ISSN 0412-1961
CN 21-1139/TG
Started in 1956

About the Journal

  Current Issue
    , Volume 30 Issue 14 Previous Issue    Next Issue
    For Selected: View Abstracts
    MODELS OF ACTIVITY AND ACTIVITY INTERACTION PARAMETER IN TERNARY METALLIC MELT
    G Xueyong(Northeastern University;Shenyang);FAN Peng;HAN Qiyong(University of Science and Technology Beijing)(Manuscript received 8 April;1993;in revised form 15 July;1993)
    Acta Metall Sin, 1994, 30 (14): 49-60. 
    Abstract   PDF (605KB) ( 962 )
    The calculating models for activity and activity interaction parameter in ternary metallic melts were established.1nγof any element,ε,εand,ρ,ρ,ρbetween any element in any metallic melt could be calculated rapidly and accurately except for O,S,Se and Te.The models could be used in both solid and liquid metallic solutions.The factors to affect 1nγ were the electron density,nWS,electronegativity,Φ,and molar volume,V of solute i and solvent k.The values of 1nγ by calculation were well accordant with those by experiments.The fraction of same sign between calculating values and experiment data for Fe-base alloys reached 95.7%.The factors to affectεandεwere nWS,Φ,V of solute i,j and solvent k.The data by calculation and experiments were basically same.The fraction of same sign was above 80%.The more reliable the experiments,the more the ratio of the same sign.
    References | Related Articles | Metrics
    MICROSTRUCTURE AND MAGNETIC PROPERTIES OF NANOCRYSTALLINE(Fe,Cu,Nb)_(77.5)Si_xB_(22.5-x) ALLOYS
    ZHI Jing;HE Kaiyuan;CHENG Lizhi;FU Yujun;WANG Zhi;LIU Yi (Northeastern University;Shengyang)(Manuscript received 30 January 1993:in revised form 25 June;1993)
    Acta Metall Sin, 1994, 30 (14): 61-65. 
    Abstract   PDF (316KB) ( 634 )
    Curie temperature and lattice constants of the nanocrystalline(Fe,Cu.Nb)_(77.5)Si_xB_(22.5-x)(x=9.5-17.5) alloys were found to decrease linearly with the increase of their total Si contenty x While the Si content in crystallized grains,x_α,increases linearly with increasing x.With the increase x,the magnetostriction of the alloys increases in amorphous state,but decreases after crystallization.The volume fraction of the nanocrystalline grains occurred in alloys may increase with the increase of x after annealing under certain temperature.
    References | Related Articles | Metrics
    STRUCTURAL STUDY OF NANOCRYSTALLINE Fe-Cu-Nb-Si-B ALLOYS BY MSSBAUER SPECTROSCOPY
    BAI Kuichang;JIANG Ziying;HE Kaiyuan;CHENG Lizhi;ZHI Jing(Northeastern University;Shenyang)(Manuscript received 7 June;1993;in revised form 9 August;1993)
    Acta Metall Sin, 1994, 30 (14): 66-71. 
    Abstract   PDF (388KB) ( 544 )
    The Mssbauer spectra of some Fe_(73.5)Cu_1Nb3Si_(13.5)B_9 alloy samples as-quenched or after annealing at different temperatures have been measured at room temperature.The spectrum of as-quenched sample exhibits a typical broadened sextet as amorphous with mean internal field=17.01 MA/m.The structural relaxation or partial crystallization started after annealing at 480 to 500℃ for 0.5 h in N_2 atmosphere.General crystallization occurred remarkabley when annealed at 530℃ and above.The α-Fe(Si) nanocrystalline solid solution and residual amorphous are the two main phases after annealing at 530℃ for 1h and the relative amount of the amorphous is about 39.1%.The amount of residual amorphous phase decreases with increasing annealing temperature,down to about 25% when annealed at 620t.The internal field of the amorphous also decreases with increasing annealing temperature when general crystallization occured,however it increases a little at the structural relaxation stage.The nearest neighbour Fe atoms number distribution of Mossbauer atom in α-Fe(Si) solid solution has been calculated according to their correspondent subspectrum areas.The concentration of Si in the α-Fe(Si) phase and the ordering degree of the solid solution can also be estimated in the same way.Finally,bulk magnetic texture with different orientation has been found in the sample annealed at 550℃.
    References | Related Articles | Metrics
    STRUCTURE AND MAGNETIC PROPERTIES OF Sm_2(Fe_(1-x)Cr_x)17N_(~2.7) MAGNETS
    ZHOU Shouzeng;YANG Jun;ZHANG Maocai(University of Science and Technologl. Beijing);LIN Yi; YIN Youxiang;LIN Guobiao(Beijing General institute of Mining and Metallurgy)(Manuscript received 19 May;1993;in revised form 19 August;1993)
    Acta Metall Sin, 1994, 30 (14): 72-76. 
