对超细晶WC-Co硬质合金的复相显微组织进行了系统的定量化表征和分析, 获得了WC晶粒尺寸dWC, Co相平均自由程LCo和WC晶粒邻接度CWC-WC等显微组织参数与力学性能的定量关系, 模型预测结果与实验测定结果符合很好. 结果表明, 当CWC-WC基本相同时, 超细晶硬质合金的硬度分别与dWC-1/2和LCo-1/2成线性正比关系, 断裂韧性KIC分别与dWC-1/2和LCo-1/2成确定性函数关系. 在Co含量一定、WC平均晶粒尺寸基本相同的情况下, 随着 CWC-WC的增大, 超细晶硬质合金的横向断裂强度降低, 且当CWC-WC>0.5时, 硬质合金的强度随CWC-WC增加显著下降.
The microstructures of ultrafine WC-Co cemented carbides were characterized and analyzed by stereological methods. The quantitative relationships between the mechanical properties and microstructure parameters, such as the mean grain size dWC, mean free path LCo and contiguity CWC-WC, were obtained. The calculated results of mechanical properties agree well with the experimental measurements. With the equivalent contiguity, the Vickers hardness of ultrafine cemented carbides has linear relationships with dWC-1/2 and LCo-1/2 and the fracture toughness KIC has deterministic relationships with dWC-1/2 and LCo-1/2, respectively. With certain Co content and mean grain size, the transverse rupture strength decreases with the increase of contiguity. Especially when the contiguity is above 0.5, the strength decreases obviously. The present results may be used as criteria to optimize the microstructure and to improve mechanical properties of ultrafine cemented carbides.
[1] Gurland J. Trans TMS, 1963; 227: 1146
[2] Huang P Y. Principle of Powder Metallurgy. 2nd Ed., Beijing: Metallurgical Industry Press, 1997: 425
(黄培云. 粉末冶金原理. 第二版, 北京: 冶金工业出版社, 1997: 425)
[3] Hayashi K, Suzuki H. J Jpn Inst Metal, 1974; 38: 11
[4] Liu S R. Cem Carbides, 2002; 19: 129
(刘寿荣. 硬质合金, 2002; 19, 129)
[5] Sun B Q. Rare Met Cem Carbides, 2004; 32(1): 46
(孙宝琦. 稀有金属与硬质合金, 2004; 32(1): 46)
[6] Sun B Q. Rare Met Cem Carbides, 2004; 32(2): 29
(孙宝琦. 稀有金属与硬质合金, 2004; 32(2): 29)
[7] Sun B Q. Rare Met Cem Carbides, 2004; 32(3): 40
(孙宝琦. 稀有金属与硬质合金, 2004; 32(3): 40)
[8] Sun B Q. Rare Met Cem Carbides, 2004; 32(4): 33
(孙宝琦. 稀有金属与硬质合金, 2004; 32(4): 33)
[9] Shi X L, Shao G Q, Duan X L, Zhang W F, Yuan R Z. Rare Met Mater Eng, 2005; 34: 1283
(史晓亮, 邵刚勤, 段兴龙, 张卫丰, 袁润章. 稀有金属材料与工程, 2005; 34: 1283)
[10] Xie H, Xiao Y F, He Y H, Feng P, Huang Z Q. China Tungsten Ind, 2006; 21(6): 27
(谢宏, 肖逸锋, 贺跃辉, 丰 平, 黄自谦. 中国钨业, 2006; 21(6): 27)
[11] Liu X M, Song X Y, Zhang J X, Zhao S X. Mater Sci Eng, 2008; A488: 1
[12] Lin C G. Rare Met, 2004; 28: 762
(林晨光. 稀有金属, 2004; 28: 762)
[13] Zhang L, Chen S, Liu G, Yang G B, Huang Z L, Huang B Y, Zhang C F. Mater Rev, 2005; 19(11): 4
(张立, 陈述, 刘刚, 杨贵彬, 黄泽兰, 黄伯云, 张传福. 材料导报, 2005; 19(11): 4)
[14] Liu G Q. Chin J Stereol Image Anal, 1996; 1(1): 96
(刘国权. 中国体视学与图像分析, 1996; 1(1): 96)
[15] Song X Y, Liu G Q, He Y Z. Prog Nat Sci, 1998; 8: 92
[16] Song X Y, Liu G Q. J Mater Sci, 1999, 34: 2433
[17] Luyckx S, Love A. Int J Refract Met Hard Mater, 2006; 24: 75
[18] Golovchan V T, Litoshenko N V. Int J Refract Met Hard Mater, 2003; 21: 241
[19] Laugier M T. J Mater Sci Lett, 1985; 4: 263
[20] Chernyavskii K S, Travushkin G G. Problemy Prochnosti, 1980; 4: 11
[21] Song X Y, Zhao S X, Liu X M, Wei C B, Wang H B, Gao Y, Liu G Q. Chin J Stereol Image Anal, 2011; 16: 131
(宋晓艳, 赵世贤, 刘雪梅, 魏崇斌, 王海滨, 高杨, 刘国权. 中国体视学与图像分析, 2011; 16: 131)
[22] Zhao S X, Song X Y, Zhang J X, Liu X M. Acta Metall Sin, 2007; 43: 107
(赵世贤, 宋晓艳, 张久兴, 刘雪梅. 金属学报, 2007; 43: 107)
[23] Zhao S X, Song X Y, Zhang J X, Liu X M. Mater Sci Eng, 2008; A473: 323
[24] Zhao S X, Song X Y, Wang M S, Liu X M, Zhang J X. Int J Refract Met Hard Mater, 2009; 27: 1014
[25] Lee H C, Gurland J. Mater Sci Eng, 1978; 33: 125
[26] Xu Z H, Agren J. Mater Sci Eng, 2004; A386: 262
[27] Liu S R. Trans Mater Heat Treat, 2005; 26: 62
(刘寿荣. 材料热处理学报, 2005; 26: 62)
[28] Liu S R. Cem Carbides, 2003; 20(2): 65
(刘寿荣. 硬质合金, 2003; 20(2): 65)
[29] Liu S R. Phy Test Chem Anal, 2003, 39(2): 70
(刘寿荣. 理化检验--物理分册, 2003; 39(2): 70)
[30] Chermant J L, Coster M. J Mater Sci, 1979; 14: 509
[31] Fang Z Z. Int J Refract Met Hard Mater, 2005; 23: 119
[32] Liu B H, Zhang Y, Ouyang S X. Mater Chem Phy, 2000; 62: 35