研究了Al-6.3Zn-2.8Mg-1.8Cu铸造铝合金的组织和室温力学性能. 研究表明,在金属型铸造条件下, Al-6.3Zn-2.8Mg-1.8Cu合金的铸态组织为近等轴晶,相组成为α(Al)基体、枝晶间α(Al)+η(MgZn2)共晶、晶内游离η相(MgZn2)、少量T相(Mg3ZnxCu3-xAl2)及少量颗粒状Al7Cu2Fe. 固溶处理后, 原铸态组织中的η(MgZn$_{2}$)相大部分溶解消失, 但形成新的沿晶界分布的S相(Al2CuMg).实验确定了固溶态Al-6.3Zn-2.8Mg-1.8Cu合金较优的单级和双级时效工艺. 与单级时效工艺相比, 采用双级时效工艺处理后, 抗拉强度由480 MPa增加至490 MPa,延伸率由0.2%增加至2.2%.
The microstructures and room temperature mechanical properties of metal–mold– casting aluminum alloy Al–6.3Zn–2.8Mg–1.8Cu were studied. It was found that the microstructure of the as–cast experimental alloy consists of near equiaxed α(Al) matrix, α(Al)+η(MgZn2) eutectic and little Al7Cu2Fe particle phase. The phase constitution of the quenched experimental alloy was changed, the η phase was dissolved into α(Al) matrix and tended to disappear, however a new phase, S(Al2CuMg), appeared, which still mainly distributed along the α(Al) grain boundary. The optimum single–aging process parameters were determined by investigating age hardening response of the experimental alloy. It was found that the double–aging process could make the tensile strength of the experimental alloy increase from 480 MPa to 490 MPa, and the elongation from 0.2% to 2.2%,comparing with the single–aging process.
[1] Heinz A, Haszler A, Keidel C, Moldenhauer S. Mater Sci Eng, 2000; A280: 102
[2] Srivatsan T S. J Mater Sci, 1992; 27: 4772
[3] Zakharov V V, Rostova T D. Met Sci Heat Treat, 1995; 37(5–6): 203
[4] Mukhopadhyay A K, Reddy G M, Prasad K S, Varma V K, Mondac C. In: Nie J F, Morton A J, Muddle B C, eds., Proc 9th Int Conf on Aluminium Alloys, Australia: Institute
of Materials Engineering Australia Ltd, 2004: 883
[5] Wang H B, Huang J F, Yang B, Zhang J S, Zhang Y A, Xiong B Q. Mater Rev, 2003; 17(9): 1
(王洪斌, 黄进峰, 杨滨, 张济山, 张永安, 熊柏青. 材料导报, 2003; 17(9): 1)
[6] Chen C Q. Chin J Nonferrour Met, 2002; 12(3): 22
(陈昌麒. 中国有色金属学报, 2002; 12(3): 22)
[7] Chen K H, Liu H W, Zhang Z, Li S, Todd R I. J Mater Process Technol, 2003; 142: 190
[8] Mondal C, Mukhopadhyay A K. Mater Sci Eng, 2005; A391: 367
[9] Xie F Y, Yan X Y, Ding L, Zhang F, Chen S L, Chu M G, Chang Y A. Mater Sci Eng, 2003; A355: 144
[10] Manish D D. PhD Thesis, Georgia Institute of Technology, 2000
[11] Fan X G. PhD Thesis, Harbin Institute of Technology, 2007
(樊喜刚. 哈尔滨工业大学博士学位论文, 2007)
[12] Fan X G, Jiang D M, Meng Q C, Zhong L. Mater Lett, 2006; 60: 1475
[13] Starink M J, Wang S C. Acta Mater, 2003; 51: 5131
[14] Poole W J, Sæter J A, Skjervold S, Watercoo G. Metall Mater Trans, 2000; 31A: 2327
[15] Starink M J, Li X M. Metall Mater Trans, 2003; 34A: 899
[16] You W, Lin S Y. Alum Fabr, 1999; 22(1): 4
(游文, 林顺岩. 铝加工, 1999; 22(1): 4)
[17] Si N C, Fu M X. Nonferrous Metal Material and Preparation. Beijing: Chemical Industry Press, 2006: 36
(司乃潮, 傅明喜. 有色金属材料及制备. 北京: 化学工业出版社, 2006: 36)
[18] Li Y Y, Guo GW, Luo Z Q, Long Y. Spec Cast Nonferrous Alloys, 2000; 6: 45
(李元元, 郭国文, 罗宗强, 龙雁. 特种铸造及有色合金, 2000; 6: 45)
[19] Li N K, Cui J Z. Light Alloy Fabr Technol, 2008; 36(1): 5
(李念奎, 崔建忠. 轻合金加工技术, 2008; 36(1): 5)
[20] Zhang B C. Nonferrous Metal and Heat–treatment. Xi’an: NWPU Industry Press, 1993: 62
(张宝昌. 有色金属及其热处理. 西安: 西北工业大学出版社, 1993: 62)
[21] Sheppard T. Extrusion of Aluminium Alloy. London: Kluwer Academic Publisher, 1999: 23
[22] Alekseev A A, Fridlyander I N, Berg L B. Mater Sci Forum, 2002; 396–342: 821
[23] Rokhlin L L, Dobatkina T V, Bochvar N R, Lysova E V. J Alloys Compd, 2004; 367: 10
[24] Metallographic Atlas Compilation Group. Wrought Aluminum Alloy Metallographic Atlas. Beijing: Metallurgical Industry Press, 1975: 157
(金相图谱编写组. 变形铝合金金相图谱. 北京: 冶金工业出版, 1975: 157)
[25] Ding H L, Xin Z H. Practical Aluminum, Copper and Its Alloys Heat Treatment and Metallurgical Failure Analysis. Beijing: Machinery Industry Press, 2008: 102
(丁惠麟, 辛智华. 实用铝、铜及其合金金相热处理和失效分析. 北京: 机械工业出版社, 2008: 102)
[26] Lu S S, Gu K D, Zheng L S. Nonferrous Casting Alloys and Melting. Beijing: National Defense Industry Press, 1983: 52
(陆树荪, 顾开道, 郑来苏. 有色铸造合金及熔炼. 北京: 国防工业出版社, 1983: 52)