海洋防腐涂料的最新研究进展

doi:10.11903/1002.6495.2015.221

腐蚀科学与防护技术

2016, Vol. 28

Issue (3): 269-275 DOI: 10.11903/1002.6495.2015.221

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本期目录 | 过刊浏览

海洋防腐涂料的最新研究进展

张超智¹(

),蒋威¹,李世娟¹,徐洪飞²,袁阳¹

1. 南京信息工程大学环境科学与工程学院南京 210044
2. 常州绝缘材料总厂有限公司常州 213023

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摘要:

介绍了海洋防腐涂料的防腐机理;综述了国内外海洋防腐涂料的最新研究进展;讨论了环氧类防腐涂料、聚氨酯防腐涂料、橡胶类防腐涂料、氟树脂防腐涂料、有机硅树脂涂料、聚脲弹性体防腐涂料和富锌涂料的性质特点及其应用,及其不足与今后研究的方向;展望了海洋防腐涂料应用前景和发展趋势。

关键词 ：海洋防腐, 树脂, 防腐涂料, 制备工艺, 防腐性能

基金资助:江苏特聘教授科研经费项目 (R2012T01),江苏省产学研项目(BY2012028)和教育部留学回国启动基金项目 (2013S010) 资助

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张超智,蒋威,李世娟,徐洪飞,袁阳. 海洋防腐涂料的最新研究进展[J]. 腐蚀科学与防护技术, 2016, 28(3): 269-275.

链接本文:

https://www.cspt.org.cn/CN/Y2016/V28/I3/269

种类	优点	缺点	适用范围	使用寿命
环氧类防腐涂料	高粘附力、高强度、固化收缩率低、耐腐蚀性与耐磨性强等	耐冲击力和韧性较差,耐热性能不高等	桥梁、船舶、海上平台钢结构面漆、中间漆或底漆使用	10~15 a
氟碳防腐涂料	超强的耐腐蚀性和耐酸碱性、憎水憎油、免维护、自清洁等	价格高,涂装工艺较复杂、硬度不够等	桥梁和建筑领域作为面漆	20~25 a
聚氨酯类防腐涂料	涂膜坚硬、丰满,附着力强、耐水性能优异	耐候性不佳,户外易泛黄、施工工序复杂	海上平台和船舶桥梁等领域,可配套做中间漆或面漆	10~15 a
橡胶防腐涂料	阻燃性好,耐热耐低温性优异,干燥快、硬度强	需多次涂刷才能达到厚度要求,生产过程使用四氯化碳,环保性能差	桥梁等钢结构和船底、船舶水线等部位的防腐,与环氧富锌底漆等配套使用	10~15 a
有机硅类树脂涂料	耐热耐寒性强、防霉性能优异、优良的耐腐蚀和电绝缘性等	成膜性能较差、大面积施工不便、附着力不强、固化温度高等	化工管道和集装箱等领域的涂装、对其他涂料进行改性用作面漆或底漆使用	10~20
聚脲弹性体防腐涂料	无溶剂,不含VOC,固化速度快,耐高温低温性能好,耐候性强等	力学性能一般,发泡,价格较高等	主要应用于桥梁、船闸、船舶及码头、贮罐内壁的防腐	15 a
玻璃鳞片类重防腐涂料	优异的封闭性、抗渗透性和防腐蚀性能,耐紫外性能和耐老化性能好	力学性能和抗变形性能差	主要船舶内仓和甲板,桥梁和海上平台等领域做面漆或底漆使用	20 a
富锌涂料	有机富锌底漆具有低表面处理和附着力强的优点,无机富锌底漆防锈作用优异	有机富锌底漆耐热性、导电性和耐溶剂性能较差,无机富锌底漆成膜性能差,施工条件苛刻	桥梁、船舶等钢结构的防护,主要与其他涂料配套做底漆或面漆使用	15~25 a

表1 不同种类涂料对比

图1 双酚A环氧树脂结构式

图2 双酚A酚醛环氧树脂结构式

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