研究论文

高钨镍基高温合金K416BW相的析出行为

  • 朱玉平 ,
  • 盛乃成 ,
  • 谢君 ,
  • 王振江 ,
  • 荀淑玲 ,
  • 于金江 ,
  • 李金国 ,
  • 杨林 ,
  • 侯桂臣 ,
  • 周亦胄 ,
  • 孙晓峰
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  • 1.中国科学院金属研究所 师昌绪先进材料创新中心 沈阳 110016
    2.沈阳工业大学 材料科学与工程学院 沈阳 110870
    3.中国科学院轻型动力创新研究院 北京 100190
朱玉平,男,1996年生,硕士生

收稿日期: 2020-05-27

  修回日期: 2020-09-01

  网络出版日期: 2020-11-04

基金资助

国家自然科学基金项目(51971214);中国科学院引才计划项目(51771191);中国科学院轻型动力创新研究院创新引导基金项目(CXYJJ20-QN-02)

Precipitation Behavior of W-Rich Phases in a High W-Containing Ni-Based Superalloys K416B

  • Yuping ZHU ,
  • SHENG Naicheng ,
  • Jun XIE ,
  • Zhenjiang WANG ,
  • Shuling XUN ,
  • Jinjiang YU ,
  • Jinguo LI ,
  • Lin YANG ,
  • Guichen HOU ,
  • Yizhou ZHOU ,
  • Xiaofeng SUN
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  • 1.Shi -Changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    2.School of Materials Science and Technology, Shenyang University of Technology, Shenyang 110870, China
    3.Innovation Academy for Light-Duty Gas Turbine, Chinese Academy of Sciences, Beijing 100190, China

Received date: 2020-05-27

  Revised date: 2020-09-01

  Online published: 2020-11-04

Supported by

National Natural Science Foundation of China(51971214);Talents Program of Chinese Academy of Sciences(51771191);Innovation Science Foundation from Innovation Academy for Light-Duty Gas Turbine, Chinese Academy of Sciences(CXYJJ20-QN-02)

摘要

研究了K416B合金中富W相的析出行为与合金浇注温度和凝固速率的关系。结果表明,在相同冷却速率下,合金的浇注温度由1500℃降低到1450℃时,晶粒尺寸明显减小。在不同浇注温度下,合金中均有块状α-W相在残余共晶中析出,α-W相形貌差别不大。合金的残余共晶中存在大尺寸的M6C相,而残余共晶的边缘处有小尺寸的M6C相。高凝固速率时,合金中富W相数量减少、尺寸减小,表明富W相析出受到明显抑制。对于铸造高钨镍基高温合金,选择合适的浇注温度以及保温体系加快凝固初期的冷却速率,可以控制富W相的析出和转变,从而优化合金性能。

本文引用格式

朱玉平 , 盛乃成 , 谢君 , 王振江 , 荀淑玲 , 于金江 , 李金国 , 杨林 , 侯桂臣 , 周亦胄 , 孙晓峰 . 高钨镍基高温合金K416BW相的析出行为[J]. 金属学报, 2021 , 57(2) : 215 -223 . DOI: 10.11900/0412.1961.2020.00180

Abstract

The high temperature strength of Ni-based cast superalloys can be significantly improved by adding tungsten (W), a solid solution strengthening element. Hence, superalloys with high W content have been developed as key materials for the preparation of aircraft engine blades. However, the high segregation coefficient of W results in inconsistent composition and microstructure during the solidification process, which can be difficult to eliminate via heat treatment leading to deteriorated mechanical properties. The Ni-based superalloy K416B contains approximately 16.5%W (mass fraction) and exhibits a high tendency to precipitate W-rich phases, such as the α-W and M6C phases, which not only consume a large amount of W in the matrix but also reduce the solid solution strengthening ability of the alloy. W-rich precipitates also become the origin and propagation paths of cracks during stress-rupture testing. Much research on high W-containing, Ni-based superalloys has focused on the effects of W content on W-rich phase formation and mechanical properties. However, the roles of casting temperature and cooling rate on the formation of the W-rich phase are still unclear. In this work, five groups of K416B alloy test bars with the same composition were prepared with different processes. Three casting temperatures were chosen, and the cooling rate was controlled by burying sand in the thick shell and single shell, respectively. The relationship between the precipitation behavior of the W-rich phase in the K416B alloy and casting temperature, and solidification rate under different casting processes were analyzed using SEM and EDS. When the casting temperature is lowered from 1500°C to 1450°C, the grain size is significantly reduced. Results show massive α-W phases in the residual eutectic of the alloy at different casting temperatures, and the morphology of the α-W phase show few differences. The larger M6C phase in the alloy exists with residual eutectic, and the small M6C phase is embedded at the edge of the residual eutectic. At a high solidification rate, the precipitation of the W-rich phase is inhibited, which is primarily manifested by the decreased number and size of the W-rich phase in the alloy. When casting high W-containing Ni-based superalloys, choosing an appropriate casting temperature and adopting an appropriate heat preservation system to accelerate the cooling rate during solidification will affect the precipitation and transformation of W-rich phases, and optimize the properties of the alloy.

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