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金属学报  1986, Vol. 22 Issue (1): 132-140    
  论文 本期目录 | 过刊浏览 |
天然高纯MgO-CaO材料的活化烧结
张治平;黄辉煌;李广平
冶金工业部洛阳耐火材料研究所;冶金工业部洛阳耐火材料研究所;冶金工业部洛阳耐火材料研究所
ACTIVATED SINTERING OF NATURAL HIGH PURITY MgO-CaO SERIES MATERIALS
ZHANG Zhiping; HUANG Huihuang; LI Guangping (Luoyang Institute of Refractory Research; Ministry of Metallurgical Industry)
引用本文:

张治平;黄辉煌;李广平. 天然高纯MgO-CaO材料的活化烧结[J]. 金属学报, 1986, 22(1): 132-140.
, , . ACTIVATED SINTERING OF NATURAL HIGH PURITY MgO-CaO SERIES MATERIALS[J]. Acta Metall Sin, 1986, 22(1): 132-140.

全文: PDF(1453 KB)  
摘要: 本工作在前文的基础上进一步研究整个MgO-CaO系列材料的活化烧结规律,着重探讨MgO/CaO之比对轻烧-水化试样烧结行为的影响和烧结试样的抗水化性。 试验工作证明,天然高纯MgO-CaO系列的两相材料,用轻烧-水化方法,可以在1400℃烧后基本完成致密化过程,在1600℃烧后可得显微结构良好和高度直接结合的MgO-CaO熟料。二端员原料烧结时,晶粒异常长大,密度低,闭气孔率高。 轻烧-水化试样的易烧结主要同CaO和MgO对OH-的吸附-脱附作用有关。
Abstract:On the basis of the previous works by the authors, a continuous approach to the calcination-hydration activated sintering of the natural MgO-CaO series materials of high purity was studied with putting much emphasis upon the effect of the ratio of MgO/CaO on the sintering behaviour and upon the resistance of grogs to disintegration as well. It is found that the densification of the two-phase materials is practically completed when the specimens fired at 1400℃ and developed the highly direct-bonded basic grogs of fine microstructure at 1600℃, while that of one-phase end members grows a lot of exaggerated grains with moderate intragranular pore formation resulting in lowering of the density. The activated sintering of the calcination-hydration specimens seems to be related to the adsorption-desorption of OH~- by CaO and MgO. The resistance to disintegration decreases with the increase of their CaO content.
收稿日期: 1986-01-18     
1 李广平;张治平;黄辉煌,硅酸盐学报,11 (1983) ,193.
2 黄辉煌;张治平;李广平,硅酸盐学报,13 (1985) ,217
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