分别以预合金粉末和混合元素粉末为原料进行激光多层沉积Ti-6A-4V合金, 采用XRD研究了预合金粉末、混合元素粉末和沉积试样的相组成,采用金相显微镜研究了沉积试样的凝固组织. 结果表明, 预合金法激光多层沉积Ti-6Al-4V合金的凝固组织由外延生长的柱状晶组成,且随激光功率的提高, 合金凝固组织倾向于由柱状晶转变为等轴晶; 随着激光功率由1600 W增加至2700 W, 混合元素法激光多层沉积Ti-6Al-4V合金的凝固组织则由粗大等轴晶逐渐转变为外延生长的柱状晶.扫描速率对合金凝固组织的影响较小. 对混合焓对合金凝固组织的影响进行了讨论.
XRD and OM were used to study the phase constitution and solidified structure of the Ti–6Al–4V alloys prepared by laser multi–layer deposited pre–alloyed powder and blended elemental powder. It was found that the deposited layer obtained by using the pre–alloyed powder consists mainly of the epitaxial columnar grains, and the solidified structures change from the columnar grains to the equiaxed grains with increasing laser power. Meanwhile, the solidified structures of the deposited layer obtained by using the blended elemental powders change from large equiaxed grains to epitaxial columnar grains with increasing laser power from 1600 W to 2700 W. Laser scanning velocity has little effect on the morphology of the prior grains in the deposited layer obtained by using the blended elemental powders. The influence of mixing enthalpy on the structures of Ti–6Al–4V alloy was discussed also.
[1] Huang W D, Lin X, Chen J, Liu Z X, Li Y M. Laser Solid Forming Technology. Xi’an: Northwestern Polytechnical University Press, 2007: 1
(黄卫东, 林 鑫, 陈静, 刘振侠, 李延民. 激光立体成形. 西安: 西北工业大学出版社, 2007: 1)
[2] Collins P C, Banerjee R, Banerjee S, Fraser H L. Mater Sci Eng, 2003; A352: 118
[3] Banerjee R, Collins P C, Bhattacharyya D, Banerjee S, Fraser H L. Acta Mater, 2003; 51: 3277
[4] Banerjee R, Bhattacharyya D, Collins P C, Viswanathan G B, Fraser H L. Acta Mater, 2004; 52: 377
[5] Genc A, Banerjee R, Hill D, Fraser H L. Mater Lett, 2006; 60: 859
[6] Nag S, Banerjee R, Fraser H L. Acta Biomater, 2007; 3: 369
[7] Xu X J, Lin X, Huang W D, Wang L. Acta Metall Sin, 2010; 46: 1081
(许小静, 林 鑫, 黄卫东, 王亮. 金属学报, 2010; 46: 1081)
[8] Xu X J, Lin X, Yang M C, Chen J, Huang W D. Acta Metall Sin, 2008; 44: 1013
(许小静, 林 鑫, 杨模聪, 陈静, 黄卫东. 金属学报, 2008; 44: 1013)
[10] Tan H, Chen J, Zhang F Y, Lin X, Huang W D. Rare Met Mater Eng, 2009; 38: 574
(谭华, 陈静, 张凤英, 林鑫, 黄卫东. 稀有金属材料与工程, 2009; 38: 574)
[11] Tan H, Chen J, Lin X, Zhang F Y, Huang W D. J Mater Process Technol, 2008; 198: 454
[12] Lin X, Li Y M, Wang M, Feng L P, Chen J, Huang W D. Sci China, 2003; 33E: 577
(林鑫, 李延民, 王猛, 冯莉萍, 陈静, 黄卫东. 中国科学, 2003; 33E: 577)
[13] Zhang B W, HuW Y, Shu X L. Theory of Embedded Atom Method and Its Application to Materials Science: Atomic Scale Materials Design Theory. Changsha: Hunan University
Press, 2003: 1
(张邦维, 胡望宇, 舒小林. 嵌入原子方法理论及其在材料科学中的应用: 原子尺度材料设计理论. 长沙: 湖南大学出版社, 2003: 1)
[14] Guo J J, Su Y Q. Analysis of Thermodynamics and Kinetics in Melting Process of Titanium Alloy. Harbin: Harbin Institute of Technology Press, 1998: 46
(郭景杰, 苏彦庆. 钛合金ISM熔炼过程热力学与动力学分析. 哈尔滨: 哈尔滨工业大学出版社, 1998: 46)