Please wait a minute...
金属学报  2013, Vol. 49 Issue (5): 621-628    DOI: 10.3724/SP.J.1037.2012.00720
  论文 本期目录 | 过刊浏览 |
Al和Zn对铸造Mg-5Sn合金微观组织和力学性能的影响
董旭光,付俊伟,杨院生
中国科学院金属研究所, 沈阳 110016
EFFECTS OF Al AND Zn ADDITION ON THE MICROSTRUCTURE AND MECHANICAL PROPERTIES OF CAST Mg-5Sn ALLOY
DONG Xuguang, FU Junwei, YANG Yuansheng
Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016
引用本文:

董旭光,付俊伟,杨院生. Al和Zn对铸造Mg-5Sn合金微观组织和力学性能的影响[J]. 金属学报, 2013, 49(5): 621-628.
DONG Xuguang, FU Junwei, YANG Yuansheng. EFFECTS OF Al AND Zn ADDITION ON THE MICROSTRUCTURE AND MECHANICAL PROPERTIES OF CAST Mg-5Sn ALLOY[J]. Acta Metall Sin, 2013, 49(5): 621-628.

全文: PDF(3870 KB)  
摘要: 

根据合金成分设计, 在Mg-5Sn铸造合金中逐步添加2%Al及4%Zn(质量分数), 实验结果表明,单独添加Al后, 一次枝晶尺寸减小, 且二次臂变的更加细密, 合金的延伸率从6.6%提高到22.4%; Al和Zn复合添加后, 长程枝晶转变为较为圆整的蔷薇状, 在合金中生成了Mg32(Al, Zn)49,合金的屈服强度和抗拉强度分别达到96和232 MPa, 但延伸率则下降到14.8%. 通过固溶时效处理,Mg-5Sn-4Zn-2Al合金在175 ℃时效24 h后达到硬度峰值83.5 HV, 其晶内析出相由沿[0001]晶向分布的MgZn2和块状的Mg2Sn相组成, 对应的室温屈服和抗拉强度分别提升到144和264 MPa; 在150 ℃下其屈服强度仍可达到138 MPa, 这表明合金的晶内析出的MgZn2Mg2Sn相在高温下仍具有良好的强化作用.

关键词 Mg-5Sn合金Al和Zn添加微观组织时效强化力学性能断口分析    
Abstract

A cast Mg-5Sn-4Zn-2Al alloy was developed by adding 2%Al and 4%Zn (mass fraction) into a Mg-5Sn base alloy. The results showed that the combined addition of Al and Zn had more obvious effect on dendrite refinement than the single Al addition. The single Al addition remarkably increased the elongation from 6.6% to 22.4%. With further addition of Zn, Mg32(Al, Zn)49 phase was introduced into the solidified microstructure, and the yield strength and ultimate tensile strength were increased to 96 and 232 MPa while elongation was decreased to 14.8%. After aging treatment at 175 ℃ for 24 h, there appeared peak hardness of 83.5 HV by forming the rod-shaped MgZn2 along c-axis and cubic Mg2Sn precipitates into α-Mg matrix for Mg-5Sn-4Zn-2Al alloy. With the aging strengthening, the yield strength and ultimate tensile strength were further increased to 144 and 264 MPa, respectively. When the testing temperature was elevated to 150 ℃, the yield strength of peak-aged Mg-5Sn-4Zn-2Al alloy still attained to 138 MPa, which indicated that both the MgZn2 and Mg2Sn precipitates possess good thermal stability for elevated temperature property.

Key wordsMg-5Sn alloy    addition of Al and Zn    microstructure    aging strengthening    mechanical property    fracture analysis
收稿日期: 2012-12-07     
基金资助:

国家高技术研究发展计划资助项目2011BAE22B01-1

作者简介: 董旭光, 男, 1982年生, 博士生

[1] Liu H M, Chen Y G, Tang Y B, Wei S H, Niu G.  J Alloys Compd, 2007; 440: 122


[2] Nayyeri G, Mahmudi R.  Mater Sci Eng, 2010; A527: 4613

[3] Poddara P, Sahooa K L, Mukherjeeb S, Raya A K.  Mater Sci Eng, 2012; A545: 103

[4] Cheng W L, Park S S, You B S, Koo B H.  Mater Sci Eng, 2012; A527: 4650

[5] Park S S, Tang W N, You B S.  Mater Lett, 2010; 64: 31

[6] Sasaki T T, Yamamoto K, Honma T, Kamadob S, Honoa K.  Scr Mater, 2008; 59: 1111

[7] C'aceres C H, Rovera D M.  J Light Met, 2001; 1: 151

[8] Blake A H, C'aceres C H.  Mater Sci Eng, 2008; A483-484: 161

[9] Shi B Q, Chen R S, Ke W.  J Alloys Compd, 2011; 509: 3357

[10] Liu H M, Chen Y G, Zhao H F, Wei S H, Gao W.  J Alloys Compd, 2010; 504: 345

[11] Liu H M, Chen Y G, Tang Y B, Huang D M, Niu G.  Mater Sci Eng, 2006; A437: 348

[12] Yang M B, Pan F S.  Mater Sci Eng, 2009; A525: 112

[13] Yang M B, Pan F S, Cheng L, Shen J.  Mater Sci Eng, 2009; A512: 132

[14] Kim B H, Lee S W, Park Y H, Park I M.  J Alloys Compd, 2010; 493: 502

[15] Lee S G, Jeon J J, Park K C, Park Y H, Park I M.  Mater Chem Phys, 2011; 128: 208

