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金属学报  2015, Vol. 51 Issue (9): 1145-1152    DOI: 10.11900/0412.1961.2015.00041
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弯月面热障涂层方法对结晶器传热及铸坯振痕形貌的影响
侯晓光1,2,王恩刚1(),许秀杰1,邓安元1,王万林3
2 宝山钢铁股份有限公司, 上海 201900
3 中南大学冶金与环境学院, 长沙 410083
EFFECT OF THERMAL BARRIER COATINGS ABOVE MOULD MENISCUS ON MOULD HEAT TRANSFER AND OSCILLATION MARK MORPHOLOGY OF STRANDS
Xiaoguang HOU1,2,Engang WANG1(),Xiujie XU1,Anyuan DENG1,Wanlin WANG3
1 Key Laboratory of Electromagnetic Processing of Materials (Ministry of Education), Northeastern University, Shenyang 110819
2 Baoshan Iron & Steel Co., Ltd., Shanghai 201900
3 School of Metallurgy and Environment, Central South University, Changsha 410083
引用本文:

侯晓光,王恩刚,许秀杰,邓安元,王万林. 弯月面热障涂层方法对结晶器传热及铸坯振痕形貌的影响[J]. 金属学报, 2015, 51(9): 1145-1152.
Xiaoguang HOU, Engang WANG, Xiujie XU, Anyuan DENG, Wanlin WANG. EFFECT OF THERMAL BARRIER COATINGS ABOVE MOULD MENISCUS ON MOULD HEAT TRANSFER AND OSCILLATION MARK MORPHOLOGY OF STRANDS[J]. Acta Metall Sin, 2015, 51(9): 1145-1152.

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摘要: 

提出了一种在结晶器弯月面上方涂敷热障涂层, 来抑制弯月面传热, 进而控制铸坯振痕形成的新方法, 称为弯月面热障涂层方法(TBCMM). 利用模拟结晶器弯月面一维传热的测试装置, 研究了热障涂层在结晶器弯月面的不同位置对传热的影响规律, 分析了热障涂层抑制振痕形成的机理; 在浸铸式连铸模拟机上, 分别进行了结晶器有、无热障涂层的低熔点Sn-12.5%Pb合金的模拟连铸实验, 获得了实测的弯月面温度波动曲线和铸坯, 对比分析了弯月面热流和铸坯表面振痕形貌, 证实了提出的TBCMM的有效性; 最后, 在中试实验连铸机上, 研究了热障涂层对钢连铸坯表面质量的影响, 获得了表面振痕减轻甚至消除的连铸钢坯.

关键词 热障涂层连铸弯月面振痕    
Abstract

Oscillation marks are closely related to the surface quality of bloom. Excellent surface quality of bloom is essential assurance of the technology of continuous casting and rolling. The improvement of heat transfer process through mold is beneficial to alleviate oscillation marks. A new method of inhibiting formation of oscillation marks in continuous casting, namely spraying or embedding thermal barrier coatings above mold meniscus (TBCMM) was proposed, by which the temperature and heat flux fluctuation of meniscus was reduced, and then the surface quality of strands was improved. Using an one-dimensional heat transfer simulating apparatus, the effect of location of thermal barrier coatings on heat transfer near meniscus was investigated, and the possible mechanism of TBCMM on inhibiting formation of oscillation marks was also discussed. With a dip simulator for continuous casting, lower melt point Sn-12.5%Pb alloy was casted with thermal barrier coating (TBC) and without TBC molds respectively, and the temperature fluctuation was also measured. The heat flux near meniscus in mold and the oscillation marks morphology on strands confirm the effectiveness of the proposed TBCMM. Finally, in a pilot continuous caster, casting experiments of steel with TBCMM was conducted, and the oscillation marks on billet surface were alleviated or removed.

Key wordsthermal barrier coating    continuous casting    meniscus    oscillation mark
    
基金资助:*国家自然科学基金项目50834009和51474065, 教育部重大科技项目311014, 以及高等学校学科创新引智计划项目B07015资助
图1  结晶器一维传热测试装置示意图
图2  热障涂层在结晶器不同位置的示意图
图3  浸铸模拟机结晶器与热电偶分布示意图
图4  中试连铸机结晶器示意图
图5  不同位置热障涂层对Cu模实时温度的影响
图6  不同位置热障涂层对Cu模实时热流的影响
Condition Rm mm2KW-1 Rs mm2KW-1 Rc mm2KW-1 Ri mm2KW-1 Rt mm2KW-1 A
No plating 0.0656 2.667 0.0 8.781 11.514 0.763
Hot side 0.0656 2.667 0.2 10.092 13.025 0.775
Meniscus 0.0656 2.667 0.2 12.957 15.890 0.815
表1  Cu模结晶器的热阻
图7  Sn-12.5%Pb合金浸铸实验实时温度曲线
图8  Sn-12.5%Pb合金2次浸铸实验结晶器的输入热流曲线
图9  Sn-12.5%Pb合金2次浸铸实验获得的铸坯形貌
图10  弯月面热障涂层抑制铸坯振痕形成的作用机理示意图
图11  钢连铸坯表面振痕形貌
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