Fe-Cu-Pb合金液-液相分离及废旧电路板混合金属分级分离与回收
陈斌1,2,何杰1,2(),孙小钧1,2,赵九洲1,2,江鸿翔1,张丽丽1,郝红日1
Liquid-Liquid Phase Separation of Fe-Cu-Pb Alloy and Its Application in Metal Separation and Recycling of Waste Printed Circuit Boards
Bin CHEN1,2,Jie HE1,2(),Xiaojun SUN1,2,Jiuzhou ZHAO1,2,Hongxiang JIANG1,Lili ZHANG1,Hongri HAO1

图6. 1473 K时次要金属在富Fe和富Cu液相中的分配系数的对数值lgKMCu/Fe以及其他学者的研究结果[27,48],及1233 K时添加和不添加Al作为捕集剂时次要金属在富Cu和富Pb液相中的分配系数的对数值lgKMCu/Pb

Fig.6. Logarithm values of the estimated molar distribution ratio of minor metals between Fe-rich and Cu-rich liquids lgKMCu/Fe at 1473 K and distribution ratios obtained in different literatures[27,48] (a), and logarithm values of the estimated molar distribution ratio of minor metals between Cu-rich and Pb-rich liquids lgKMCu/Pb at 1233 K without and with the collecting agent Al (b)