一种Zr改性双相PtAl<sub>2</sub>+(Ni, Pt)Al涂层的制备及热腐蚀行为研究

doi:10.11900/0412.1961.2017.00376

金属学报

2018, Vol. 54

Issue (4): 581-590 DOI: 10.11900/0412.1961.2017.00376

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一种Zr改性双相PtAl₂+(Ni, Pt)Al涂层的制备及热腐蚀行为研究

蒋成洋^1,², 阳颖飞², 张正义³, 鲍泽斌²(

), 朱圣龙², 王福会¹

1 东北大学材料科学与工程学院沈阳 110819
2 中国科学院金属研究所沈阳材料科学国家研究中心沈阳 110016
3 中国航发南方工业有限公司株洲 412002

Preparation and Enhanced Hot Corrosion Resistance of aZr-Doped PtAl₂+(Ni, Pt)Al Dual-Phase Coating

Chengyang JIANG^1,², Yingfei YANG², Zhengyi ZHANG³, Zebin BAO²(

), Shenglong ZHU², Fuhui WANG¹

1 School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China
2 Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3 China National South Aviation Industry Co., Ltd., Zhuzhou 412002, China

引用本文:

蒋成洋, 阳颖飞, 张正义, 鲍泽斌, 朱圣龙, 王福会. 一种Zr改性双相PtAl₂+(Ni, Pt)Al涂层的制备及热腐蚀行为研究[J]. 金属学报, 2018, 54(4): 581-590.
Chengyang JIANG, Yingfei YANG, Zhengyi ZHANG, Zebin BAO, Shenglong ZHU, Fuhui WANG. Preparation and Enhanced Hot Corrosion Resistance of aZr-Doped PtAl₂+(Ni, Pt)Al Dual-Phase Coating[J]. Acta Metall Sin, 2018, 54(4): 581-590.

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摘要:

在镍基单晶高温合金上采用复合电镀的方法沉积Pt-Zr复合镀层,随后通过气相渗铝的方法,获得Zr改性的PtAl₂+(Ni, Pt)Al双相涂层,该涂层分为3层：外层由PtAl₂颗粒弥散分布在β-(Ni, Pt)Al中的双相区组成,中间层为β-(Ni, Pt)Al及少量Cr的析出物,内层为互扩散区(IDZ)。其中,Zr元素主要固溶在外层双相区以及中间层β-(Ni, Pt)Al中。分别对Zr改性和普通PtAl₂+(Ni, Pt)Al双相涂层在850 ℃下Na₂SO₄/NaCl (75:25,质量比)混合盐中进行热腐蚀实验,结果表明,因Zr元素具有固定S和Cl的作用,可降低S和Cl在热腐蚀过程中的破坏性,故Zr改性PtAl₂+(Ni, Pt)Al双相涂层比普通PtAl₂+(Ni, Pt)Al双相涂层具有更好的抗热腐蚀性能。经过低真空预氧化处理后,普通PtAl₂+(Ni, Pt)Al双相涂层表面生成的Al₂O₃膜较薄,在后续热腐蚀过程中并不能有效抵挡混合盐的持续入侵,涂层长期抗热腐蚀性能与原始状态PtAl₂+(Ni, Pt)Al涂层样品接近。

关键词 ： Zr改性, 活性元素, Pt-Al涂层, 热腐蚀

Abstract：

Prior to practical service, hot-section components (e.g. airfoils and vanes) of a gas turbine engine are necessarily coated by a protective metallic coating (such as aluminide diffusion coating, modified aluminide coating and MCrAlY overlay etc.) to resist high temperature oxidation and hot corrosion. Among the modified aluminide coatings, the coating with Pt-modification has attracted great attention and is widely used in applications requiring high reliability and extended service life since it possesses superior oxidation/corrosion resistance at high temperature. The presence of Pt in aluminide coating is favorable for increasing bonding strength of oxide scale, enlarging phase region of β-NiAl and confining detrimental effect of sulphur etc. Although Pt-modification has exhibited visible benefits for acquiring better high-temperature performance, it is far from satisfaction to develop an ideal aluminide diffusion coating. Reactive elements such as Y, Hf, Zr or their oxides have been employed to modify the nickel aluminide coating system, with an aim to further improve scale adhesion and promote exclusive formation of α-Al₂O₃simultaneously. In this work, a Zr-doped PtAl₂+(Ni, Pt)Al dual-phase aluminide coating was prepared on a Ni-based single crystal superalloy by co-deposition of Pt-Zr through electroplating and subsequent aluminization treatments. The coating was mainly composed of three layers: the outmost layer consisted of double phases with PtAl₂ particles dispersed in β-(Ni, Pt)Al domain, while the interlayer comprised β-(Ni, Pt)Al with small amount of Cr-precipitates, and the bottom layer was an inter-diffusion zone (IDZ). Zirconium was mainly distributed inside β-(Ni, Pt)Al solid solution in both the outmost layer and the interlayer. Compared with normal PtAl₂+(Ni, Pt)Al dual-phase coating, the hot corrosion behavior of the Zr-doped PtAl₂+(Ni, Pt)Al coating was assessed in a salt mixture of Na₂SO₄/NaCl (75:25, mass ratio) at 850 ℃ in static air. The results indicated that the Zr-doped PtAl₂+(Ni, Pt)Al dual-phase coating exhibited superior hot corrosion resistance since Zr was confirmed able to capture and fix S and Cl to diminish their detrimental effects. Meanwhile, a pre-oxidation treatment did not effectively improve the overall hot corrosion resistance of normal PtAl₂+(Ni, Pt)Al coating because the thin alumina scale formed during pre-oxidation was unable to prohibit the sustained inward-invasion of the mixed salt.

