镁合金焊缝液化裂纹敏感性及预测方法探究

  • 陈树君 ,
  • 王宣 ,
  • 袁涛 ,
  • 李晓旭
展开
  • 北京工业大学机电学院汽车结构部件先进制造技术教育部工程研究中心 北京 100124

作者简介 陈树君,男,1971年生,教授,博士

收稿日期: 2018-04-19

  网络出版日期: 2018-08-30

基金资助

国家自然科学基金项目No.51704013,北京市教委科研计划一般项目No.KM201810005016和中国博士后科学基金项目No.2016M600881

Research on Prediction Method of Liquation Cracking Susceptibility to Magnesium Alloy Welds

  • Shujun CHEN ,
  • Xuan WANG ,
  • Tao YUAN ,
  • Xiaoxu LI
Expand
  • Engineering Research Center of Advanced Manufacturing Technology for Automotive Components, Ministry of Education, Beijing University of Technology, Beijing 100124, China

Received date: 2018-04-19

  Online published: 2018-08-30

Supported by

Supported by National Natural Science Foundation of China (No.51704013), Beijing Municipal Education Commission General Research Project (No.KM201810005016) and China Postdoctoral Science Foundation (No.2016M600881)

摘要

以AZ31与AZ91镁合金为母材,AZ61与AZ92镁合金为填充焊丝,利用冷金属过渡焊接(CMT)方法进行横向拘束环行焊缝裂纹实验,探究AZ系列镁合金部分熔化区的液化现象,并结合液化裂纹产生机理提出一种定性判断镁合金液化裂纹敏感性的方法。结果表明,焊接过程中,AZ91镁合金焊缝边缘发生了γ (Mg17Al12)相与富Mg α相的共晶反应,产生了液相,形成了部分熔化区;在AZ31镁合金中不存在γ (Mg17Al12)相,液化现象不明显,部分熔化区较小。同时,提出了基于二元合金相图的镁合金液化裂纹敏感性判断方法,以判断镁合金母材和焊丝成分对焊缝部分熔化区液化裂纹敏感性的影响规律,即,母材为AZ91时的液化裂纹敏感性比母材为AZ31时更高,焊丝为AZ92时的液化裂纹敏感性较焊丝为AZ61时更低。

本文引用格式

陈树君 , 王宣 , 袁涛 , 李晓旭 . 镁合金焊缝液化裂纹敏感性及预测方法探究[J]. 金属学报, 2018 , 54(12) : 1735 -1744 . DOI: 10.11900/0412.1961.2018.00151

Abstract

Magnesium alloys has a wide application prospect due to their good properties, such as high specific strength and specific stiffness, but the susceptibility of liquation cracking is also pretty high. The liquation in partially melted zone of AZ-series magnesium alloys were investigated with circular-patch welding test. The AZ91, AZ31 base alloys were welded with AZ61 and AZ92 filler wires by using the cold metal transter metal inert-gas (CMT-MIG) welding. The results show that, the liquation occurred along the weld edge of AZ91 with the eutectic reaction occurring between γ (Mg17Al12) phase and Mg-rich phase. The liquation susceptibility of AZ31 was pretty low as γ (Mg17Al12) was not present in base metal of AZ31. Meanwhile, a new method for predicting liquation cracking based on binary phase diagram was proposed. When the initial solidification temperature of weld is higher and the solidification temperature range of weld is shorter than those of base metal, the liquation crack susceptibility of weld is mostly higher. When the initial solidification temperature of weld is close to or below that of base metal, and the solidification temperature range of weld is close to or longer than that of base metal, the liquation cracking susceptibility of weld is lower. This method worked well on predicting the effect of composition of base metal and filler wires on liquation cracking, and the predicting results are consistent with the experimental results. That is, the liquation cracking susceptibility is higher with AZ91 base metal used than that with AZ31 base metal. And, the liquation cracking susceptibility is lower with AZ92 filler wire than that with AZ61 filler wire.

