新型钴基与Nb-Si基高温合金扩散动力学研究进展
刘兴军, 魏振帮, 卢勇, 韩佳甲, 施荣沛, 王翠萍

Progress on the Diffusion Kinetics of Novel Co-based and Nb-Si-based Superalloys
LIU Xingjun, WEI Zhenbang, LU Yong, HAN Jiajia, SHI Rongpei, WANG Cuiping
表1 钴基高温合金中合金化元素的作用[16~26]
Table 1 Effects of alloying elements on Co-based superalloys[16-26]
ElementMicrostructure and mechanical propertyOxidation resistance property
Al, CrStabilizing elements of γ-phase, reducing the alloy densityForming a dense oxide layer (Al2O3 or Cr2O3) to
prevent the oxidation of alloy
NiExtending γ/γ' two-phase region, increasing the volumeInhibiting the formation of the oxide layer Al2O3,
fraction of γ' phaseand reducing the oxidation resistance of the alloy

Ta, W

Stabilizing elements of the γ' phase, significantly increasing the alloy density and forming the new phases unfavorable to mechanical properties with high content

Enhancing the oxidation resistance of the alloy below 1000oC by reducing the diffusion rate of each element, and decreasing the oxidation resistance of the alloy above 1000oC by inhibiting the formation of continuous oxide layers

Ti

The stabilizing element of γ' phase, significantly reduces the density of the alloy and the mismatch between the two phases of γ/γ' which benefits mechanical properties. However, high content Ti leading to the formation of lamellar TCP phase is not conducive to the mechanical propertiesWith increasing temperature, the resistance to oxid-ations decreases because of the reduction in the density of oxide films caused by a phase trans-formation in TiO2

C, N, B

The alloy's strength increases, but its ductility and toughness decrease, due to the formation of interstitial phases with high

hardness, melting point, and brittleness

The addition of small amount of B is good for enhancing the adhesion of oxide film to the substrate, but too much of it will promote the diffusion of the element, which is not good for the high temperature oxidation resistance of the alloy