表面沉积NaCl和NaHSO3的低合金钢和碳钢在干湿交替条件下的腐蚀行为

于全成; 王振尧; 汪川

doi:10.3724/SP.J.1037.2010.00248

金属学报 >

2010 , Vol. 46 >Issue 9: 1133 - 1140

DOI: https://doi.org/10.3724/SP.J.1037.2010.00248

论文

表面沉积NaCl和NaHSO₃的低合金钢和碳钢在干湿交替条件下的腐蚀行为

于全成 ,
王振尧 ,
汪川

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中国科学院金属研究所金属腐蚀与防护重点实验室, 沈阳 110016

于全成, 男, 1984年生, 硕士生

收稿日期: 2010-05-20

修回日期: 2010-06-29

网络出版日期: 2010-09-11

基金资助

沈阳市科学技术计划资助项目1091182-1-00

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CORROSION BEHAVIORS OF LOW ALLOY STEEL AND CARBON STEEL DEPOSITED WITH NaCl AND NaHSO₃UNDER DRY/HUMID ALTERNATIVE CONDITION

YU Quan-Cheng ,
YU Zhen-Yao ,
WANG Chuan

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State Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016

Received date: 2010-05-20

Revised date: 2010-06-29

Online published: 2010-09-11

Supported by

Supported by Science and Technology Plan Project of Shenyang (No.1091182-1-00)

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摘要

利用Fourier变换红外(FTIR)光谱、XRD和SEM技术以及恒电流测试技术, 研究了表面沉积NaCl和NaHSO₃的低合金钢和碳钢在干湿交替条件下的腐蚀行为. 结果表明, 低合金钢和碳钢的腐蚀速率都随着实验周期的延长而减小, 且其失重量基本相同, 低合金钢并未表现出比碳钢优越的耐蚀性. 主要腐蚀产物为α-FeOOH, Fe₃O₄, γ-FeOOH和硫酸盐, 此外还存在大量的δ-FeOOH, 导致腐蚀速率降低.

关键词： 低合金钢; 碳钢,; 大气腐蚀; 干湿交替

本文引用格式

于全成 , 王振尧 , 汪川 . 表面沉积NaCl和NaHSO₃的低合金钢和碳钢在干湿交替条件下的腐蚀行为[J]. 金属学报, 2010 , 46(9) : 1133 -1140 . DOI: 10.3724/SP.J.1037.2010.00248

Abstract

The corrosion behaviors of low alloy steel P265GH and carbon steel Q235 deposited with NaCl and NaHSO₃ under dry/humid alternative condition were investigated by FTIR, XRD, SEM and galvanostatic method. The results reveal that under present experimental condition, corrosion rates of low alloy steel and carbon steel decrease with prolonging time and their mass losses are almost identical. Besides, corrosion resistance of low alloy steel P265GH is not better than that of carbon steel Q235. The corrosion products formed on the two steels are mainly composed of δ-FeOOH, α-FeOOH, Fe₃O₄, γ-FeOOH and sulphate, among which δ-FeOOH is predominant. The existence of δ-FeOOH accounts for the decrease of corrosion rates of the steels.

Key words： low alloy steel; carbon steel; atmospheric corrosion; dry/humid alternative environment

参考文献

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