 450oC to 550oC, the lath martensite recovers and the martensite-austenite component gradually decomposes. The retained austenite with 4.8% volume fraction was obtained after tempering at 600oC. The NiCrMoV low carbon alloyed steel obtained intercritical ferrite and fresh martensite when tempered at 650oC. The reverse transformation process of austenite was analyzed through a dilatometer curve. The partition behavior of alloying elements C, Ni, and Mn during intercritical tempering was analyzed kinetically through DICTRA simulation. An appropriate fraction of thermally stable retained austenite obtained at 600oC was attributed to the extent of partitioning of C, Ni, and Mn into the reversed austenite, which contributed to the best balance of strength-ductility-toughness properties. After direct quenching and tempering at 600oC, high yield strength of 1030 MPa with a high ductility of 18%, low yield to tensile ratio of 0.93, and excellent low-temperature toughness of 160 J at -80oC were obtained.

参考文献

1 Klemm-Toole J, Benz J, Thompson S W, et al. A quantitative evaluation of microalloy precipitation strengthening in martensite and bainite [J]. Mater. Sci. Eng., 2019, A763: 138145
2 Zhang G H, Cheng L, Li Y, et al. Progress on marine corrosion resistant steels [J]. Mater. China, 2014, 33: 426
2 张国宏, 成林, 李钰 等. 海洋耐蚀钢的国内外进展 [J]. 中国材料进展, 2014, 33: 426
3 Abdollah-Zadeh A, Belbasy M. Effects of Mn and Cu on the mechanical properties of a high strength low alloy NiCrMoV steel [J]. J. Mater. Sci. Technol., 2005, 21: 470
4 Salemi A, Abdollah-Zadeh A. The effect of tempering temperature on the mechanical properties and fracture morphology of a NiCrMoV steel [J]. Mater. Charact., 2008, 59: 484
5 Lu J, Yu H, Yang S F. Mechanical behavior of multi-stage heat-treated HSLA steel based on examinations of microstructural evolution [J]. Mater. Sci. Eng., 2021, A803: 140493
6 Zhang X J. Microhardness characterisation in developing high strength, high toughness and superior ballistic resistance low carbon Ni steel [J]. Mater. Sci. Technol., 2012, 28: 818
7 Chen Q Y, Ren J K, Xie Z L, et al. Correlation between reversed austenite and mechanical properties in a low Ni steel treated by ultra-fast cooling, intercritical quenching and tempering [J]. J. Mater. Sci., 2020, 55: 1840
8 Dhua S K, Mukerjee D, Sarma D S. Influence of tempering on the microstructure and mechanical properties of HSLA-100 steel plates [J]. Metall. Mater. Trans., 2001, 32A: 2259
9 Hou W, Liu Q D, Gu J F. Nano-sized austenite and Cu precipitates formed by using intercritical tempering plus tempering and their effect on the mechanical property in a low carbon Cu bearing 7 Ni steel [J]. Mater. Sci. Eng., 2020, A780: 139186
10 Liu D S, Cheng B G, Chen Y Y. Strengthening and toughening of a heavy plate steel for shipbuilding with yield strength of approximately 690 MPa [J]. Metall. Mater. Trans., 2013, 44A: 440
11 Otani K, Muraoka H, Tsuruta S, et al. Development of ultraheavy-gauge (210 mm thick) 800 N/mm2 tensile strength plate steel for racks of jack-up rigs [J]. Nippon Steel Tech. Rep., 1993, 58: 1
12 Dhua S K, Ray A, Sarma D S. Effect of tempering temperatures on the mechanical properties and microstructures of HSLA-100 type copper-bearing steels [J]. Mater. Sci. Eng., 2001, A318: 197
13 Kim J I, Morris J W. The composition of precipitated austenite in 5.5Ni steel [J]. Metall. Mater. Trans., 1981, 12A: 1957
14 Saastamoinen A, Kaijalainen A, Nyo T T, et al. Direct-quenched and tempered low-C high-strength structural steel: The role of chemical composition on microstructure and mechanical properties [J]. Mater. Sci. Eng., 2019, A760: 346
