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Acta Metall Sin  2018, Vol. 54 Issue (11): 1637-1652    DOI: 10.11900/0412.1961.2018.00371
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Basic Research in Development and Applicationof Cast Superalloy
Jian ZHANG(), Langhong LOU
Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
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Jian ZHANG, Langhong LOU. Basic Research in Development and Applicationof Cast Superalloy. Acta Metall Sin, 2018, 54(11): 1637-1652.

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Abstract  

Cast superalloy is widely used in aerospace and energy industry. The research and development of these alloys is correlated with a large variety of materials and disciplines. The technology readiness level (TRL) of advanced cast superalloys is generally a mirror of the industry base of a country. China has made great progress in the field under the strong pull of demand in recent years. However, many issues are emerging in the industrial applications, reflecting a low TRL of advanced materials and a large gap between China and the developed countries. We present (1) development of directionally solidified and single crystal superalloys, (2) processing techniques of complex castings and (3) service behavior of blades as examples in this paper to explain the important role of basic research in research and development of cast superalloys.

Key words:  cast superalloy      blade      basic research     
Received:  16 August 2018     
ZTFLH:  TG24  
Fund: Supported by National Natural Science Foundation of China (Nos.51631008, 51201164, 51671196, 50901079, 51771204 and U1732131), National Basic Research Program of China (No.2010CB631201), National Key Research and Development Program of China (Nos.2017YFB0702904 and 2016YFB0701403)

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https://www.ams.org.cn/EN/10.11900/0412.1961.2018.00371     OR     https://www.ams.org.cn/EN/Y2018/V54/I11/1637

Fig.1  Schematic of research and development procedure of cast superalloy (DS—directional solidification)
Fig.2  Effect of Re addition on hot corrosion resistance of Ni-base single crystal (SX) superalloy (t—time)[9]
Fig.3  Microstructure evolution (insets) during 900 ℃, 24000 h thermal exposure and its effect on creep rupture life[18]
Fig.4  L-M plots of DZ411 and DD410 alloys comparing the creep rupture life below and over 5000 h (Inset shows M23C6 precipitated in DD410 alloy during long term creep tests; σ—strength, T—temperature)
Fig.5  Sizes of S-pores and H-pores in DD33 superalloy during solution heat treatment at 1330 ℃. Evolution of micro-pores was observed by XCT, one type of the micro-pores is the solidification pores (S-pores), and the second kind of micro-pores is named as H-pores, which has been observed during solution heat treatment of the SX alloys. The equivalent diameter (Deq, μm) of micro-pores is labeled in the bracket[26]
Fig.6  Creep rupture lives of DD410 alloy with tilt and twist grain boundaries at 760 ℃ (Insets show the TEM and HRTEM images of grain boundaries (GBs))[35]
Fig.7  Normalized creep rupture lives of directional solidification and single-crystal superalloys at high temperature (a) and intermediate temperature (b) as a function of transverse recrystallization area fraction (ARX—the area of the recrystallization on the cross section, A—the area of the cross section of the specimen)[43,52,53,55~60]
Fig.8  Grain structures of fine grain (a) and dual structural blisk (b)
Fig.9  Simulated temperature profiles of the blade with different sizes and the experimental criterion (dash line) showing that the surface reaction would be avoided if the volume of the blade is reduced to 30% of its original size. The experimental criterion (dash line) is obtained from the observation of thickness and morphology of the reaction layers on surface of DZ411. No reaction was observed below the dash line[89]
Fig.10  Morphologies of gas turbine after long term service
(a~c) γ’, MC and internal surface oxidation at tip of airfoil (d, e) γ’ and MC in ablation zone
(f) MC in middle zone of upper section (g, h) γ’ and MC in lower section of airfoil
(i, j) γ’ and MC near cooling passage in lower section of airfoil (k, l) γ’ and coating in root section
Fig.11  Thermal fatigue (room temperature~1100 ℃, water quenching) behaviors of single crystal superalloy with different secondary orientations (Insets show the morphologies around cooling holes (0.5 mm in diameter) after 0, 80 and 120 cyc)[111]
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