金属学报  2006, Vol. 42 Issue (12): 1279-1284

论文 本期目录 | 过刊浏览 |

氮元素对2Cr13不锈钢CO2腐蚀产物膜结构和电化学性能的影响

杨丽颖; 柳 伟; 路民旭

北京科技大学材料科学与工程学院

EFFECT OF ELEMENT N ON THE MICROSTRUCTURE OF CO2 CORROSION FILM OF 2Cr13 STAINLESS STEELS

北京科技大学材料科学与工程学院

杨丽颖; 柳伟; 路民旭 . 氮元素对2Cr13不锈钢CO2腐蚀产物膜结构和电化学性能的影响[J]. 金属学报, 2006, 42(12): 1279-1284 .

摘要 参考文献 相关文章 Metrics 全文: PDF(1195 KB)   摘要: 利用高温高压釜进行2Cr13不锈钢的高温高压CO2腐蚀实验, 用扫描电镜(SEM)和X射线光电子谱(XPS)分析腐蚀产物膜的形貌和成分, 电化学交流阻抗谱测试腐蚀产物膜对2Cr13不锈钢电极过程影响, 失重法评价两种2Cr13不锈钢CO2均匀腐蚀速率. 结果表明: 含氮钢的腐蚀产物膜结构比较疏松, 腐蚀膜中的Cr2O3被CrN和Na3CrO4部分替代, 并且含有较多的Fe3O4和-FeOOH, 其膜的电阻值比不含氮的2Cr13钢 的小, 腐蚀速率较大. 关键词 ： 氮添加,  2Cr13不锈钢,  腐蚀产物膜     Abstract：In this paper, the effect of N element on the CO2 corrosion capability of the 2Cr13 stainless steel was researched.The corrosion films of the steels were observed by SEM, and the surface components of the films were analyzed by XPS; the electrochemical impedance spectrum (EIS) of the steels was analyzed by impedance measure system ( PARSTAT 2273), and the corrosion rates of the stainless steels was measured by weight loss method. The obtained results show that the structure of the corrosion film of the 13CrMoTiNbN steel is looser, Cr2O3 is replaced by CrN and Na3CrO4 on the surface of the film, and there is a amount of Fe3O4 and a-FeOOH phases. The impedance value of the 13CrMoTiNbN steel is less than the 13CrMoTiNb steel, and the corrosion rate of the 13CrMoTiNbN steel is more. Key words： 收稿日期: 2006-03-14      ZTFLH:  TG113.25   服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 杨丽颖 柳伟 路民旭 44.8K 链接本文: https://www.ams.org.cn/CN/Y2006/V42/I12/1279 [1] Zhang Z H, Guo J B, Cai H Y, Huang Z Y. Steel Pipe, 2004; 33(5): 18 (张忠铧,郭金宝,蔡海燕,黄子阳．钢管, 2004;33(5):18) [2] Zhou B, Cui R J. Steel Pipe, 2003; 32(1): 21 (周波．崔润炯．钢管,2003,32(1):21) [3] Olsson C O A, Landolt D. Electrochim Acta, 2003; 48: 1093 [4] Montemor M F, Simoes A M P. Corroa Sci, 1999; 41: 17 [5] Olefjord I, Wegrelius L. Corns Sci, 1996; 38: 1203 [6] Wallinder D, Pana J, Leygraf C. Corros Sci, 1999; 41: 275 [7] Wang J Q, Wu W H, Feng D M. Eelectron Spectrum Science (XPS/XAES/UPS) Introduce. Beijing: National Defence Industry Press, 1992: 513 (王建棋,吴文辉,冯大明．电子能谱学(XPS／XAES／UPS)引论．北京:国防工业出版社．1992:513) [8] Baba H, Kodama T, Katada Y. Corros Sci, 2002; 44: 2393 [9] Osozawa K, Okato N, Fukase Y. Corros Sci, 1975; 24: 1 [10] Leth-Olsen A A, Kemal N. Corros Sci, 1998; 40: 1195 [11] Toro A, Misiolek W Z, Tschiptschin A P. Acta Mater, 2003; 51: 3363 [12] Mathieu H J, Landolt D. Corros Sci, 1986; 26: 547 [13] Kimura Y, Takebayashi Y, Hirota N. Chem Phys Lett, 1996; 257: 429 [14] Liu C, Bi Q, Leyland A, Matthews A. Corros Sci, 2003; 45: 1243b [1] 张慧, 杜艳霞, 李伟, 路民旭. 不同环境介质中X70钢的交流腐蚀行为及腐蚀产物膜层分析[J]. 金属学报, 2017, 53(8): 975-982. [2] 许立宁,王贝,路民旭. 6.5%Cr钢在高温高压CO2环境下的腐蚀行为研究*[J]. 金属学报, 2016, 52(6): 672-678. [3] 徐庆东,林鑫,宋梦华,杨海欧,黄卫东. 激光成形修复2Cr13不锈钢热影响区的组织研究[J]. 金属学报, 2013, 49(5): 605-613. [4] 郝宪朝 高明 张龙 赵秀娟 刘奎. 退火态12Cr13不锈钢显微组织及其对冲击韧性的影响[J]. 金属学报, 2011, 47(7): 912-916. [5] 孙建波 柳伟 常炜 张忠铧 李忠涛 于湉 路民旭. 低铬X65管线钢CO2腐蚀产物膜的特征及形成机制[J]. 金属学报, 2009, 45(1): 84-90. [6] 陈长风; 路民旭; 赵国仙; 白真权; 严密林; 杨延清 . N80油套管钢CO2腐蚀产物膜特征[J]. 金属学报, 2002, 38(4): 411-416 . [7] 朱小龙;林乐耘;雷廷权. 70Cu—30Ni合金海水腐蚀产物膜形成过程[J]. 金属学报, 1997, 33(12): 1256-1261. Viewed Full text Abstract Cited   Shared      Discussed