Fe-Co-Ni系组合合金热等静压高通量制备方法初探
收稿日期: 2021-02-07
修回日期: 2021-04-03
网络出版日期: 2021-04-30
基金资助
国家重点研发计划项目(2017YFB0701900)
First Exploration of Hot Isostatic Pressing High-Throughput Synthesis on Fe-Co-Ni Combinatorial Alloy
Received date: 2021-02-07
Revised date: 2021-04-03
Online published: 2021-04-30
Supported by
National Key Research and Development Program of China(2017YFB0701900)
提出基于热等静压工艺的高通量制备新方法，即采用纯Ni和Ti作为蜂巢结构骨架材料，内含不同组元合金粉末的成分梯度设计新思路，成功一次性制备出含有19种不同化学成分的Fe-Co-Ni组合块体合金。高通量成分与组织结构分析表明：蜂巢骨架内各区域成分均匀，含量符合设计要求；混粉均扩散形成合金相；块体合金内部致密度良好，无宏观缺陷。通过对高通量制备Fe-Co-Ni组合试样硬度的分析，探讨了合金化作用机理及其对力学行为的影响规律。铁基和镍基材料均是以固溶强化和第二相强化为主，钴基材料以双相固溶强化为主。对于铁基材料，Ni的强化效果优于Co；对于镍基材料，Fe的强化效果优于Co；对于钴基材料，Ni的强化效果优于Fe。
赵雷 , 王辉 , 杨丽霞 , 陈学斌 , 郎润秋 , 贺林峰 , 陈东风 , 王海舟 . Fe-Co-Ni系组合合金热等静压高通量制备方法初探[J]. 金属学报, 2021 , 57(12) : 1627 -1636 . DOI: 10.11900/0412.1961.2021.00070
Material genome engineering (MGE) is an advanced research concept that integrates high-throughput computing, high-throughput experiment (synthesis and characterization), and a special database. The purpose of MGE is to adopt an efficient and economical method to accelerate the correlation between the composition, microstructure, and performance. However, low composition, small size, characterization difficulty, and high cost limit its application in the high-throughput synthesis of a bulk metal. A new high-throughput synthesis based on hot isostatic pressing (HIP), which uses a honeycomb structure sleeve made of pure Ni and Ti foils, was proposed. A combinatorial-bulk-alloy with 19 gradient components was HIPed by filling different mixtures of pure Fe, Co, and Ni powders into each cell of the honeycomb sleeve. The high-throughput characterization of the composition and microstructure showed that the composition of each cell was homogeneous and in accordance with the design, the mixed powders diffused to the alloy phases, and the bulk alloy had good density and without macroscopic defects. The mechanism of alloying and its effect on the mechanical behavior was discussed by investigating the microhardness of Fe-Co-Ni combinatorial alloy. Fe- and Ni-based alloys were solid solution and second phase strengthened, whereas Co-based alloy was two-phase solid solution strengthened. The strengthening effect of Ni was better than that of Co for Fe-based alloy. The strengthening effect of Fe was better than that of Co for Ni-based alloy. The strengthening effect of Ni was better than that of Fe for Co-based alloy.
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