碳纳米材料增强镁基复合材料研究进展

doi:10.11900/0412.1961.2018.00316

金属学报

2019, Vol. 55

Issue (1): 73-86 DOI: 10.11900/0412.1961.2018.00316

本期目录 | 过刊浏览

碳纳米材料增强镁基复合材料研究进展

王晓军, 向烨阳, 胡小石, 吴昆(

)

哈尔滨工业大学材料科学与工程学院哈尔滨 150000

Recent Progress on Magnesium Matrix Composites Reinforced by Carbonaceous Nanomaterials

Xiaojun WANG, Yeyang XIANG, Xiaoshi HU, Kun WU(

)

School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150000, China

引用本文:

王晓军, 向烨阳, 胡小石, 吴昆. 碳纳米材料增强镁基复合材料研究进展[J]. 金属学报, 2019, 55(1): 73-86.
Xiaojun WANG, Yeyang XIANG, Xiaoshi HU, Kun WU. Recent Progress on Magnesium Matrix Composites Reinforced by Carbonaceous Nanomaterials[J]. Acta Metall Sin, 2019, 55(1): 73-86.

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摘要:

本文综述了碳纳米材料增强镁基复合材料的国内外研究进展,详细介绍了碳纳米材料增强镁基复合材料的制备方法,着重分析了其强韧化机制,探讨了其界面结构,简单概述了其储氢性能、热性能、抗腐蚀性能,最后总结了镁基复合材料现阶段的局限性,展望了镁基复合材料未来的发展方向。

关键词 ：镁基复合材料, 碳纳米材料, 制备方法, 强韧化机制

Abstract：

Carbon nanotubes (CNTs) and graphene nanoplatelets (GNPs) with ultra-high mechanical properties are attractive reinforcements to fabricate light weight, high strength metal matrix composites. In this paper, research progress on CNTs/GNPs reinforced magnesium matrix composites is systematically reviewed. This review focuses on the recent development of the preparation techniques, strengthening and toughening mechanism, interface structure of magnesium matrix composites reinforced by carbonaceous nanomaterials. Four kinds of preparation techniques are introduced, including powder metallurgy, stirring casting, disintegrated melt deposition and friction stir process. The yield strength of composites increases with the addition of GNPs/CNTs. Several possible factors can contribute to this: (1) grain size refinement; (2) load-transfer effects; (3) generation of the dislocation density due to strain generated by the thermal expansion mismatch between the matrix and GNPs/CNTs; (4) Orowan strengthening caused by the resistance of closely spaced GNPs/CNTs to the passing of dislocations. In addition, hydrogen storage behaviors, thermal properties and corrosion resistance of composites are also briefly introduced. In the end, this review summarizes the limitations of magnesium matrix composites at present stage as well as the prospect of its future development.

Key words： magnesium matrix composite carbonaceous nanomaterial preparation method strengthening and toughening mechanism

收稿日期: 2018-07-09

ZTFLH:

TG146

基金资助:国家自然科学基金项目Nos.51671066和51471059

作者简介:

作者简介王晓军,男,1981年生,副教授,博士

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https://www.ams.org.cn/CN/10.11900/0412.1961.2018.00316 或 https://www.ams.org.cn/CN/Y2019/V55/I1/73

图1 粉末冶金法示意图

图2 搅拌铸造法制备石墨烯增强镁基复合材料过程示意图[26]

图3 分离熔体沉积法示意图

图4 搅拌摩擦加工法示意图

图5 挤压态CNTs/Mg-6Zn显微组织[30]

图6 CNTs、MgO、Mg位向关系示意图

图7 GNPs周围的Zn原子偏聚及其形成机理示意图[57]

图8 不同力学模型计算的Young's模量计算值(Ec)与GNPs体积分数(VG)关系曲线[26]

图9 不同强化机制计算结果及其实验值[26]

图10 基面及非基面滑移迹线的SEM-EBSD分析[39]

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