[16] Kang D H, Park S S, Kim N J.  Mater Sci Eng, 2005; A413-414: 555

[17] Park S S, You B S.  Scr Mater, 2011; 65: 202

[18] Son H T, Lee J B, Jeong H G, Konno T J.  Mater Lett, 2011; 65: 1966

[19] Lim H K, Kim D H, Lee J Y, Kim W T, Kim D H.  J Alloys Compd, 2009; 468: 308

[20] Emley E F.  Principles of Magnesium Technology. London: Pergamon Press, 1966: 969

[21] Chen J H, Chen Z H, Yan H G, Zhang F Q, Liao K.  J Alloys Compd, 2008; 461: 209

[22] Harosh S, Miller L, Levi G, Bamberger M.  J Mater Sci, 2007; 42: 9983

[23] Mendis C L, Bettles C J, Gibson M A, Hutchinson C R.  Mater Sci Eng, 2006; A435-436: 163

[24] Sasaki T T, Oh-ishi K, Ohkubo T, Hono K.  Scr Mater, 2006; 55: 251

[25] Sasaki T T, Oh-ishi K, Ohkubo T, Hono K.  Mater Sci Eng, 2011; A530: 1

[26] Lee Y C, Dahle A K, Stjohn D H.  Metall Mater Trans, 2000; 31A: 2895

[27] Fu J W, Yang Y S.  J Cryst Growth, 2011; 322: 84

[28] Hu H Q.  Principal of Metal Solidification. Beijing: China Machine Press, 2008: 117

(胡汉起. 金属凝固原理. 北京: 机械工业出版社, 2008: 117)

[29] Tang W N, Park S S, You B S.  Mater Design, 2011; 32: 3537

[30] Nave M D, Dahle A K, Stjohn D H. In: Kaplan H I, Hryn J, Clow B eds.,  Magnesium Technology 2000.

Tennessee: The Minerals, Metals & Materials Society, 2000: 233

[31] Lu Y Z, Wang Q D, Ding W J, Zeng X Q, Zhu Y P.  Mater Lett, 2000; 44: 265

[32] Nie J F.  Scr Mater, 2003; 48: 1009
[1] 张健, 王莉, 谢光, 王栋, 申健, 卢玉章, 黄亚奇, 李亚微. 镍基单晶高温合金的研发进展[J]. 金属学报, 2023, 59(9): 1109-1124.
[2] 郑亮, 张强, 李周, 张国庆. /降氧过程对高温合金粉末表面特性和合金性能的影响:粉末存储到脱气处理[J]. 金属学报, 2023, 59(9): 1265-1278.
[3] 宫声凯, 刘原, 耿粒伦, 茹毅, 赵文月, 裴延玲, 李树索. 涂层/高温合金界面行为及调控研究进展[J]. 金属学报, 2023, 59(9): 1097-1108.
[4] 张雷雷, 陈晶阳, 汤鑫, 肖程波, 张明军, 杨卿. K439B铸造高温合金800℃长期时效组织与性能演变[J]. 金属学报, 2023, 59(9): 1253-1264.
[5] 陈礼清, 李兴, 赵阳, 王帅, 冯阳. 结构功能一体化高锰减振钢研究发展概况[J]. 金属学报, 2023, 59(8): 1015-1026.
[6] 刘兴军, 魏振帮, 卢勇, 韩佳甲, 施荣沛, 王翠萍. 新型钴基与Nb-Si基高温合金扩散动力学研究进展[J]. 金属学报, 2023, 59(8): 969-985.
[7] 丁桦, 张宇, 蔡明晖, 唐正友. 奥氏体基Fe-Mn-Al-C轻质钢的研究进展[J]. 金属学报, 2023, 59(8): 1027-1041.
[8] 李景仁, 谢东升, 张栋栋, 谢红波, 潘虎成, 任玉平, 秦高梧. 新型低合金化高强Mg-0.2Ce-0.2Ca合金挤压过程中的组织演变机理[J]. 金属学报, 2023, 59(8): 1087-1096.
[9] 袁江淮, 王振玉, 马冠水, 周广学, 程晓英, 汪爱英. Cr2AlC涂层相结构演变对力学性能的影响[J]. 金属学报, 2023, 59(7): 961-968.
[10] 冯艾寒, 陈强, 王剑, 王皞, 曲寿江, 陈道伦. 低密度Ti2AlNb基合金热轧板微观组织的热稳定性[J]. 金属学报, 2023, 59(6): 777-786.
[11] 吴东江, 刘德华, 张子傲, 张逸伦, 牛方勇, 马广义. 电弧增材制造2024铝合金的微观组织与力学性能[J]. 金属学报, 2023, 59(6): 767-776.
[12] 张东阳, 张钧, 李述军, 任德春, 马英杰, 杨锐. 热处理对选区激光熔化Ti55531合金多孔材料力学性能的影响[J]. 金属学报, 2023, 59(5): 647-656.
[13] 王长胜, 付华栋, 张洪涛, 谢建新. 冷轧变形对高性能Cu-Ni-Si合金组织性能与析出行为的影响[J]. 金属学报, 2023, 59(5): 585-598.
[14] 刘满平, 薛周磊, 彭振, 陈昱林, 丁立鹏, 贾志宏. 后时效对超细晶6061铝合金微观结构与力学性能的影响[J]. 金属学报, 2023, 59(5): 657-667.
[15] 侯娟, 代斌斌, 闵师领, 刘慧, 蒋梦蕾, 杨帆. 尺寸设计对选区激光熔化304L不锈钢显微组织与性能的影响[J]. 金属学报, 2023, 59(5): 623-635.