15 Xie Z J, Shang C J, Wang X L, et al. Microstructure-property relationship in a low carbon Nb-B bearing ultra-high strength steel by direct-quenching and tempering [J]. Mater. Sci. Eng., 2018, A727: 200
16 Hu J, Du L X, Dong Y, et al. Effect of Ti variation on microstructure evolution and mechanical properties of low carbon medium Mn heavy plate steel [J]. Mater. Charact., 2019, 152: 21
17 Jain D, Isheim D, Hunter A H, et al. Multicomponent high-strength low-alloy steel precipitation-strengthened by sub-nanometric Cu precipitates and M2C carbides [J]. Metall. Mater. Trans., 2016, 47A: 3860
18 Zou Y, Xu Y B, Hu Z P, et al. High strength-toughness combination of a low-carbon medium-manganese steel plate with laminated microstructure and retained austenite [J]. Mater. Sci. Eng., 2017, A707: 270
19 Wang M, Liu Z Y, Li C G. Correlations of Ni contents, formation of reversed austenite and toughness for Ni-containing cryogenic steels [J]. Acta Metall. Sin. (Engl. Lett.)., 2017, 30: 238
20 Kuzmina M, Ponge D, Raabe D. Grain boundary segregation engineering and austenite reversion turn embrittlement into toughness: Example of a 9 wt.% medium Mn steel [J]. Acta Mater., 2015, 86: 182
21 Hu B, Luo H W, Yang F, et al. Recent progress in medium-Mn steels made with new designing strategies, a review [J]. J. Mater. Sci. Technol., 2017, 33: 1457
22 Zou Y, Xu Y B, Wang G, et al. Improved strength-ductility-toughness balance of a precipitation-strengthened low-carbon medium-Mn steel by adopting intercritical annealing-tempering process [J]. Mater. Sci. Eng., 2021, A802: 140636
23 Wang D C, Cai Q W, Yu W, et al. Tempering microstructure and mechanical properties of an ultra high strength bainitic steel [J]. Trans. Mater. Heat Treat., 2013, 34(5): 143
23 万德成, 蔡庆伍, 余伟 等. 超高强贝氏体钢的回火组织与力学性能 [J]. 材料热处理学报, 2013, 34(5): 143
24 Srivatsa K, Srinivas P, Balachandran G, et al. Room temperature microstructure and property evaluation of a heat treated fully bainitic 20CrMoVTiB410 steel [J]. JOM, 2016, 68: 2704
25 Lee S, De Cooman B C. Annealing temperature dependence of the tensile behavior of 10 pct Mn multi-phase TWIP-TRIP steel [J]. Metall. Mater. Trans., 2014, 45A: 6039
26 Seo E J, Cho L, Estrin Y, et al. Microstructure-mechanical properties relationships for quenching and partitioning (Q&P) processed steel [J]. Acta Mater., 2016, 113: 124
27 Han J B, Lee S J, Jung J G, et al. The effects of the initial martensite microstructure on the microstructure and tensile properties of intercritically annealed Fe-9Mn-0.05C steel [J]. Acta Mater., 2014, 78: 369
28 Cao W Q, Wang C, Shi J, et al. Microstructure and mechanical properties of Fe-0.2C-5Mn steel processed by ART-annealing [J]. Mater. Sci. Eng., 2011, A528: 6661
29 Wang Z H, Hui W J, Xie Z Q, et al. Effects of tempering temperature on microstructure and mechanical properties of a Mn-Cr type bainitic forging steel [J]. Acta Metall. Sin., 2020, 56: 1441
29 王占花, 惠卫军, 谢志奇 等. 回火对钒钛微合金化Mn-Cr系贝氏体型非调质钢组织和性能的影响 [J]. 金属学报, 2020, 56: 1441
30 Li Z J, Xiao N M, Li D Z, et al. Influence of microstructure on impact toughness of G18CrMo2-6 steel during tempering [J]. Acta Metall. Sin., 2014, 50: 777
30 李振江, 肖纳敏, 李殿中 等. G18CrMo2-6钢回火组织及冲击韧性研究 [J]. 金属学报, 2014, 50: 777
31 Yan P, Liu Z D, Bao H S, et al. Effect of tempering temperature on the toughness of 9Cr-3W-3Co martensitic heat resistant steel [J]. Mater. Des., 2014, 54: 874
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