参考文献

[1] Froes F H, Eliezer D, Aghion E.The science, technology, and applications of magnesium[J]. JOM, 1998, 50(9): 30
[2] Ishihara S, Nan Z Y, Goshima T. Effect of microstructure on fatigue behavior of AZ31 magnesium alloy [J]. Mater. Sci. Eng., 2007, A468-470: 214
[3] Li W, Zhou H, Zhou W, et al.Effect of cooling rate on ignition point of AZ91D-0.98 wt.% Ce magnesium alloy[J]. Mater. Lett., 2007, 61: 2772
[4] Montemor M F, Sim?es A M, Carmezim M J.Characterization of rare-earth conversion films formed on the AZ31 magnesium alloy and its relation with corrosion protection[J]. Appl. Surf. Sci., 2007, 253: 6922
[5] Munitz A, Cotler C, Stern A, et al.Mechanical properties and microstructure of gas tungsten arc welded magnesium AZ91D plates[J]. Mater. Sci. Eng., 2001, A302: 68
[6] Rethmeier M, Kleinpeter B, Wohlfahrt H.MIG welding of magnesium alloys metallographic aspects[J]. Weld. World, 2004, 48: 28
[7] Yu Z H, Yan H G, Yin X Y, et al.Liquation cracking in laser beam welded joint of ZK60 magnesium alloy[J]. Trans. Nonferrous Met. Soc. China, 2012, 22: 2891
[8] Ma B X, Zhao J X, Wang L P, et al.Research progress of welding hot crack of magnesium alloys[J]. Mater. Rev., 2016, 30(3): 81(马宝霞, 赵建勋, 王丽萍等. 镁合金焊接热裂纹的研究进展[J]. 材料导报, 2016, 30(3): 81)
[9] Zhou W, Long T Z, Mark C K.Hot cracking in tungsten inert gas welding of magnesium alloy AZ91D[J]. Mater. Sci. Technol., 2007, 23: 1294
[10] Zhao X X.Liquefaction crack of welding[J]. Machinery, 1981,(11): 19(赵晓星. 焊接液化裂纹 [J]. 机械, 1981, (11): 19)
[11] Lippold J C, translated by Qu Z X, Zhang H Q, Wang D P. Welding Metallurgy and Weldability [M]. Beijing: Machinery Industry Press, 2017: 34(Lippold J C著, 屈朝霞, 张汉谦, 王东坡译. 焊接冶金与焊接性 [M]. 北京: 机械工业出版社, 2017: 34)
[12] Huang C, Kou S. Partially melted zone in aluminum welds—Liquation mechanism and directional solidification [J]. Weld. J., 2000, 79: 113-s
[13] Huang C, Kou S. Liquation cracking in full-penetration Al-Cu welds [J]. Weld. J., 2004, 83: 50-s
[14] Huang C, Kou S. Liquation cracking in full-penetration Al-Mg-Si welds [J]. Weld. J., 2004, 83: 111-s
[15] Cao G, Kou S. Predicting and reducing liquation-cracking susceptibility based on temperature vs. fraction solid [J]. Weld. J., 2006, 85: 9-s
[16] Sun D X.Study on weldability of magnesium alloys (AZ91D and AZ31B) [D]. Changchun: Jilin University, 2008(孙德新. 镁合金(AZ91D、AZ31B)焊接性的研究 [D]. 长春: 吉林大学, 2008)
[17] Yuan T.Study on welding metallurgy process and microstructure of magnesium welds with the external energy field [D]. Tianjin: Tianjin University, 2016(袁涛. 基于外加能量场的镁合金焊接冶金过程及微观组织研究 [D]. 天津: 天津大学, 2016)
[18] Yuan T, Chai X, Luo Z, et al.Predicting susceptibility of magnesium alloys to weld-edge cracking[J]. Acta Mater., 2015, 90: 242
[19] Chai X, Yuan T, Kou S. Liquation and liquation cracking in partially melted zones of magnesium welds [J]. Weld. J., 2016, 95: 57-s
[20] Yuan T, Luo Z, Liu Y Y.Study on sensitivity of magnesium alloy weld to liquefaction crack[J]. Weld. Technol., 2016, 45(12): 14(袁涛, 罗震, 刘亚云. 镁合金焊缝液化裂纹敏感性研究[J]. 焊接技术, 2016, 45(12): 14)
[21] Kou S.Welding Metallurgy[M]. 2nd Ed., Hoboken, NJ: John Wiley & Sons, 2003: 301
[22] Flemings M C.Solidification Processing[M]. New York: McGraw-Hill, 1974: 15
[23] Kou S, Sun D K.Fluid flow and weld penetration in stationary arc welds[J]. Metall. Trans., 1985, 16A: 203
[24] Kou S, Wang Y H.Computer simulation of convection in moving arc weld pools[J]. Metall. Trans., 1986, 17A: 2271
[25] Tsai M C, Kou S.Marangoni convection in weld pools with a free surface[J]. Int. J. Numer. Methods Fluids, 1989, 9: 1503
文章导航

/