    Abstract   PDF (360KB) ( 602 )
    Effect of Cr in substitution for a part of Fe on structure and magnetic properties of Sm_2(Fe_(1-x)Cr_x)_(17)N_(~2.7) alloys powder has been investigated.The structure of the alloys remains the same with an addition of Cr,saying x=0-0.1.With the increase of Cr content,their Curie temperature,anisotropic field.saturation magnetization,average Fe atom moment and average hyperfine field decrease slightly.But their homogeneity may be obviously improved and coercivity increased even up to 1592 kA/m for Sm_2(Fe_0.95Cr_0.05)_17N_(~2.7) powder.
    References | Related Articles | Metrics
    ROLE OF MULTI-ARC PLATED Ti-N FILM AS A DIFFUSION BARRIER
    WANG Jiajun(Tsinghua University; Beijing);YE Ruizeng(University of Science and Technology Beijing);SUN Yufang(General Research institute for Nonferrous Metals;Beijing)(Manuscript received 27 July;1993;in revised form 6 September 1993)
    Acta Metall Sin, 1994, 30 (14): 77-81. 
    Abstract   PDF (374KB) ( 686 )
    Several multi-layer coatings have been designed so as to assess the diffusion barriering ability against Al,Ni,Co,etc.as well as the high temperature stability of the multi-arc plated Ti-N film after being aged at 1000 and 1100℃ for a long time.The results show that,up to 1000℃,Ti-N film is of good stability;it can prevent effectively Al from diffusing towards matrix,and slow down the rate of diffusion of Ni,Co from CoCrAlTaY to matrix.Above 1100℃,the morphology of Ti-N film changes from thin foil to particles.Apparently the particle-shaped Ti-N can not prevent Ni,Co from the inter-diffusing between matrix and CoCrAlTaY coating.
    References | Related Articles | Metrics
    BEHAVIOUR OF OXYGEN AND CARBON IN Pt THIN FILM
    WU Yunzhong;DING Qing;XU Meifang;WANG Weiyuan(Shanghai institute of Metallurgy;The Chinese Academy of Sciences)(Manuscript received 17 December;1992;in revised form 5 August;1993)
    Acta Metall Sin, 1994, 30 (14): 82-85. 
    Abstract   PDF (259KB) ( 591 )
    Behaviours of O_2 and C in Pt thin film were observed by Auger spectroscopy to be limited by diffusion.The activation energy of O_2 diffusion into Pt is different,saying,0.98 and 0.44 eV at higher and lower than 1000℃ respectively.In a range of 550-1000℃ or 1000-1200℃,O_2 diffuses outward or inward Pt film,which may be purified or oxidized respectively.In the temperature range studied,the activation energy of C diffusion is equal to 0.52 eV.Its diffusion behaviour is identical to that of O_2 and the concentration of C in Pt film increases or decreases with increasing or decreasing O_2 content respectively.
    References | Related Articles | Metrics
    FRACTAL GROWTH OF PRE-PASSIVE FILM ON Fe
    SONG Guangling;CAO Chunan;LIN Haichao (Corrosion Science Laboratory;Institute of Corrosion and Protection of Metals;The Chinese Academy of Sciences;Shenyang);GAO Weihong;LI YingCHEN Shenhao(Shandong University;Jinan)(Manuscript received 15 March;1993;in revised form 24 May;1993)
    Acta Metall Sin, 1994, 30 (14): 86-90. 
    Abstract   PDF (334KB) ( 628 )
    An investigation on transient processe of active dissolution-passivation was carried out for Fe in H_2SO_4 media.Based on the model for the growth of the pre-passive film developed by the authors,a fractal dememsion(D_s) of the film was obtained.This D_s and the rates of the formation of pre-passive film inceases with the increase of passivation potential.
    References | Related Articles | Metrics
    PREPARATION OF Ni-Al INTERMETALLIC COMPOUNDS BY MECHANICAL ALLOYING
    LI Gusong;DING Bingzhe;MIAO Weifang;YE Lilei;GUO Jianting(State Key La boratory of RSA;Institute of Metal Research;The Chinese Academy of Sciences;Shenyang)(Manuscript received 30 June;1993;in revised form 18 August;1993)
    Acta Metall Sin, 1994, 30 (14): 91-96. 
    Abstract   PDF (427KB) ( 925 )
    The powder mixtures of Ni and Al with compositions of Ni50 at.-% Al and Ni-25 at.-% Al as well as Ni_3Al alloy powder were milled in a Spex 8000 Mixer/Mill respectively.After 3 h of milling,Ni-50 at.-%Al mixture transforms into NiAl with grain size of about 5 nm,while after 5 h,Ni-25 at.-%Al mixture transforms into disordered metastable Ni solid solution.As to the Ni_3Al alloy powder,5 h milling makes its structure change from Ll_2-type intermetallic compound with long range order into fcc disordered solid solution;further milling results in the formation of nanocrystalline structure.
    References | Related Articles | Metrics