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Acta Metall Sin  2020, Vol. 56 Issue (3): 351-360    DOI: 10.11900/0412.1961.2019.00245
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Fabrication and Properties of Novel Multi-LayeredMetal Composites
ZHANG Le1,2,WANG Wei1,3(),M. Babar Shahzad1,SHAN Yiyin1,3,YANG Ke1
1. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
2. School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
3. Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
Cite this article: 

ZHANG Le,WANG Wei,M. Babar Shahzad,SHAN Yiyin,YANG Ke. Fabrication and Properties of Novel Multi-LayeredMetal Composites. Acta Metall Sin, 2020, 56(3): 351-360.

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Abstract  

With the development of science and technology, more and more products with excellent quanlity and abundant functionalities have been exploited and provided. Inspired by the concept of "brick wall" structure or layer structure with alternated distribution of hard and soft phases discovered in nature creatures such as mother pearl shellfish, a entirely novel steel composite which not only can minimize the shortcomings of the original materials at the maximum extent, but also possess excellent mechanical performance as well as new physical properties, has been developed. Taking ultra-high strength maraging steel and 316L austenitic stainless steel as the original materials, the influence of deformation reduction under high vacuum on interfacial bonding strength and interface characteristics of heterogeneous multi-layered metal composites was studied, and the fabrication feasibility of heterogeneous multi-layered metal composites was explored. The results showed that in the vacuum hot-pressing process, the interfaces under different deformations were clear and straight. Slight mutual diffusion phenomenon occurred in the hot-pressing process. Due to the difference of rheological properties of the original materials at high temperature, dynamic recovery and dynamic recrystallization occurred in the 316L layer, while deformed microstructure was dominant in the maraging steel layer. Combined with rolling process and heat treatment, bulk metal composites with 9 layers and 11 layers were prepared, respectively. The results of the three-point bending experiment showed that the crack occurred firstly at the outermost side of the multi-layer composites which withstood the tensile stress. Due to the passivation, delamination and bridging of heterogeneous interface in the multi-layer metal composites, the propagation path of crack was greatly extended and more energy was consumed, which showed excellent ability to block the crack propagation.

Key words:  maraging steel      austenitic stainless steel      multi-layer metal composite      vacuum hot pressing      interface characterization      bending property     
Received:  24 July 2019     
ZTFLH:  TG147  
Fund: National Natural Science Foundation of China(51472249);National Natural Science Foundation of China Research Fund for International Young Scientists(51750110515);Youth Innovation Promotion Association of Chinese Academy of Sciences(2017233);Innovation Project of Institute of Metal Research(2015-ZD04);Shenyang Science and Technology Project(Z18-0-026)

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https://www.ams.org.cn/EN/10.11900/0412.1961.2019.00245     OR     https://www.ams.org.cn/EN/Y2020/V56/I3/351

MaterialCSiMnCrNiCoTiAlMoPSFe
316L0.0801.02.017.012.0---2.000.0450.0300Bal.
MAS0.003---18.215.11.070.16.420.0040.0023Bal.
Table 1  Chemical compositions of maraging steel (MAS) and 316L austenitic stainless steel (mass fraction / %)
Fig.1  Schematic of interface bonding (a), sampling method for tensile tests of heterogeneous initial material (b) and bulk multilayered composite (c)
Fig.2  Interface characteristics of metal composites under different deformation reductions(a) 10% (b) 20% (c) 40% (d) 60% (e) 80% (f) enlarged view of square area in Fig.2b
Fig.3  Tensile performances and fractographs of metal composites under different deformation reductions(a) photo of interface bonding specimens (b) photo of specimens after tensile tests(c) tensile stress-strain curves (d~f) SEM fractographs of 20%, 40% and 60% reductions, respectively
Fig.4  Elements distributions near the interface of the metal composites with 20% deformation reductionColor online(a) Fe (b) Ni (c) Cr (d) Co (e) Mo (f) Ti
Fig.5  EBSD image near the interface of the metal composites with 20% deformation reductionColor online
Fig.6  Statistics of microstructure near interface in Fig.5
Fig.7  Photos of bulk multi-layered MAS/316L stainless steel composites with different layers after hot pressing in vacuum(a) 9 layers (b) 11 layers
Fig.8  SEM images of interface characteristics of MAS/316L stainless steel multi-layered composites after cold rolling(a) 9 layers (b) 11 layers
Fig.9  Hardness distributions near the interface of multi-layered MAS/316L stainless steel composites at different states(a) cold rolling state (b) peak-aged state
Fig.10  Three-point bending load-displacement curves of metal composites with different layers under different heat treatments(a) 9 layers (b) 11 layers
Fig.11  Bending strengths of metal composites with different layers under different heat treatments
Fig.12  Side fracture SEM images of three-point bending of 9 layered (a~c) and 11 layered (d~f) composites(a, d) CR (b, e) CR+S (c, f) CR+S+A
Fig.13  Schematic of three-point bending characteristics(a) loading (b) bending moment (M) (c) stress distribution
Fig.14  Schematic of crack generation and propagation model for multi-layered metal composites
Fig.15  Features and predictions of complete bending cures of multi-layered metal composites treated by CRA+S+A
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