层片状珠光体组织奥氏体化速率的计算
收稿日期: 2013-02-02
修回日期: 2013-04-14
网络出版日期: 2013-07-11
基金资助
国家自然科学基金资助项目51071089
CALCULATION OF AUSTENIZATION RATE OF LAMELLAR PEARLITE
Received date: 2013-02-02
Revised date: 2013-04-14
Online published: 2013-07-11
层片状珠光体奥氏体化过程相对于球化珠光体的奥氏体化更复杂,由于沿垂直片层方向和沿片层方向的长大速率不同, 需将奥氏体长大沿这2个方向分别处理.利用Thermo Calc软件计算初始组织的平衡成分, 建立单片层模型.通过DICTRA软件模拟垂直片层方向长大的规律, 对比垂直方向长大的抛物线规律,推算Fe-C-M(M=Mn,Cr)合金体系奥氏体化的抛物线生长速率系数.在沿片层方向, 通过简化近似, 并基于组织形貌观察结果, 按照抛物线状界面假设构建长大模型.针对Fe-C二元合金推导了沿片层方向长大的一般式, 并对界面形状进行修正.当假定界面形状达到稳定抛物线形状, 可以通过观察组织形貌得到抛物线因子p和片层厚度λ,代入一般式确定沿片层长大速率. 此外综合考虑界面能的影响, 定性阐释了对称抛物线状界面的形成原因.
杨泽南 , 杨志刚 , 夏苑 , 张弛 . 层片状珠光体组织奥氏体化速率的计算[J]. 金属学报, 2013 , 49(7) : 890 -896 . DOI: 10.3724/SP.J.1037.2012.00076
In the field of phase transformation in steels, much attention has been paid to the austenite decomposition transformation, while austenization has not been vastly investigated. However, most industrial heat treatment is related to this process, which is strongly influenced by initial microstructure. The austenization of lamellar pearlite is relatively complicated compared with spheroidized pearlite due to that in spheroidized pearlite, the angular component can be neglected, so only radius growth is considered. During the past years, much work has been done for austenite's one dimensional growth in spheroidized pearlite. However, less attention has been paid to the austenization of lamellar pearlite, which is a two dimensional growth process. Since the growth rates are different along parallel direction and vertical direction to the lamellar, it is necessary to treat growth behaviors individually in these two directions. In order to further investigate effects of substitutional alloying elements, an Fe-0.6C binary alloy and Fe-0.6C-1M (M=Mn, Cr) ternary alloys were studied. Equilibrium composition and thickness ratio of initial ferrite/cementite mixture microstructure was calculated with software Thermo Calc, and a single-layer structure model is employed. Growth of austenite vertical to lamellar direction is simulated by software DICTRA. It is found that ferrite dissolution was controlled by carbon diffusion in Fe-0.6C-1Mn alloy in 1073 K, while that of Fe-0.6C-1Cr alloy was controlled by Cr diffusion. The simulation results qualitatively agreed with experimental observation result. Compared with the parabolic growth pattern, austenite's parabolic growth coefficient is calculated for various alloys. For growth along lamellar direction, parabolic shape phase boundary is deduced based on a simplified assumption and microstructure observation. A general form of growth rate in this direction is derived for Fe--C binary system, and phase boundary shape is also modified to some extent. If a stable parabolic shape interface is reached, the growth rate parallel to the lamellar direction can also be derived for certain values of parabolic shape parameter p and lamellar spacing λ, which can be decided by microstructure observation. Given the pearlite colony size and ignoring the influence of nucleation incubation, it takes 0.053 s for a pearlite colony to transform to austenite, which is consistent with that pearlite austenization is a relatively fast process. In addition, taking interfacial energy into consideration, the formation of symmetric parabolic phase boundary is rationalized.
Key words: phase transformation; lamellar pearlite; austenisation; kinetics; alloying element
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