Key words： Zr-doping reactive element Pt-Al coating hot corrosion

收稿日期: 2017-09-08

ZTFLH:

TG174.44

基金资助:国家自然科学基金项目Nos.51671202、51301184,国防基础科研项目No.JCKY2016404C001和辽宁省百千万人才工程项目

作者简介:

作者简介蒋成洋,男,1991年生,博士生

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https://www.ams.org.cn/CN/10.11900/0412.1961.2017.00376 或 https://www.ams.org.cn/CN/Y2018/V54/I4/581

图1 N5单晶高温合金上Pt-Zr复合电镀后的表面和截面形貌的SEM像

图2 普通和Zr改性PtAl2+(Ni, Pt)Al双相涂层截面形貌的SEM像

图3 普通和Zr改性PtAl2+(Ni, Pt)Al双相涂层的XRD谱

图4 N5基体、经预氧化处理的PtAl2+(Ni, Pt)Al涂层、普通PtAl2+(Ni, Pt)Al双相涂层和Zr改性PtAl2+(Ni, Pt)Al双相涂层850 ℃下在Na2SO4/NaCl (75:25,质量比)混合盐中热腐蚀质量变化曲线

图5 普通和Zr改性PtAl2+(Ni, Pt)Al双相涂层850 ℃下热腐蚀60 h后的XRD谱

图6 普通和Zr改性PtAl2+(Ni, Pt)Al双相涂层850 ℃下热腐蚀60 h截面形貌的SEM像

图7 普通和Zr改性PtAl2+(Ni, Pt)Al双相涂层850 ℃下热腐蚀100 h后的XRD谱

图8 普通和Zr改性PtAl2+(Ni, Pt)Al双相涂层850 ℃下热腐蚀100 h后截面形貌的SEM像

图9 普通PtAl2+(Ni, Pt)Al双相涂层850 ℃下热腐蚀100 h后截面的EPMA面扫描结果

图10 Zr改性PtAl2+(Ni, Pt)Al双相涂层850 ℃下热腐蚀100 h后截面的EPMA面扫描结果

图11 普通PtAl2+(Ni, Pt)Al双相涂层预氧化4 h后截面形貌的SEM像

图12 普通PtAl2+(Ni, Pt)Al双相涂层预氧化后和继续热腐蚀100 h后的XRD谱

图13 预氧化后的普通PtAl2+(Ni, Pt)Al双相涂层样品850 ℃下在混合盐中热腐蚀100 h后截面形貌的SEM像

[1]	Rapp R A.Hot corrosion of materials: A fluxing mechanism?[J]. Corros. Sci., 2002, 44: 209
[2]	Padture N P, Gell M, Jordan E H.Thermal barrier coatings for gas-turbine engine applications[J]. Science, 2002, 296: 280
[3]	Zeng C L, Wu W T, Guo J T.High temperature hot corrosion of NiAl-20%Fe with its surface aluminide coating[J]. Acta Metall. Sin., 1996, 32: 197(曾潮流, 吴维?, 郭建亭. 渗铝NiAl-20%Fe金属间合金的高温热腐蚀[J]. 金属学报, 1996, 32: 197)
[4]	Rhys-Jones T N. Coatings for blade and vane applications in gas turbines[J]. Corros. Sci., 1989, 29: 623
[5]	Guan H R, Lou H Y, Mao X Y, et al.Deterioration of aluminide coating on nickel-base superalloys[J]. Acta Metall. Sin., 1981, 17: 412(管恒荣, 楼翰一, 毛晓禹等. 两种高温合金渗Al防护层的退化过程[J]. 金属学报, 1981, 17: 412)
[6]	Felten E J, Pettit F S.Development, growth, and adhesion of Al2O3 on platinum-aluminum alloys[J]. Oxid. Met., 1976, 10: 189
[7]	Kohlscheen J, Stock H R.Deposition of silicon enriched nickel aluminide coatings on internally cooled airfoils[J]. Met. Finish., 2009, 107: 22
[8]	Li M J, Sun X F, Guan H R, et al.High temperature hot-corrosion behavior of (Ni, Pd)Al coating[J]. Acta Metall. Sin., 2004, 40: 773(李猛进, 孙晓峰, 管恒荣等. (Ni, Pd)Al涂层的高温热腐蚀[J]. 金属学报, 2004, 40: 773)
[9]	Li M J, Sun X F, Guan H R, et al.High temperature oxidation behavior of Pd-Ni-Al coating[J]. Acta Metall. Sin., 2003, 39: 755(李猛进, 孙晓峰, 管恒荣等. Pd-Ni-Al涂层的高温长期氧化行为[J]. 金属学报, 2003, 39: 755)
[10]	Boone D H, Deb P, Purvis L I, et al.Surface morphology of platinum modified aluminide coatings[J]. J. Vac. Sci. Technol., 1985, 3A: 2557
[11]	Deb P, Boone D H, Streiff R.Platinum aluminide coating structural effects on hot corrosion resistance at 900 ℃[J]. J. Vac. Sci. Technol., 1985, 3A: 2578
[12]	Deb P, Boone D H, Manley II T F. Surface instability of platinum modified aluminide coatings during 1100 ℃ cyclic testing[J]. J. Vac. Sci. Technol., 1987, 5A: 3366
