微合金化4043铝合金焊丝焊接接头的组织与性能
收稿日期: 2013-05-02
修回日期: 2013-06-19
网络出版日期: 2013-08-11
基金资助
国家自然科学基金项目51004036和教育部基本科研业务费项目N110408005资助
MICROSTRUCTURE AND PROPERTY OF WELDING JOINT WELD WITH MICRO-ALLOYING 4043 WELDING WIRE
Received date: 2013-05-02
Revised date: 2013-06-19
Online published: 2013-08-11
在传统4043铝合金焊丝基础上, 通过单独和复合添加Mg, Zr和Sc对4043铝合金焊丝进行微合金化,使微合金化焊丝焊后的焊接接头可热处理强化, 并对其热处理工艺进行优化.使用传统4043铝合金焊丝和微合金化后的铝合金焊丝进行焊接实验.对比焊后焊接接头的显微组织和力学性能发现, 添加0.25% Mg(质量分数)可以改善铝合金焊丝焊后的焊接接头的显微组织,提高焊接接头的抗拉和屈服强度, 抗拉强度提高10%, 屈服强度提高12%, 而延伸率基本保持不变.经530℃, 2 h+170℃, 6 h热处理后, 焊接接头的抗拉强度提高54%,屈服强度提高105%. 焊丝中添加Sc和Zr可以明显细化焊缝组织的晶粒,增加热处理后强化相析出数量, 提高焊接接头的抗拉和屈服强度.
赵志浩 , 徐振 , 王高松 , 崔建忠 . 微合金化4043铝合金焊丝焊接接头的组织与性能[J]. 金属学报, 2013 , 49(8) : 946 -952 . DOI: 10.3724/SP.J.1037.2013.00239
Aluminum alloys have been widely used in civil fields and war industry as structural materials due to their good corrosion resistance, electrical conductivity, thermal conductivity and high specific strength. But there is a serious problem of welding joints softening in welding process, which limits greatly the application of aluminum alloys. It is found that improving the composition of aluminum alloy welding wire can refine grains and enhance the mechanical properties of welding joints. Of all micro-alloying additions to aluminum, Sc offers the greatest potential for developing new light weight structural materials with excellent mechanical properties, good welding performance, desirable corrosion and creep resistance, due to the formation of extremely fine, coherent Al3Sc particles, which can effectively refine grains and inhibit recrystallization. This aspect permits to increase the possible use of commercial aluminum alloys. The strengthening mechanism is due to the coherent thermodynamically stable particles with ordered L12 structure. Addition of sufficient amount of magnesium can enhance the nucleation rate of Al3Sc. It was shown that clusters of Mg atoms were found at the center of Al3Sc particles, suggesting that Mg promotes nucleation of these particles. Moreover, addition of zirconium substitutes for scandium(for up to half of the scandium atoms) to form Al3(Sc, Zr) precipitates, which are more resistant to coarsening than binary Al3Sc precipitates. Micro--alloying aluminum alloy welding wires which can be strengthened by heat treatment were designed by adding Mg, Sc and Zr to the traditional 4043 aluminum alloy welding wire, and the heat treatment process was optimized. Welding experiment was carried out using the traditional 4043 aluminum alloy welding wire and micro-alloying aluminum alloy welding wires. After comparing the microstructures and mechanical properties of welding joints, it was found that the mechanical properties of welding joints could be improved when adding 0.25% Mg to the 4043 aluminum alloy welding wire. The yield strength increased by 12% and the tensile strength increased by 10%, while the elongation remained constant substantially. After 530℃, 2 h+170℃, 6 h heat treatment, the yield strength of the welding joints increased by 105% and the tensile strength increased by 54%. The additions of Sc and Zr to the welding wires resulted in the finer grains significantly, raising the number of strengthening phase and increasing the strength of the welding joints.
[1] Zhou W S, Yao J S. Welding of Aluminum and It's Alloy.Beijing: China Machine Press, 2006: 1
(周万盛, 姚君山. 铝及铝合金的焊接. 北京: 机械工业出版社, 2006: 1)/
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