[13]	Stringer J. The reactive element effect in high-temperature corrosion [J]. Mater. Sci. Eng., 1989, A120-121: 129
[14]	Wei F I, Stott F H.The development of Cr2O3 scales on iron-chromium alloys containing reactive elements[J]. Corro. Sci., 1989, 29: 839
[15]	Thanneeru R, Patil S, Deshpande S, et al.Effect of trivalent rare earth dopants in nanocrystalline ceria coatings for high-temperature oxidation resistance[J]. Acta Mater., 2007, 55: 3457
[16]	Sánchez L, Bolívar F J, Hierro M P, et al.Effect of Ce and La additions in low temperature aluminization process by CVD-FBR on 12%Cr ferritic/martensitic steel and behaviour in steam oxidation[J]. Corros. Sci., 2008, 50: 2318
[17]	Hong S J, Hwang G H, Han W K, et al.Effect of zirconium addition on cyclic oxidation behavior of platinum-modified aluminide coating on nickel-based superalloy[J]. Intermetallics, 2010, 18: 864
[18]	Liu Q, Yang Y F, Bao Z B, et al.Oxidation property and failure mechanism of a single phase PtAl2 coating[J]. Acta Metall. Sin., 2014, 50: 1102(柳泉, 阳颖飞, 鲍泽斌等. PtAl2单相涂层的高温抗氧化性能及失效机制研究[J]. 金属学报, 2014, 50: 1102)
[19]	Moretto P, Bressers J, Arrell D J.Evolution of a PtAl2 coating on the nickel-base alloy CMSX-6 subjected to thermo-mechanical fatigue[J]. Mater. Sci. Eng., 1999, A272: 310
[20]	Smeggil J G.Some comments on the role of yttrium in protective oxide scale adherence[J]. Mater. Sci. Eng., 1987, 87: 261
[21]	Smialek J L.Adherent Al2O3 scales formed on undoped nicrai alloys[J]. Metall. Mater. Trans., 1987, 18A: 164
[22]	Smialek J L, Jayne D T, Schaeffer J C, et al.Effects of hydrogen annealing, sulfur segregation and diffusion on the cyclic oxidation resistance of superalloys: A review[J]. Thin Solid Films, 1994, 253: 285
[23]	Lee W Y, Wright I G, Pint B A, et al.Effects of sulfur impurity on the scale adhesion behavior of a desulfurized Ni-based superalloy aluminized by chemical vapor deposition[J]. Metall. Mater. Trans., 1998, 29A: 833
[24]	Eliaz N, Shemesh G, Latanision R M.Hot corrosion in gas turbine components[J]. Eng. Fail. Anal., 2002, 9: 31
[25]	Barin I, translated by Cheng N L, Niu S T, Xu G Y, et al. Thermochemical Data of Pure Substances [M]. Beijing: Science Press, 2010: 563(Barin I 著, 程乃良, 牛四通, 徐桂英等译. 纯物质热化学数据手册 [M]. 北京: 科学出版社, 2010: 563)
[26]	Bao Z B, Wang Q M, Li W Z, et al.Preparation and hot corrosion behaviour of an Al-gradient NiCoCrAlYSiB coating on a Ni-base superalloy[J]. Corros. Sci., 2009, 51: 860
[27]	Shinata Y.Accelerated oxidation rate of chromium induced by sodium chloride[J]. Oxid. Met., 1987, 27: 315
[28]	Shinata Y. Nishi Y.NaCl-induced accelerated oxidation of chromium[J]. Oxid. Met., 1986, 26: 201
[29]	Deodeshmukh V, Gleeson B.Effects of platinum on the hot corrosion behavior of Hf-modified γ′-Ni3Al +γ-Ni-based alloys[J]. Oxid. Met., 2011, 76: 43

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